全文获取类型
收费全文 | 187篇 |
免费 | 12篇 |
专业分类
化学 | 125篇 |
晶体学 | 1篇 |
数学 | 7篇 |
物理学 | 66篇 |
出版年
2023年 | 1篇 |
2021年 | 3篇 |
2020年 | 4篇 |
2019年 | 2篇 |
2018年 | 3篇 |
2017年 | 4篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 10篇 |
2013年 | 12篇 |
2012年 | 13篇 |
2011年 | 18篇 |
2010年 | 12篇 |
2009年 | 11篇 |
2008年 | 16篇 |
2007年 | 5篇 |
2006年 | 13篇 |
2005年 | 9篇 |
2004年 | 10篇 |
2003年 | 6篇 |
2002年 | 6篇 |
2001年 | 5篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1995年 | 7篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1989年 | 2篇 |
1977年 | 1篇 |
1944年 | 2篇 |
1934年 | 1篇 |
排序方式: 共有199条查询结果,搜索用时 31 毫秒
81.
82.
83.
84.
85.
I. Bruns A. Siebert R. Baumbach J. Miersch D. Günther B. Markert G.-J. Krauß 《Analytical and bioanalytical chemistry》1995,353(1):101-104
The water moss Fontinalis antipyretica has been investigated to estimate heavy metal pollution in the river Elbe (middle Germany). Procedures of plant separation, digestion as well as an analytical method for ICP-MS analyses have been evaluated. Reproducibility and accuracy have been demonstrated on BCR 61 (NIST) reference material and results have been compared with AAS and AES data. The distribution of heavy metals in different plant segments of indigenous material has been analyzed. Exposition of plant material in the river Elbe have shown no correlation between the heavy metal content in plants and that of water samples. Cd and Zn concentrations found in the plant material are significantly enriched relatively to control samples. To understand the sophisticated ‘real system’ experiments have been carried out under laboratory conditions to investigate induced sulphur-rich compounds in the presence of heavy metals using HPLC including on-line derivatization. 相似文献
86.
I. Bruns A. Siebert R. Baumbach J. Miersch D. Günther B. Markert G.-J. Krau? 《Fresenius' Journal of Analytical Chemistry》1995,353(1):101-104
The water moss Fontinalis antipyretica has been investigated to estimate heavy metal pollution in the river Elbe (middle Germany). Procedures of plant separation, digestion as well as an analytical method for ICP-MS analyses have been evaluated. Reproducibility and accuracy have been demonstrated on BCR 61 (NIST) reference material and results have been compared with AAS and AES data. The distribution of heavy metals in different plant segments of indigenous material has been analyzed. Exposition of plant material in the river Elbe have shown no correlation between the heavy metal content in plants and that of water samples. Cd and Zn concentrations found in the plant material are significantly enriched relatively to control samples. To understand the sophisticated real system experiments have been carried out under laboratory conditions to investigate induced sulphur-rich compounds in the presence of heavy metals using HPLC including on-line derivatization. 相似文献
87.
Biomolecular surface engineering of materials often requires precise, versatile and efficient quantification of immobilized proteins at solid surfaces. Acidic hydrolysis of surface-bound proteins and subsequent HPLC analysis of fluorescence-derivatized amino acids were adapted and critically evaluated for that purpose. Contaminations and concentration-dependent amino acid retrieval during HPLC were found to influence the accuracy of the method. In addition to the choice of adequate conditions for hydrolysis, derivatization and chromatographic separation extensions of the data evaluation were suggested to improve the accuracy of the approach when applied to single protein systems: comparing the experimentally obtained amino acid ratio to the protein constitution enabled to identify the properly separated and detected amino acids. Those amino acids were selected for a more precise calculation of the amount of immobilized protein. To further increase the accuracy of the method, the retrieval of amino acids corresponding to protein amounts in the range between 0.5 and 4.0 microg was analyzed for a variety of proteins of interest to derive protein-specific correction factors. The evaluation of amino acid data was furthermore applied to quantify binary protein mixtures at similar settings. This method was proven useful to detect the composition of protein mixtures throughout a wide range of absolute and relative concentrations. 相似文献
88.
Schwerdtfeger P Bast R Gerry MC Jacob CR Jansen M Kellö V Mudring AV Sadlej AJ Saue T Söhnel T Wagner FE 《The Journal of chemical physics》2005,122(12):124317
An attempt is made to improve the currently accepted muonic value for the 197Au nuclear quadrupole moment [+0.547(16)x10(-28) m2] for the 3/2+ nuclear ground state obtained by Powers et al. [Nucl. Phys. A230, 413 (1974)]. From both measured Mossbauer electric quadrupole splittings and solid-state density-functional calculations for a large number of gold compounds a nuclear quadrupole moment of +0.60x10(-28) m2 is obtained. Recent Fourier transform microwave measurements for gas-phase AuF, AuCl, AuBr, and AuI give accurate bond distances and nuclear quadrupole coupling constants for the 197Au isotope. However, four-component relativistic density-functional calculations for these molecules yield unreliable results for the 197Au nuclear quadrupole moment. Relativistic singles-doubles coupled cluster calculations including perturbative triples [CCSD(T) level of theory] for these diatomic systems are also inaccurate because of large cancellation effects between different field gradient contributions subsequently leading to very small field gradients. Here one needs very large basis sets and has to go beyond the standard CCSD(T) procedure to obtain any reliable field gradients for gold. From recent microwave experiments by Gerry and co-workers [Inorg. Chem. 40, 6123 (2001)] a significantly enhanced (197)Au nuclear quadrupole coupling constant in (CO)AuF compared to free AuF is observed. Here, these cancellation effects are less important, and relativistic CCSD(T) calculations finally give a nuclear quadrupole moment of +0.64x10(-28) m2 for 197Au. It is argued that it is currently very difficult to improve on the already published muonic value for the 197Au nuclear quadrupole moment. 相似文献
89.
Fei Cheng Stephen M. Kelly Stephen Clark John S. Bradley Marc Baumbach Andreas Schütze 《Journal of membrane science》2006,280(1-2):530-535
We report a novel fabrication process of a mesoporous Si3N4 membrane on an Al2O3 support via a non-aqueous sol–gel technique. The membrane was prepared by dipping an -Al2O3 support disk into a silicon diimide sol that was synthesized by catalytic ammonolysis of tris(dimethylamino)silylamine, H2NSi(NMe2)3. The SEM image and nitrogen adsorption analysis indicate that amorphous Si3N4 layers with nano-sized pores have formed on the surface and also inside the pores of the Al2O3 support disk. The new membrane demonstrates high selective absorption of NO2, suggesting a potential application as a selective filter for gas sensors. 相似文献
90.
Wolfgang Vautz Bertram Bödeker Sabine Bader Jörg Ingo Baumbach 《International Journal for Ion Mobility Spectrometry》2008,11(1-4):71-76
The harmonization of data formats is always under discussion, especially with respect to the increasing application of ion mobility spectrometry in metabolomics and different other life sciences. To organise the exchange between different types of ion mobility spectrometers (IMS) using various pre-separation techniques [gas-chromatography (GC), e.g. multi-capillary columns (MCC)] applied and several sensors for a controlled sampling and to start a uniform visualisation procedure, a data format is recommended with respect to further use in data acquisition, visualisation, peak finding, signal comparison and data mining. Although the format is optimised for MCC/IMS and GC/IMS with sampling control by CO2 or flow sensors for breath analysis, its flexibility is ensured by the possibility of version-controlled modifications. The data format proposed will be described in detail. 相似文献