Adsorption of nonpolar benzene derivatives on single-walled carbon nanotubes

The adsorption of benzene, toluene, and chlorobenzene on single-walled carbon nanotubes (SWCNTs) with and without acid oxidation was conducted to investigate the influences of derivative groups on benzene rings and functional groups from SWCNTs on adsorption by SWCNTs. The SWCNTs of high purity were chosen and moderate acid oxidation was performed so that the surface physical properties remained unchanged after acid oxidation and the influences of acid oxidation on adsorption were only contributed from the modification of the surface chemistry of SWCNTs. The oxygen-containing surface groups introduced by acid oxidation obstructed the interactions between functional groups of nonpolar benzene derivatives and C-rings of SWCNTs significantly. The dispersive interaction between the partially positive H⁺ of the methyl group and the oxygen-containing surface groups slightly increased the adsorption of toluene on oxidized SWCNTs at high solution pH. The thermodynamic of adsorption was also studied at different temperatures.     

A combined experimental and theoretical analysis of Fe-implanted TiO2 modified by metal plasma ion implantation

Photocatalyst titanium dioxide (TiO₂) thin films were prepared using sol-gel process. To improve the photosensitivity of TiO₂ at visible light, transition metal of Fe was implanted into TiO₂ matrix at 20 keV using the metal plasma ion implantation process. The primary phase of the Fe-implanted TiO₂ films is anatase, but X-ray diffraction revealed a slight shift of diffraction peaks toward higher angles due to the substitutional doping of iron. The additional band gap energy levels were created due to the formation of the impurity levels (Fe-O) verified by X-ray photoelectron spectroscopy, which resulted in a shift of the absorption edge toward a longer wavelength in the absorption spectra. The optical band gap energy of TiO₂ films was reduced from 3.22 to 2.87 eV with an increase of Fe ion dosages from 0 to 1 × 10¹⁶ ions/cm². The band gap was determined by the Tauc plots. The photocatalysis efficiency of Fe-implanted TiO₂ was assessed using the degradation of methylene blue under ultraviolet and visible light irradiation. The calculated density of states for substitutional Fe-implanted TiO₂ was investigated using the first-principle calculations based on the density functional theory. A combined experimental and theoretical Fe-implanted TiO₂ film was formed, consistent with the experimentally observed photocatalysis efficiency of Fe-implanted TiO₂ in the visible region.     

Max-min of polynomials and exponential diophantine equations

In this paper we study the maximum-minimum value of polynomials over the integer ring Z. In particular, we prove the following: Let F(x,y) be a polynomial over Z. Then, maxx∈Z(T)miny∈Z|F(x,y)|=o(T1/2) as T→∞ if and only if there is a positive integer B such that maxx∈Zminy∈Z|F(x,y)|?B. We then apply these results to exponential diophantine equations and obtain that: Let f(x,y), g(x,y) and G(x,y) be polynomials over Q, G(x,y)∈(Q[x,y]−Q[x])∪Q, and b a positive integer. For every α in Z, there is a y in Z such that f(α,y)+g(α,y)bG(α,y)=0 if and only if for every integer α there exists an h(x)∈Q[x] such that f(x,h(x))+g(x,h(x))bG(x,h(x))≡0, and h(α)∈Z.     

Semipolar (11\bar 2\bar 2) ZnO thin films grown on LaAlO3‐buffered LSAT (112) single crystals by pulsed laser deposition

Semipolar (11\bar 2 \bar 2) ZnO was successfully grown on (112) LaAlO₃/(LaAlO₃)_0.29(Sr₂AlTaO₆)_0.35 substrate by pulsed laser deposition. The epitaxial relationship is [11\bar 23]_{\rm ZnO} // [11\bar 1]_{\rm LAO/LSAT} with the polar axis of [000\bar 1]_{\rm ZnO} pointing to the surface. For ZnO films with thickness of 1.6 μm, the threading dislocation density is ～1 × 10⁹ cm^–2, and the density of basal stacking faults is below 1 × 10⁴ cm^–1. The (11\bar 2 \bar 2) ZnO exhibits strong D⁰X emissions with a FWHM of 9 meV and very few green–yellow emissions in the low‐temperature (10 K) and room‐temperature photoluminescence spectra, respectively.

     

Proposal for a New Dense Wavelength Division Multiplexing Filter Based on Two-Dimensional Photonic Crystal Ring Resonator

Abstract

A new optical filter design based on a two-dimensional photonic crystal ring resonator structure with an N-channel model is proposed in this article. This study also shows that modifying the scatter radius and the waveguide width can significantly improve the performance of the original structure, which can solve the mode mismatch problem for output waveguide. Here, an example of a 16-channel photonic crystal ring resonator is provided; wavelength spacing of 1.6 nm and a high quality factor Q of 6,000 were achieved. The optical filter would be a potential key component in the application of dense wavelength division multiplexer devices.     

Holomorphic Anomaly in Gauge Theory on ALE space

We consider four-dimensional Ω-deformed ${\mathcal{N} = 2}$ supersymmetric SU(2) gauge theory on A ₁ space and its lift to five dimensions. We find that the partition functions can be reproduced via special geometry and the holomorphic anomaly equation. Schwinger-type integral expressions for the boundary conditions at the monopole/dyon point in moduli space are inferred. The interpretation of the five-dimensional partition function as the partition function of a refined topological string on A ₁ × (local ${\mathbb{P}^{1} \times \mathbb{P}^1}$ ) is suggested.     

Hyaluronan-assisted synthesis of silver nanoparticles and nanowires

Research on Chemical Intermediates - Silver nanowires (NWs) were successfully synthesized in high yield in cationic surfactant solutions of cetyltrimethylammonium bromide (CTAB) with hyaluronan...     

Point-mutation effects on charge-transport properties of the tumor-suppressor gene p53

We report on a theoretical study of point mutations effects on charge transfer properties in the DNA sequence of the tumor-suppressor p53 gene. On the basis of effective tight-binding models which simulate hole propagation along the DNA, a statistical analysis of mutation-induced charge transfer modifications is performed. In contrast to noncancerous mutations, mutation hot spots tend to result in significantly weaker changes of transmission properties. This suggests that charge transport could play a significant role for DNA-repairing deficiency yielding carcinogenesis.     

Synthesis and properties of thermoresponsive magnetic polymer composites and their electrospun nanofibers

The thermoresponsive magnetic polymer composites and nanofibers were fabricated. Their thermal and magnetic properties were also investigated. Fe₃O₄ nanoparticles were prepared by coprecipitation method. Further condensation reaction was used to fabricate the double‐layer lauric acid modified Fe₃O₄ (DLF) nanoparticles dispersed well in water. Thermal properties of poly(N‐isopropylacrylamide) (PNIPAAm) and DLF/PNIPAAm composites and their aqueous solutions were measured by TGA and DSC. With the increasing of DLF content, the interaction between DLF and PNIPAAm caused the lower critical solution temperature (LCST) of polymer solution to shift from 33 to 31.25 °C. The effects of concentration and pH on LCST were also studied. The DLF/PNIPAAm nanofibers were fabricated by electrospinning. Their diameters were around 100–250 nm. Magnetization curves of DLF/PNIPAAm composite and nanofibers were overlapped and the saturated magnetizations were the same. Magnetic attraction behaviors of DLF/PNIPAAm polymer solution at temperatures below and above LCST were different. Aggregation of DLF/PNIPAAm above LCST enhanced magnetic moment density as well as magnetic attraction ability. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 848–856     

Crosslinkable high dielectric constant polymer dielectrics for low voltage organic field‐effect transistor memory devices

I n this study, we successfully synthesized water/methanol soluble random copolymers with a high dielectric constant, poly(n‐(hydroxymethyl) acrylamide‐co‐5‐(9‐(5‐(diethylamino)pentyl)?2‐(4‐vinylphenyl)?9H‐fluorene(P(NMA‐co‐F6NSt)), which contained chemical crosslinkable segment (NMA) and hole trapping building block (F6NSt). The feeding molar ratios of two monomers (NMA:F6NSt) were set as 100:0, 95:5, 80:20, and 67:33 for the copolymers of P1 , P2 , P3, and P4 , respectively. The crosslinked P(NMA‐co‐F6NSt) thin film could serve as both dielectric and charge storage layers in organic field‐effect transistor (OFET) memory device and exhibited high k (i.e., 4.91–6.47) characteristics, leading to a low voltage operation and a small power consumption. Devices based on the P1 ‐ P4 dielectrics showed excellent insulating properties and good charge storage performance under a low operating voltage in a range of ±5V because of tightly network structures and well‐dispersed trapping cites. In particular, P3 ‐based memory device exhibited a large memory window of 4.13 V with stable data retention stability over 10⁴ s, a large on/off ratio of 10⁴, and good endurance characteristics as high as 200 cycles. The above results suggested that a high‐performance OFET memory device could be facilely achieved using the novel crosslinkable high‐k copolymers. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 3224–3236