求总极值的区间压缩方法

对求解无约束最优化问题 ,本文给出了一个区间压缩方法 .应用此方法能使函数值按几何级数收敛于 f (x)的极小值 ,并且计算量远小于郑权等人方法的计算量     

Comment on the Clauser chart method for determining the friction velocity

A known difficulty with using the Clauser chart method to determine the friction velocity in wall bounded flows is that it assumes, a priori, a logarithmic law for the mean velocity profile. Using both experimental and DNS data in the literature, this note explicitly shows how friction velocities obtained using the Clauser chart method can potentially mask subtle Reynolds-number-dependent behavior.

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醋酸地塞米松在Nafion修饰玻碳电极上的伏安行为及其测定

１引言醋酸地塞米松为一种抗炎、抗过敏的药物。目前,其含量的测定方法主要有光度法、色谱法等。本文发现醋酸地塞米松在玻碳电极（ＧＣＥ）上有电化学活性,但测定的灵敏度较低。如用Ｎａｆｉｏｎ修饰ＧＣＥ后,氧化峰电流增大两个数量级。２实验部分２．１仪器与试剂ＢＡＳ－１００Ａ电化学系统（美国ＢＡＳ仪器公司）,三电极系统：玻碳电极为工作电极（Ｓ＝１．９２ｍｍ２）,饱和甘汞电极为参比电极,铂丝为辅助电极。醋酸地塞米松（北京生物制品研究所,含量≥９９％）用无水乙醇配制成１．０×１０－３ｍｏｌ／Ｌ的储备液。实验所用…     

Er2O3的光致发光光谱,吸收光谱和Raman光谱

在可见激光的激发下,Ｅｒ２Ｏ３粉晶样品的Ｒａｍａｎ光谱易受Ｅｒ＾３＋光致发光光谱的干扰。本文利用同一Ｒａｍａｎ光谱仪测得Ｅｒ２Ｏ３的高分辨可见光吸收光谱和激发光谱。     

Surface self-segregation, wettability, and adsorption behavior of core-shell and pentablock fluorosilicone acrylate copolymers

The surfaces of films cast from core-shell fluorosilicone acrylate copolymer (BA/MMA/DFHM and BA/MMA/DFHM/MPTMS/D(4)) latexes and linear pentablock fluorosilicone acrylate copolymer (PDMS-b-(PMMA-b-PDFHM)(2)) solutions are intensively investigated and compared by XPS, DCA, AFM, and QCM-D measurements. It is found that the molecular structures and in-solution aggregate structures of these well-defined copolymers have a dramatic influence on the surface structure formation, surface wetting, and adsorption behavior. The PDMS-b-(PMMA-b-PDFHM)(2) film cast from chloroform solution with high concentration of low-density unimers is able to perform as strong surface self-segregation of fluorine-containing groups as core-shell copolymer latex films. The BA/MMA/DFHM/MPTMS/D(4) in the core-shell latex particles exhibits the less pronounced surface self-segregation of silicon-containing groups than PDMS-b-(PMMA-b-PDFHM)(2) due to the occurrence of cross-linking reactions between polysiloxane chains. Indeed, such reactions induce the formation of silica network within the film material, which immobilizes tightly the fluorinated groups on the film surface and thus endows the film with higher surface structural stability for water compared to PDMS-b-(PMMA-b-PDFHM)(2) film with similar surface fluorine concentration and even higher silicon concentration. Still, the PDMS-b-(PMMA-b-PDFHM)(2) film definitely demonstrates higher advancing and receding contact angles for water than BA/MMA/DFHM/MPTMS/D(4) latex film in the case of synergism between surface enrichment of fluorine and silicon.     

Asymmetric Arrangement of Monolayer in the Multilayer Films of 2-Hydroxy-4,4＇-dihexyloxy-azobenzene

Multilayer films of 2-hydroxy-4,4‘‘-dihexyloxy-azobenzene (HAB) on silicon substrates have been studied with atomic force microscopy, temperature-dependent FTIR, and X-Ray diffraction technique. The results show that the multilayer films are formed by stacking of HAB monolayers via π-π interactions and the adjacent two monolayers in the film are arranged in an asymmetric way in the multilayer films.     

Effect of Substituents on Aggregation Behaviors of Stilbazole and Stilbazolium Derivatives

Stilbazole and stilbazolium derivatives with dialkylaniline as electron pushing substituents and pyridine or pyridinium substituents as electron drawing substituents were synthesized and their aggregation behaviors were studied by UV‐visible, fluorescence and surface photovoltage spectroscopies. Experimental results indicate that the formation of aggregates can be mediated by the electron drawing ability of the substituents introduced for those compounds all bearing strong electron pushing substituent. When the electron drawing substituent is pyridine group, the molecules tend to aggregate in head‐to‐tail manner, whereas the substituent is pyridinium group, the molecules tend to aggregate in face‐to‐face manner. The effect of electron pushing and drawing ability of the substituents on the aggregation behavior is further analyzed in terms of frontier orbital interactions.     

A glassy carbon electrode modified with carbon nano-fragments and bismuth oxide for electrochemical analysis of trace catechol in the presence of high concentrations of hydroquinone

Microchimica Acta - A glassy carbon electrode was modified with carbon nanofragments and bismuth oxide, and the resulting electrode (CNF-Bi/GCE) was applied to the voltammetric determination of...     

NO_2对Cu/SAPO-34分子筛催化剂上NH_3选择性催化还原NO性能的影响

主要考察了NO2对Cu/SAPO-34分子筛催化剂在整个温度范围内(100-500°C)NH3选择性催化还原(SCR)NO性能的影响.研究所使用样品为新鲜Cu/SAPO-34催化剂在750°C下水热处理4 h的稳定期样品.通过X射线衍射(XRD)和扫描电子显微镜(SEM)对样品的结构以及形貌进行表征,采用SCR活性评价、动力学实验以及原位漫反射傅里叶变换红外光谱(in situ-DRIFTS)表征催化剂的性能以及催化剂表面物种的变化.活性评价实验结果表明,NO2会抑制催化剂的低温(100-280°C)活性,但其存在会提高催化剂的高温(280°C以上)活性.与此同时,随着反应物中NO/NO2的摩尔比例减少,由于NH4NO3物种的分解,副产物(N2O)的浓度增大.动力学结果表明,Cu/SAPO-34催化剂上快速SCR反应的表观活化能(Ea=64.02 kJ?mol-1)比标准SCR反应的表观活化能(Ea=48.00 kJ?mol-1)更大.In situ-DRIFTS实验结果表明NO比NO2更容易在催化剂表面形成硝酸盐,并且NO2更容易与吸附在Br?nsted酸性位上的NH3物种反应生成NH4NO3.低温下,催化剂表面的NH4NO3物种会覆盖SCR反应的活性位,造成活性降低,但在高温时,形成的NH4NO3物种一部分会被NO还原为N2,而另一部分会直接热分解为N2O,造成催化剂的选择性降低.     

Construction of Supramolecular Assemblies from Self‐Organization of Amphiphilic Molecular Isomers

Amphiphilic coil‐rod‐coil molecules, incorporating flexible and rigid blocks, have a strong affinity to self‐organize into various supramolecular aggregates in bulk and in aqueous solutions. In this paper, we report the self‐assembling behavior of amphiphilic coil‐rod‐coil molecular isomers. These molecules consist of biphenyl and phenyl units connected by ether bonds as the rod segment, and poly(ethylene oxide) (PEO) with a degree of polymerization of 7 and 12 as the flexible chains. Their aggregation behavior was investigated by differential scanning calorimetry, thermal optical polarized microscopy, small‐angle X‐ray scattering spectroscopy, and transmission electron microscopy. The results imply that the molecular structure of the rod building block and the length of the PEO chains dramatically influence the creation of supramolecular aggregates in bulk and in aqueous solutions. In the bulk state, these molecules self‐organize into a hexagonal perforated lamellar and an oblique columnar structure, respectively, depending on the sequence of the rod building block. In aqueous solution, the molecule with a linear rod segment self‐assembles into sheet‐like nanoribbons. In contrast, its isomer, with a rod building block substituted at the meta‐position of the aryl group, self‐organizes into nanofibers. This is achieved through the control of the non‐covalent interactions of the rod building blocks.