Catalyst‐Free Protocol for the Synthesis of Quinoxalines and Pyrazines in PEG

A facile and simple catalyst‐free protocol has been developed for the condensation of 1,2‐diketones with aromatic 1,2‐diamines in polyethylene glycol (PEG), providing quinoxaline derivatives in good yields. The important features of the methodology are broad substrates scope, simple workup, catalyst free, environmentally benign, and no requirement for metal catalysts. It is noteworthy that the cyclization reaction of 1,2‐diketones with aliphatic 1,2‐diamines is also conducted smoothly to afford pyrazines in good yields under the standard conditions. In addition, PEG could be recovered easily and was reused without evident loss in activity     

Supramolecular nanostructures from self‐assembly of T‐shaped rod building block oligomers

T‐shaped coil–rod–coil oligomers, consisting of a dibenzo[a,c]phenazine unit and phenyl groups linked together with acetylenyl bonds at the 2,7‐position of dibenzo[a,c]phenazine as a rigid segment have been synthesized. The coil segments of these new molecules composed of poly(ethylene oxide) (PEO)–poly(propylene oxide) (PPO) incorporating lateral methyl groups between the rod and coil segment and two flexible alkyl groups connecting with the rigid segment at the 4,6‐position of dibenzo[a,c]phenazine, respectively. The experimental results reveal that the length of the flexible PEO coil chain influence construction of various supra‐nanostructures from lamellar structure to rectangular columnar structure. It is also shown that introduction of different length of alkyl side chain groups in the backbone of the T‐shaped molecules affect the self‐organization behavior to form hexagonal perforate layer or oblique columnar structures. In addition, lateral methyl groups attached to the surface of rod and coil segments, dramatically influence the self‐assembling behavior in the crystalline phase. T‐shaped molecules containing a lateral methyl group at the surface of rod and PEO coil segments, self‐assemble into 3D body‐centered tetragonal structures in the crystalline phase, while molecules without a lateral methyl group based on PEO coil chain self‐organize into 2D oblique columnar crystalline structures. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013 , 51, 5021–5028     

Synthesis and antitumor and antibacterial evaluation of fluoroquinolone derivatives(Ⅲ):Mono- and bis-Schiff-bases

To further explore an efficient modified route for the shift from an antibacterial fluoroquinolone to an antitumor one,mono-Schiff bases 6a-6h related to ciprofloxacin C3 carbonylhydrazone and bis-Schiff bases 4a-4h corresponding to C3/C7 carbonylhydrazone/hydrazone attached on a skeleton of ciprofloquinolone were designed and synthesized,and their in vitro antitumor activity against CHO,HL60,L1210 cells and antibacterial activity against Staphylococcus aureus and Escherichia coli were also reported.     

La掺杂浓度对PLZT薄膜红外光学性质的影响

采用溶胶-凝胶法在Pt/Ti/SiO2/Si衬底上制备了不同La掺杂浓度PLZT(x/40/60)薄膜- x射线衍射分析表明制备的PLZT(x/40/60)薄膜是具有单一钙钛矿结构的多晶薄膜- 通过红外椭圆偏振光谱仪测量了波长为2-5—12-6μm范围内PLZT薄膜的椭偏光谱，采用经典色 散模型拟合获得PLZT薄膜的红外光学常数，同时也拟合获得PLZT薄膜的厚度- 随着La掺杂浓 度的增大，折射率逐渐减小- 而消光系数除PLZT(4/40/60)薄膜外，呈现逐渐增大的趋势- 分析表明这些差异主要与PLZ 关键词： PLZT薄膜 红外光学性质 红外椭圆偏振光谱     

Dimension of divergence sets for dispersive equation

Consider the generalized dispersive equation defined by{iδtu+Ф(√-△)u=0,(x,t)∈R^n×R,u(x,0)=f(x),F∈F(R^n),(*)whereФ(√-△)is a pseudo-differential operator with symbolФ(|ζ|).In the present paper,assuming thatФsatisfies suitable growth conditions and the initial data in H^s(R^n),we bound the Hausdorff dimension of the sets on which the pointwise convergence of solutions to the dispersive equations(*)fails.These upper bounds of Hausdorff dimension shall be obtained via the Kolmogorov-Seliverstov-Plessner method.     

Manipulation of multi-transparency windows and fast-slow light transitions in a hybrid cavity optomechanical system

We study the generation of quadruple-transparency windows and the implementation of a conversion between slow and fast light in a hybrid optomechanical system. By demonstrating the generation of these transparency windows one by one, we analyze the physical mechanism through which each transparency window forms in detail. Additionally, we discuss how the system parameters affect the formation of transparency windows and conclude that the location, width, and absorption of each transparency window can be arbitrarily manipulated by varying the appropriate parameters. Moreover, when the pump field is changed from red to blue detuning, conversions between slow and fast light occur in the output field. These interesting properties of the output field can be applied to achieve the coherent control and manipulation of light pulses using cavity optomechanical system.     

Dihydrochalcones from Symplocos vacciniifolia

A new dihydrochalcone glucoside, vacciniifolin, along with confusoside, trilobatin and sieboldin were isolated from the leaves of Symplocos vacciniifolia. By the method of spectral analysis, this new compound was elucidated as 2‘,3,4,4‘-tetrahydroxydihydrochalcone 4‘-O-β-D-glu-copyranoside.     

Surface states and its influence on luminescence in ZnS nanocrystallite

In this pape,r the influence of surface effects on the self-activated (SA) luminescence in ZnS nanoparticles prepared by the wet-chemical method is presented. It is observed that the luminescence of SA decreases dramatically by rinsing with methanol. In the rinsed sample, the luminescence of SA increases more by ultraviolet (UV) light irradiation. To clarify its origin, the Raman spectra and electron paramagnetic resonance (EPR) are studied. The results demonstrate that the vibrational modes assigned to organic functional groups of -OH and -COO and -CH₃ decreases remarkably by rinsing, while the EPR signal originated from the unpaired electrons of some transition metal impurity ions including Mn²⁺ increases. It is suggested that the SA centers prefer to occupy the sites near the surface and that the donor of SA emission may be partly related to the organic functional groups of -OH and -COO adsorbed on the surface. The surface-dangling bonds caused by unpaired electrons of some transition metal impurity ions play a role of surface states, leading to the quenching of the SA emissions. The organic functional groups chemically combine with these surface-dangling bonds leading to the decrease in surface states and surface nonradiative relaxation channels and to the increase in the SA emissions.     

THE STABILITY AND APPROXIMATION PROPERTIES OF RITZ-VOLTERRA PROJECTION AND APPLICATION,I

The purpose of this paper is to study the stability and approximation properties of Ritz-Volterra projection. Through constructing a new type of Green functions and making use of various properties and estimates related with the functions, we prove that the Ritz-Volterra projection defined on the finite-dimensional subspace S_h of H_o~1 possesses the W_p~1-stability and the optimal approxi mation properties in W_p~1 and L_p for 2≤p≤∞. Our results, in this paper, can be applied to the finite element approximations for many evolution equations such as parabolic and hyperbolic integrodifferential equations,Sobolevequations and visco-elasticity, etc.     

正己烷在不同硅含量SAPO-5分子筛上的裂化反应特征

正己烷在不同硅含量ＳＡＰＯ┐５分子筛上的裂化反应特征高大维黄彦孙铁杨胥微（吉林大学化学系，长春１３００２３）关键词磷酸硅铝分子筛，正己烷，裂化反应，酸中心１９８２年Ｗｉｌｓｏｎ等［１］首次报道了ＡｌＰＯ４－ｎ系列分子筛的合成工作，１９８３年Ｂｅｎｎｅ...