深水环境下隔水管的横向自由振动分析

隔水管是海洋钻井工程中的必要设备。在深水环境下,隔水管的疲劳失效问题普遍存在,隔水管的强烈振动是导致其失效的主要原因之一。本文采用微元法,得到了隔水管在各种载荷作用下的横向振动规律及其横向振动的固有频率的分布规律,进一步分析了各种因素对隔水管横向振动固有频率的影响。结果表明:隔水管的长度增加时,固有频率减小;随着顶部张力比的增加,隔水管的横向振动的固有频率也增加;随着壁厚的增加,隔水管横向振动的固有频率逐渐降低;而随着钻井液密度的增加,隔水管横向振动的固有频率增加;海水的存在使隔水管的横向振动固有频率降低。该研究有利于避免隔水管在使用过程中出现强烈的共振现象,为减小隔水管的失效提供了理论依据。     

固体火箭发动机振动试验夹具优化分析与研究

通过相同激励条件下对三种典型振动试验夹具进行宽频段随机振动试验分析,发现夹具在试验频段内出现不同程度的共振现象,过试验现象严重。通过三种典型振动试验夹具质量、一阶固有频率、位移变化量及应变变化量等数据对比、分析,得出影响振动试验夹具振动传递特性的主要因素,以影响因素为优化变量,以典型部位平均响应与输入的振动传递比为优化目标,进行拓扑优化设计,最终经过夹具振动试验验证,过试验情况得到有效控制,满足相关规范要求,为固体火箭发动机振动试验控制提供保障。     

稀土掺杂磷酸钇荧光粉的控制合成和发光性能

利用水热法分别合成了Ce~(3+)、Tb~(3+)共掺杂的YPO_4下转换荧光粉和Er~(3+)、Yb~(3+)、Tm~(3+)共掺杂的YPO_4上转换荧光粉,经过工艺优化获得了1μm左右尺寸均匀的发光材料。通过系列实验研究了反应温度、反应时间、稀土离子掺杂比例和退火温度对样品发光性能的影响。YPO_4∶Ce~(3+),Tb~(3+)荧光粉在295 nm紫外光的激发下产生下转换发光效应,当Tb~(3+)摩尔分数为1%时得到明亮的绿光;YPO_4∶Er~(3+),Tm~(3+),Yb~(3+)荧光粉在980nm近红外光激发下产生上转换发光效应,当稀土离子中Er~(3+)摩尔分数为3%时,所制备的样品经过1 000℃退火处理后发出很强的暖白光。     

Alcohol‐Processable Organic Amorphous Electrolytes as an Effective Electron‐Injection Layer for Organic Light‐Emitting Diodes

A new series of monoammonium‐based organic electrolytes with the tetrafluoroborate (BF₄^?) counteranion have been synthesized. Replacing the pendant ethyl groups in the fluorenyl unit with 4‐ethoxyphenyl groups dramatically improves both solubility and morphological stability. The characterization of the alcohol‐processable amorphous ionic compounds as an electron‐injection layer in organic light‐emitting diodes (OLEDs) reveals that the organic electrolyte that comprises a rigid linear‐conjugated unit provides better device performance, with respect to its counterpart containing a branched bulky moiety. The capability of these compounds to facilitate electron injection from air‐stable aluminum metal is preliminarily discussed on the basis of the investigations of the electron‐only devices and photovoltaic experiments.     

Femtosecond laser ablation of ZnO nanorods for two-photon-pumped random lasing and optical data storage

Femtosecond laser ablation based on two-photon absorption was employed to cut ZnO nanorods into uniform ZnO nanoparticles of deep subwavelength size. The fabricated ZnO nanoparticles possess a shorter mean transport length for photons at the emission wavelength and a much smaller scattering cross section at the pump wavelength, leading to highly efficient two-photon-pumped random lasing with a low threshold of ??8?mJ/cm². It was demonstrated that the significant enhancement in two-photon luminescence after the irradiation of femtosecond laser pulses could also be utilized for realizing optical data storage.     

Syntheses and Fluorescence Properties of Two Novel Lanthanide (III) Perchlorate Complexes with Bis(benzylsulfinyl)methane

A novel ligand with double sulfinyl groups, bis(benzylsulfinyl)methane, was synthesized by a new method and its two lanthanide (III) complexes were synthesized and characterized by element analysis, molar conductivity, coordination titration analysis, IR, TG-DSC, ¹HNMR and UV spectra. The results indicated that the composition of these complexes was REL_2.5(ClO₄)₃·3H₂O (RE = Tb (III), Dy (III), L = C₆H₅CH₂SOCH₂SOCH₂C₆H₅). The FT-IR results revealed that the perchlorate group was bonded with the lanthanide ion by the oxygen atoms, and the coordination was bidentate. The fluorescent spectra illustrated that both the Tb (III) and Dy (III) complexes displayed characteristic fluorescence in solid state, especially for the Tb (III) complex, the peak of ⁵D₄ → ⁷ F₅ of the Tb (III) ion in 544 nm was stronger than that of others. It indicated that the Tb (III) complex could emit purer green fluorescence. By analysis fluorescence and phosphorescence spectra, it was found that the ligand had the advantage to absorb energy and transfer it to the Tb (III) and Dy (III) ions. The phosphorescence spectra and fluorescence lifetimes of the complexes were also measured.     

Controllable irregular phenomenon induced by Ag atomic segregation on the melting of (AgPd)561 bimetallic clusters

Here focusing on the very new experimental finding on carbon nanomaterials for solid-state electron mediator applications in Z-scheme photocatalysis, we have investigated different graphene-based nanostructures chemisorbed by various types and amounts of species such as oxygen (O), nitrogen (N) and hydroxyl (OH) and their electronic structures using density functional theory. The work functions of different nanostructures have also been investigated by us to evaluate their potential applications in Z-scheme photocatalysis for water splitting. The N-, O?CN-, and N?CN-chemisorbed graphene-based nanostructures (32 carbon atoms supercell, corresponding to lattice parameter of about 1?nm) are found promising to be utilized as electron mediators between reduction level and oxidation level of water splitting. The O- or OH-chemisorbed nanostructures have potential to be used as electron conductors between H₂-evolving photocatalysts and the reduction level (H⁺/H₂). This systematic study is proposed to understand the properties of graphene-based carbon nanostructures in Z-scheme photocatalysis and guide experimentalists to develop better carbon-based nanomaterials for more efficient Z-scheme photocatalysis applications in the future.     

斯特林发动机换热器系统内工质的压力传递变化特性研究

斯特林发动机由于其外部加热特性适合用于分布式供能系统而正在得到越来越多的重视。斯特林机运转时,其内部工质的压力传递变化特性决定了输出机械功率的大小。本文首先采用施密特分析法对自主研制的某型斯特林机在预充氦气压力为2 MPa的工况下计算其压力的周期性变化情况,然后在同样的工况下用实验测试的方法研究工质在换热器系统内的压力传递变化特性。最后比较理论计算值与实验测试值得出,施密特分析法可以反映出斯特林机换热器系统内工质压力的真实变化情况,且叠网式的回热器结构是造成换热器系统内压力损失的主要因素之一。     

On the random conjugate spaces of a random locally convex module

Theoretically speaking, there are four kinds of possibilities to define the random conjugate space of a random locally convex module. The purpose of this paper is to prove that among the four kinds there are only two which are universally suitable for the current development of the theory of random conjugate spaces. In this process, we also obtain a somewhat surprising and crucial result: if the base (Ω, F , P ) of a random normed module is nonatomic then the random normed module is a totally disconnected topological space when it is endowed with the locally L0 -convex topology.     

卤代-2-(3-甲基-5-取代-4H-1,2,4-三唑-4-基)-苯甲酸的合成

邻氮基苯甲酸;缩合反应;卤代-2-(3-甲基-5-取代-4H-1;2;4-三唑-4-基)-苯甲酸的合成