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91.
Hong-Jun Yang Chen-Qiong Chai Yong-Kang Zuo Jin-Feng Huang Yi-Ye Song Li Jiang Wen-Yan Huang Qi-Min Jiang Xiao-Qiang Xue Bi-Biao Jiang 《高分子科学》2020,(3):231-239,I0005
Phosphazene base,t-BuP2,was employed to catalyze the proton transfer polymerization(PTP)of 2-hydroxyethyl acrylate(HEA),and PTP was further combined with ring-opening polymerization(ROP)to exploit a new type of hybrid copolymerization.The studies on homopolymerization showed that t-BuP2 was a particularly efficient catalyst for the polymerization of HEA at room temperature,giving an excellent monomer conversion.Throughout the polymerization,transesterification reactions were unavoidable,which increased the randomness in the structures of the resulting polymers.The studies on copolymerization showed that t-BuP2 could simultaneously catalyze the hybrid copolymerization via the combination of PTP and ROP at 25°C.During copolymerization,HEA not only provided hydroxyl groups to initiate the ROP ofε-caprolactone(CL)but also participated in the polymerization as a monomer for PTP.The copolymer composition was approximately equal to the feed ratio,demonstrating the possibility to adjust the polymeric structure by simply changing the monomer feed ratio.This copolymerization reaction provides a simple method for synthesizing degradable functional copolymers from commercially available materials.Hence,it is important not only in polymer chemistry but also in environmental and biomedical engineering. 相似文献
92.
Zhennan Wu Qiaofeng Yao Osburg Jin Huang Chai Nan Ding Wen Xu Shuangquan Zang Jianping Xie 《Angewandte Chemie (International ed. in English)》2020,59(25):9934-9939
Aggregation‐induced emission (AIE) provides an efficient strategy to synthesize highly luminescent metal nanoclusters (NCs), however, rational control of emission energy and intensity of metal NCs is still challenging. This communication reveals the impact of surface AuI‐thiolate motifs on the AIE properties of Au NCs, by employing a series of water‐soluble glutathione (GSH)‐coordinated Au complexes and NCs as a model ([Au10SR10], [Au15SR13], [Au18SR14], and [Au25SR18]?, SR=thiolate ligand). Spectroscopic investigations show that the emission wavelength of Au NCs is adjustable from visible to the near‐infrared II (NIR‐II) region by controlling the length of the AuI‐SR motifs on the NC surface. Decreasing the length of AuI‐SR motifs also changes the origin of cluster luminescence from AIE‐type phosphorescence to Au0‐core‐dictated fluorescence. This effect becomes more prominent when the degree of aggregation of Au NCs increases in solution. 相似文献
93.
A combination of fluorobenziodoxole (FBX) and BF3 ? OEt2 in cyclopentyl methyl ether promotes regio‐ and stereoselective addition of benziodoxole and methoxy groups to alkynes. This difunctionalization reaction tolerates a variety of functionalized internal and terminal alkynes to afford trans‐β‐alkoxyvinylbenziodoxoles, which represent versatile precursors to stereochemically well‐defined multisubstituted vinyl ethers. The reaction is proposed to involve cleavage of the I?F bond of FBX by BF3, followed by electrophilic activation of the alkyne by the resulting cationic IIII species that triggers the nucleophilic addition of the ethereal oxygen. 相似文献
94.
风机大型化是我国海上风电技术发展的重要方向. 东南沿海是我国海上风电发展的重要基地, 这一区域频繁发生的台风对海上风机的影响不可忽略. 台风风场与常规大风风场有不同的湍流特性, 同时台风期间较高的风速会引起巨大的台风浪. 本文考虑台风经过期间独特的风场及波浪场, 开展风浪联合作用对大型单桩海上风机影响的研究. 基于DTU 10 MW大型单桩风机, 运用一体化分析软件SIMA建立风浪联合作用下大型单桩风机的耦合数值模型, 研究台风经过不同阶段大型风力机的动力响应特性. 计算结果显示, 叶片变桨能有效降低台风经过时风机叶片所受风载荷, 变桨状态下单桩风机所受风载荷主要来源于塔筒. 在台风经过的不同阶段, 大型单桩海上风机结构表现出不同的动力特性. 台风全过程塔筒运动均受波浪激发一阶频率控制, 塔基上方结构动力载荷以惯性载荷为主, FOVS至FEWS阶段及BOVS阶段至BEWS阶段塔筒运动一阶频率处响应能量增长较小, 响应能量向低频及波频转移. 塔基下方泥面线处剪力响应受波频控制, 弯矩响应受一阶频率控制. 相似文献
95.
Nonlinear Dynamics - During the process of spacecraft launch, the extreme vibration environment is the major influence factor that induces the failure of the mission. Inspired by the smooth motions... 相似文献
96.
Lin Yan Wengang Chai Guanghui Wang Guanli Wu Kaijuan Lu Yue Luo 《Journal of mass spectrometry : JMS》1987,22(5):279-282
During a comparison study of the fast atom bombardment (FAB) and electron impact mass spectra of 1-organyl-2,9,10-trioxa-6-aza-1-silatricyclo[4.3.3.01,6]dodecanes, an unusual ion peak at m/z 164 was noticed in the FAB spectra. Accurate mass measurement indicated that m/z 164 corresponds to protonated 1-[N,N-bis(2-hydroxyethyl)amino]-1-propanol (BHAP), which is produced by a ring-rupture reaction. Further experiment showed that the intensity of the [BHAP + H]+ ion peak increased markedly as the 7keV Ar0 bombardment proceeded, suggesting a FAB-induced reaction. The possible mechanism is also discussed. 相似文献
97.
Measuring the fermion Yukawa coupling constants is important for understanding the origin of the fermion masses and their relationship with spontaneously electroweak symmetry breaking.In contrast,some new physics(NP)models change the Lorentz structure of the Yukawa interactions between standard model(SM)fermions and the SM-like Higgs boson,even in their decoupling limit.Thus,the precise measurement of the fermion Yukawa interactions is a powerful tool of NP searching in the decoupling limit.In this work,we show the possibility of investigating the Lorentz structure of the bottom-quark Yukawa interaction with the 125 GeV SM-like Higgs boson for future e^+e^- colliders. 相似文献
98.
99.
分别采用514 nm绿光、488 nm蓝光和390 nm紫外光作为敏化光,633 nm红光作为记录光,详细研究了敏化光波长对氧化(Fe,Ni):LiNbO3晶体全息记录性能的影响.结果表明:随着敏化光波长的逐渐减小,氧化(Fe,Ni):LiNbO3晶体的非挥发全息记录性能逐渐优化,390 nm紫外光是这三种敏化光中最优的敏化光.考虑敏化光的吸收,为了在双中心全息记录中获得最优的性能,应当选择合适波长的敏化光:一方面短波长敏化光能有效地敏化深中心;另一方面短波长敏化光的吸收太强(如对光折变效应无用的基质吸收),不能沿厚度方向有效地敏化晶体,所以实际上需折衷考虑,并从理论上给予了解释. 相似文献
100.
本文研究了在股本稀释效应下认股权证的定价问题.假设随机利率服从Vasicek模型,利用Δ-对冲方法建立了权证价格所满足的偏微分方程.然后,通过计价单位变换,将偏微分方程降维,求得了权证价格的显式解,并给出了一种较好的数值计算方法,可运用市场的可观测变量来计算权证价值. 相似文献