离子液体辅助合成AuPd纳米海绵及催化性能

在功能化离子液体氯化1-羟乙基-3-甲基咪唑([HEmim]Cl)辅助下, 在室温水溶液中一步快速合成了具有多孔海绵状结构的AuPd纳米材料. 通过场发射扫描电子显微镜(FESEM)、 透射电子显微镜(TEM)、 X射线能谱(EDX)和X射线衍射分析(XRD)等对该材料进行了表征. 结果表明, AuPd纳米海绵为合金结构, 由表面粗糙的纳米颗粒聚集熔接而成. 采用不同摩尔比(3∶1, 1∶1或1∶3)的前驱物HAuCl₄和Na₂PdCl₄均可制备出海绵状AuPd合金结构. 离子液体对AuPd纳米海绵状结构的形成起关键作用. 在对硝基苯酚还原反应中, 不同组成的AuPd纳米海绵均表现出比商用Pd/C催化剂更优异的性能. 其中, Au₁Pd₃纳米海绵具有最高的催化活性, 反应在98 s内即可完成, 反应速率常数为0.0143 s ^-1, 是商用Pd/C的2.3倍. 该方法也可用于制备其它双金属(如PdCu, PtCu等)和多金属纳米海绵.     

具有分支电路的可控压电阻尼减振技术

对近10年来国内外关于具有分支电路的可控压电阻尼减振技术研究的进展进行了较为详细的评述和讨论.文中首先说明了具有分支电路的压电阻尼减振技术的基本原理和基本形式,然后较为全面的评述不同形式基本分支电路压电阻尼系统的基本特点和研究进展,在讨论了以基本分支电路压电阻尼系统为基础的各种具有可控特性的分支电路压电阻尼系统(包括半主动的和主动-被动杂交的分支电路压电阻尼系统)的研究与发展之后,说明了这种技术在实际工程中的应用,最后建议了今后应深入研究的问题.      

Novel correction method for X-ray beam energy fluctuation of high energy DR system with a linear detector

A high energy digital radiography (DR) testing system has generated diverse scientific and technological interest in the field of industrial non-destructive testing. However, due to the limitations of manufacturing technology for accelerators, an energy fluctuation of the X-ray beam exists and leads to bright and dark streak artifacts in the DR image. Here we report the utilization of a new software-based method to correct the fluctuation artifacts. The correction method is performed using a high pass filtering operation to extract the high frequency information that reflects the X-ray beam energy fluctuation, and then subtracting it from the original image. Our experimental results show that this method is able to rule out the artifacts effectively and is readily implemented on a practical scanning system.     

Design,synthesis and in vivo anti-hyperglycemic activity of gem-dimethyl-bearing C-glucosides as SGLT2 inhibitors

A series of gem-dimethyl-bearing C-glucosides were designed and synthesized as SGLT2 inhibitors,with anhydrous aluminum chloride-mediated Friedel-Crafts alkylation to construct the gem-dimethyl functionality being the key step.The in vivo anti-hyperglycemic activity was evaluated with mice oral glucose tolerance test(OGTT),and all the synthesized compounds showed significant but less potent anti-hyperglycemic activity than the positive control dapagliflozin.     

Chemical composition of PM_(2.5) during winter in Tianjin,China

PM2.5 samples for 24 h were collected during winter in Tianjin,China. The ambient mass concentration and chemical composition of the PM2.5 were determined. Ionic species were analyzed by ion chromatog-raphy,while carbonaceous species were determined with the IMPROVE thermal optical reectance(TOR) method,and inorganic elements were measured by inductively coupled plasma-atomic emission spec-trometer. The daily PM2.5 mass concentrations ranged from 48.2 to 319.2 g/m3 with an arithmetic average of 144.6 g/m3. ...     

Structure of the even-even ~(78-84)Kr isotopes within SD-pair shell model

The collective properties in the even-even 78-84Kr isotopes have been studied within the framework of the SD-pair shell model.It is found that the collectivity of low-lying states in the even-even Kr isotopes can be described very well.     

离心式冷水空调机组中CFC11替代工质的研究

对几种 HFCs、HFEs 类新工质和混合工质M1、M2进行了以在离心式冷水空调机组中替代 CFC11为目标的理论循环性能分析。结果表明,M1具有作为 CFC11 灌注式替代物的潜力;HFC143 循环性能优良,更适合应用于新设计的系统中。     

多信息输出位移传感器

本文提出一种用于空间自由曲面测量的多信息输出位移传感器.该传感器结构简单,传感器的输出量与被测量成线性关系,不但能给出位移信息、倾斜角度,还能给出测量光的强弱信息.     

Operatorenkalkül über freien Monoiden III: Lagrangeinversion und Sheffersysteme

In this part the relations between the theory of binomial systems for noncommuting variables (of part II) and the results ofRota, Cigler et al. for the commutative case are studied in some detail. Afterwards for binomial systems of diagonal type there are given generalizations of the Rodrigues formula and the theorem ofLagrange-Good. A short development of Sheffer sequences follows. Finally the results are extended to binomial systems the structure of which is determined by any partial order of linear type.     

MODIFIED APPROXIMATE PROXIMAL POINT ALGORITHMS FOR FINDING ROOTS OF MAXIMAL MONOTONE OPERATORS

§1　Introduction and preliminariesA set T Rn×Rnis called a monotone operator on Rn,if T has the property(x,y) ,(x′,y′)∈T 〈x -x′,y -y′〉≥0 ,where〈·,·〉denotes the inner product on Rn.T is maximal if(considered as a graph) itis not strictly contained in any other monotone operator on Rn.It is well known that thetheory of maximal monotone operators plays an important role in the study of convexprogramming and variational inequalities since itcan provide a powerful general framework…