大孔交联聚苯乙烯的分形结构研究

采用小角Ｘ－射线散法测定大孔交联聚苯乙烯树脂的结构,发现大多数大孔交联聚苯乙烯在数纳米至数十纳米的标度尺寸范围内具有分形结构,分形维数介于２和３之间。本研究还进一步探讨了交联度、致孔剂,功能基化反应及后处理对大孔交联聚苯乙烯分形结构的影响。     

DEGENERATE OPTIMAL BASIS GRAPHS IN LINEAR PROGRAMMING

§ 1　IntroductionA graph-theoretic approach for investigating basis transformations in a linear pro-gramming has been historically developed.Let V be the setof all bases with respectto thecolumn vectors of a matrix A.Two bases are called adjacentifthey can be transformed intoeach other by a pivot operation.Denote by E the set of edges each of which is incidentwith a pair of adjacentbases.Then G=(V,E) is called the basisgraph of matrix A(or ofthe corresponding LP) .Tucker[1 ] first called…     

沿齐次曲线的强奇异积分算子在调幅空间上的有界性

设Γ_θ(t)为R~n(n≥2)中的齐次曲线,定义沿齐次曲线的强奇异积分算子T_(n,α,β)f(x)=p.v.∫_(-1)~1f(x-Γ_θ(t))(e~((-2πi|t|)~(-β))/(t|t|~α))dt,α,β>0.本文讨论了上述奇异积分算子在广义调幅空间上的有界性.     

MODIFIED APPROXIMATE PROXIMAL POINT ALGORITHMS FOR FINDING ROOTS OF MAXIMAL MONOTONE OPERATORS

§1　Introduction and preliminariesA set T Rn×Rnis called a monotone operator on Rn,if T has the property(x,y) ,(x′,y′)∈T 〈x -x′,y -y′〉≥0 ,where〈·,·〉denotes the inner product on Rn.T is maximal if(considered as a graph) itis not strictly contained in any other monotone operator on Rn.It is well known that thetheory of maximal monotone operators plays an important role in the study of convexprogramming and variational inequalities since itcan provide a powerful general framework…     

EFFECT OF AMPHIPHILIC POLY (STYRENE-B-ETHYLENE OXIDE) DIBLOCK COPOLYMER INTERCALATED LAYERED SILICATE AS FILLER ON ACRYLONITRILE-BUTADIENE-STYRENE RESIN

1.INTRODUCTION[()-227.3()]Polymer/layeredsilicatenanocompositeshavereceivedgreatattentioninrecentyearssincethesematerialsexhibitunexpectedimprovementinstiffness,strengthandbarrierpropertiesbyaddingonlyafewweightpercentagesoforganicsmodifiedlayeredsilicatesdispersedinthenanometerscaleinthepolymermatrix[1~10].Montmorilloniteinnatureconsistsmainlyoflayeredsilicatecarryingnegativechargesthatformionicbondswithmetalcationsintheintergalleryofthelayeredsilicates.Thesesilicatesalsocontaindanglinghy…     

离子交换法从N-Ac-DL-Methionine的酶拆分液中分离制备L-Methionine和N-Ac-D-Methionine

依据N-Ac-DL-Methionine的酶拆分液及其组分特有的性质，采用强酸型阳离子交换柱成功地将拆分液中各组分进行分组．分析了流出液的pH和L-Met浓度的变化规律和原因；讨论并确定了柱的交换容量与所加拆分液中钠的含量的最佳比值范围．本实验方法不仅可以获得L-Met，且兼得N-Ac-D-Met，二者的收率在小试中分别达到85％以上75％左右．     

A Concise Total Synthesis of S-（＋）-Tylophorine

A highly efficient total synthesis of S-( )-tylophorine has been accomplished in fully asymmetric fashion.     

活性氧化铝的衍射线宽化和结构缺陷

从不同的氧化铝水合物加热脱水制备的γ和η型氧化铝,广泛用作催化剂和催化剂载体。它们具有不同的物化性质,其微观结构已进行了很多研究。γ-和η-Al_2O_3的x射线衍射有两个特征:一是其整个衍射图非常类似于尖晶石类结构的衍射图;二是各衍射线具不同的宽化特征:即所有衍射线可分成宽散线和较尖锐线两大组。根据前者,γ-和η-Al_2O_3被认为是具有畸变尖晶石结构,由于η-Al_2O_3的(400)和(440)单线在γ-Al_2O_3中变为双线,因而二     

火焰原子吸收间断雾化技术的研究及应用

本文综合评述了前人所用间断雾化的各种进样方式和装置,发现在采用峰值测量时,其灵敏度和精密度差别不大。这样,可以直接将喷雾毛细管瞬间(约3秒)插入试液,进行测定。本文对影响饱和量体积的各种因素进行了较详细的试验与对比,包括提升量的变化。喷雾响应时间,不同粘度,不同溶剂(水与有机)的影响。认为饱和量体积实质上取决于待测元素到达火焰和原子化平衡的时间,以及仪器的响应速度。本文还对高盐基体的测定,有机萃取直接FAAS测定,以及血清的测定进行了研究,发现间断雾化技术在这方面具有广泛的应用前景。