Electrochemical properties of niobium and phosphate doped spherical Li-rich spinel LiMn2O4 synthesized by ion implantation method

Spherical Li-rich lithium manganese oxide(LMO) spinel material was synthesized by an ion implanted method assisted by polyalcohol doped with Niobium and Phosphate simultaneously.The material was characterized by scanning electron microscopy,X-ray diffraction and BET specific surface area analysis.The electrochemical performances were investigated with galvanostatic techniques and cyclic voltammetry.The synthesis process was investigated with TG/DSC.The results show that the lithium ion can be immersed into the pore of manganese dioxide at a low temperature with the ion implanted method.The prepared materials have a higher discharge capacity and better crystallization than those prepared by solid phase method.The doped Nb can improve the capacity of the Li-rich LMO spinel and reinforce the crystal growth along(111) and(400) planes.The crystal grains show circular and smooth morphology,which makes the specific surface area greatly decreased.Phosphate-doped LMO spinel exhibits good high-rate capacity and structure stability.The prepared Li_(1.09)Mn_(1.87)Nb_(0.031)O_(3.99)(PO_4)_(0.021)delivers a discharge capacity of 119mAhg~(-1) at 0.2C(1C=148mAg~(-1)) and 112.8 mAhg~(-1) at 10 C,the discharge capacity retention reaches 98% at 1 ℃ after 50 cycles at 25 ℃ and 94% at 55 ℃.     

毫米波圆柱波导自由电子激光放大器的数值模拟

本文以单粒子理论为基础，在不计空间电荷效应的近似条件下推导了带轴向引导磁场的三维圆柱波导非线性模拟方程组。用CAGFEL程序计算、分析了在带入口区、常数摇摆器条件下两组不同物理参数的自由电子激光放大器的物理模型。计算结果可靠，物理图象合理。对于其中的第二组参数还着重考查了光波频率、输入功率和摇摆器场振幅改变对输出功率和效率的影响。上述这些计算结果对0．7MeV 自由电子激光放大器的设计和实验具有一定的参考价值。     

几种吸附剂对工业级粗四氢呋喃中丁醛的脱除效果研究

本文以硅藻土、分子筛、ＫＯＨ、ＮａＯＨ作为吸附剂,获得了脱除工业级粗四氢呋喃（ＴＨＦ）中丁醛的最佳温度为４８℃。在固定床反应器中,除醛以ＫＯＨ为佳,在釜式反应器中,以ＮａＯＨ为佳。     

Metrological role of neutron activation analysis. IA. Inherent characteristics of relative INAA as a primary ratio method of measurement

In a series of three papers, the inherent characteristics of relative instrumental neutron activation analysis (INAA) as a primary ratio method of measurement, the unique functions of parametric INAA as an ideal back-up method of the relative INAA, and the valuable role of INAA in characterization of sampling behavior of individual elements in certified reference materials (CRMs) will be discussed. In this paper, the first of the series, the uncertainty evaluation and the traceability of values measured by neutron activation analysis (NAA), especially instrumental NAA (INAA), will be described to demonstrate the method at its ”the state-of-the-art” level can meet CCQM criteria for a primary ratio method. The scope and examples will be given. Received: 19 March 2001 Accepted: 2 October 2001     

含氟体系中高性能T型分子筛膜的合成

含氟体系中,在负载晶种的大孔莫来石支撑体表面快速合成了高性能且取向生长的T型分子筛膜。采用XRD、SEM和MASNMR等手段对分子筛膜层和粉末进行表征。讨论了添加物、氟硅比、合成温度和合成时间等条件对膜生长与分离性能的影响,并阐述了含氟体系中T型分子筛膜快速晶化的机理。碱金属氟盐的加入促进了T型分子筛晶体层的晶化速率,并对晶体层形貌产生了一定的影响。膜应用于75℃、水/异丙醇（10：90,w/w）体系的平均渗透通量和分离因子分别为（4.91±0.18）kg·m^-2·h^-1和7060±1130。     

Exchange bias tuned by cooling field in La0.2Ca0.8MnO3 nanoparticles

We report the magnetic properties in the nanosized charge ordering manganite La_0.2Ca_0.8MnO₃ with an average particle size ～50 nm. The sample exhibits ferromagnetism at low temperatures. The exchange bias phenomenon is observed when the sample is cooled down in an external magnetic field. Moreover, the exchange bias field is dependent on the cooling field and shows a maximum of ～520 Oe under a cooling field ～5 kOe. The exchange bias effect can be attributed to the exchange coupling between the ferromagnetic shell and antiferromagnetic core. The decrease of exchange bias field in high cooling field can be attributed to the growth of ferromagnetic component under high cooling field.     

基于多角度偏振特性的云相态识别及验证

云相态识别是云参数研究的重要组成部分,为了有效识别水云和冰云,根据水云和冰云微物理性质的差别,研究了水云和冰云的单次散射特性,采用基丁倍加累加法的,人量辐射传输方程模拟了水云和冰云的多角度偏振特件.模拟结果表明,光谱的多角度偏振特件能够体现山水云粒子和冰云粒子微物理性质的差异,云在特定方向反射的偏振辐射强度对云相态非常敏感,可以用米进行云相念的识别,在模拟的基础上进行了云相态识别算法的研究,并利用多角度偏振卫星数据--POLDER 0.865μm通道数据进行了实例分析.识别结果与MODIS云相态产品及其1.38μm卷云榆测结果进行了比较.分析结果表明,基于多角度偏振特性云相态识别算法可以有效地进行云相态识别.     

The Synthesis of 1,4‐Bis[N‐(4/6‐Substituted Benzothiazole‐2‐yl)‐N′‐Glycosylguanidino]Benzenes

The starting material O‐protected glycosyl isothiocyanate ( 1?3 ) was refluxed with 1,4‐diaminobenzene in CHCl₃ under nitrogen atmosphere to give 1,4‐bis(N‐glycosyl)thioureidobenzene ( 4?6 ). Then 1,4‐bis[N‐(4/6‐substituted benzothiazole‐2‐yl)‐N′‐glycosylguanidino]benzenes ( 8a?8e , 9a?9e , 10a?10e ) were obtained in good yield by reaction of compounds ( 4?6 ) with 2‐amino‐4/6‐benzothizoles ( 7a?7e ) and HgCl₂ in the presence of TEA in DMF. The structures of all 18 new compounds were confirmed by IR, ¹H NMR, LC‐MS and elemental analysis. The bioactivity of anti‐HIV‐1 protease (HIV‐1 PR) and against angiotensin converting enzyme (ACE) have been evaluated.     

模糊层次分析法及其在优化建材连锁配送方案中的应用

本文首先说明模糊ＡＨＰ方法是在传统的ＡＨＰ方法的基础上，考虑到人们对复杂事物判断的模糊性，提出程度分析和综合决策理论，并介绍了模糊ＡＨＰ方法的主要理论及步骤。最后把它用于建材连锁配送系统模式的评价，可将专家对诸方案指标体系所进行的带有模糊性判断，通过定量计算，转化为对连锁配送系统模式的排序，从而达到选优的目的。     

中药片仔癀,六味地黄丸中的微量铬,铅和镉石墨炉原子吸收法测定

本文采用ＧＦ－ＡＡＳ加平台技术，基体改进剂，测定了中药片仔癀，六味地黄丸中铬、铅和镉的含量，铬、铅和镉的线性范围分别为０－０．８ｎｇ／ｍＬ，０－５０ｎｇ／ｍＬ，０－５ｎｇ／ｍＬ，回收率分别为１０２－１０３％，９９－１０１％，９７．５－９８％，本方法简便快速、准确。