排序方式: 共有33条查询结果,搜索用时 15 毫秒
21.
V. C. Adya A. Sengupta B. A. Dhawale B. Rajeswari S. K. Thulasidas S. V. Godbole 《Journal of Radioanalytical and Nuclear Chemistry》2012,291(3):843-848
Trace metallic impurity analysis by spectroscopic techniques is one of the important steps of chemical quality control of
nuclear fuel materials. Depending on the burn-up and the storage time of the fuel, there is an accumulation of 241Am in plutonium based fuel materials due to β decay of 241Pu. In this paper, attempts were made to develop a method for separation of 241Am from 1.2 kg of analytical solid waste containing 70% U, 23% Pu, 5% Ag and 1–2% C as major constituents along with other
minor constituents generated during trace metal assay of plutonium based fuel samples by d. c. arc carrier distillation atomic
emission spectrometry. A combination of ion exchange, solvent extraction and precipitation methods were carried out to separate
~45 mg of 241Am as Am(NO3)3 from 15 L of the analytical waste solution. Dowex 1×4 ion exchange chromatographic method was used for separation of Pu whereas
30% TBP–kerosene was utilized for separation of U. Am was separated from other impurities by fluoride precipitation followed
by conversion to nitrate. The recovery of Pu from ion exchange chromatographic separation step was ~93% while the cumulative
recovery of Am after separation process was found to be ~90%. 相似文献
22.
Determination of metallic impurities in U3O8 using energy dispersive X-ray fluorescence spectrometry
V. Natarajan B.A. DhawaleB. Rajeswari N.S. HonS.K. Thulasidas N.K. PorwalS.V. Godbole V.K. Manchanda 《Spectrochimica Acta Part B: Atomic Spectroscopy》2008
In order to examine the capability of energy dispersive X-ray fluorescence spectrometry for the determination of some common metallic impurities in nuclear grade U3O8 matrix, a series of synthetic U3O8 standards, containing impurities such as Ca, Co, Cr, Cu, Fe, Mn, Mo, Ni ,V, W and Zn in the concentration range, 100–1000 μg/g, were prepared. Using these standards, calibration curves were set up for different elements after optimizing the spectrometer parameters. Two synthetic samples and five reference standards obtained through an inter-laboratory comparison exercise within analytical laboratories of Department of Atomic Energy, India were analyzed to evaluate the performance of the newly developed analytical methods. The estimates for most of the analytes were in good agreement with the added amounts. The method is fast, since it requires no chemical treatment. The method has good precision for the analytes determined. 相似文献
23.
Madhuri J. Kulkarni Aparna A. Argekar S. K. Thulasidas A. G. Page M. D. Sastry 《Fresenius' Journal of Analytical Chemistry》1992,342(4-5):367-369
Summary An inductively coupled argon plasma-atomic emission spectrometric (ICP-AES) method has been developed for the direct determination of metallic constituents of high-critical temperature (Tc) superconducting materials with a precision of better than 2%. The typical sample matrices are YBa2Cu3O7–x, Bi2CaSr2Cu2O8 and TlBa2Ca2Cu3O8.5 and also with substitution at significant concentrations of elemental Fe, Gd, K, La, Mg, Na, Sn and Tm. The detection limits for these elements vary in the range 0.01–0.1 g/ml. The method is based on dissolution of the solids and analysis of 1 mg/ml aliquot of the samples. Apart from optimisation of experimental parameters, the method also involves inter-element interference studies. It has been successfully applied for the chemical characterisation of a variety of oxide-based superconducting materials. 相似文献
24.
Fulton R Hempstead M Jensen T Johnson DR Kagan H Kass R Morrow F Whitmore J Wilson P Chen W McIlwain RL Miller DH Ng CR Schaffner SF Shibata EI Yao W Sparks K Thorndike EH Wang C Brock IC Ferguson T Alam MS Kim IJ Li WC Lou XC Sun CR Wang P Zoeller MI Bortoletto D Goldberg M Horwitz N Jain V Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Thulasidas M Csorna SE Letson T Alexander J Artuso M Bebek C Berkelman K Cassel DG Cheu E Coffman DM Crawford G DeWire JW Drell PS Ehrlich R Galik RS 《Physical review letters》1990,64(1):16-20
25.
Butler F Fu X Kalbfleisch G Lambrecht M Ross WR Skubic P Snow J Wang PL Wood M Bortoletto D Brown DN Fast J McIlwain RL Miao T Miller DH Modesitt M Schaffner SF Shibata EI Shipsey IP Wang PN Battle M Ernst J Kroha H Roberts S Sparks K Thorndike EH Wang CH Dominick J Sanghera S Skwarnicki T Stroynowski R Artuso M He D Goldberg M Horwitz N Kennett R Moneti GC Muheim F Mukhin Y Playfer S Rozen Y Stone S Thulasidas M Vasseur G Zhu G Bartelt J Csorna SE Egyed Z Jain V Sheldon P Akerib DS Barish B 《Physical review D: Particles and fields》1994,49(1):40-57
26.
Artuso M Goldberg M He D Horwitz N Kennett R Mountain R Moneti GC Muheim F Mukhin Y Playfer S Rozen Y Stone S Thulasidas M Vasseur G Xing X Zhu G Bartelt J Csorna SE Egyed Z Jain V Kinoshita K Barish B Chadha M Chan S Cowen DF Eigen G Miller JS O'Grady C Urheim J Weinstein AJ Acosta D Athanas M Masek G Paar HP Sivertz M Gronberg J Kutschke R Menary S Morrison RJ Nakanishi S Nelson HN Nelson TK Qiao C Richman JD Ryd A Tajima H Sperka D Witherell MS Procario M Balest R Cho K Daoudi M Ford WT 《Physical review letters》1994,72(24):3762-3766
27.
Mithlesh Kumar V. C. Adya B. Rajeswari S. K. Thulasidas R. M. Kadam 《Journal of Radioanalytical and Nuclear Chemistry》2017,312(3):587-597
In view to separate La(III), Pr(III) and U(VI) ions, from aqueous solutions, batch experiments are carried out for the sorption and desorption of these ions onto and from a novel functionalized resin. The sorption capacities varied from 1.06 to 47.30 mg/g and increased in the following order La(III), Pr(III) and U(VI), while yields desorption ranged from 73.0 to 94.3% and increased in the following order Pr(III), La(III) and U(VI). Considering the largest difference in sorption capacity and desorption yield of these three elements, at different operates conditions, this material can be potential candidate for the separation of U(VI), Pr(III) and La(III) ions from nuclear and other industrial wastewater. 相似文献
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29.
Dominick J Sanghera S Shelkov V Skwarnicki T Stroynowski R Volobouev I Zadorozhny P Artuso M He D Goldberg M Horwitz N Kennett R Moneti GC Muheim F Mukhin Y Playfer S Rozen Y Stone S Thulasidas M Vasseur G Zhu G Bartelt J Csorna SE Egyed Z Jain V Sheldon P Akerib DS Barish B Chadha M Chan S Cowen DF Eigen G Miller JS O'Grady C Urheim J Weinstein AJ Acosta D Athanas M Masek G Paar H Sivertz M Bean A Gronberg J Kutschke R Menary S Morrison RJ Nakanishi S Nelson HN Nelson TK Richman JD Ryd A 《Physical review D: Particles and fields》1994,50(7):4265-4271
30.
Lepton asymmetry measurements in B-bar-->D*l- nu -barl and implications for V-A and the form factors
Sanghera S Skwarnicki T Stroynowski R Artuso M Goldberg M Horwitz N Kennett R Moneti GC Muheim F Playfer S Rozen Y Rubin P Stone S Thulasidas M Yao W Zhu G Barnes AV Bartelt J Csorna SE Egyed Z Jain V Sheldon P Akerib DS Barish B Chadha M Cowen DF Eigen G Miller JS Urheim J Weinstein AJ Acosta D Masek G Ong B Paar H Sivertz M Bean A Gronberg J Kutschke R Menary S Morrison RJ Nelson H Richman J Tajima H Schmidt D Sperka D Witherell M Procario M Daoudi M Ford WT Johnson DR Lingel K Lohner M 《Physical review D: Particles and fields》1993,47(3):791-798