Flux line lattice symmetries in the borocarbide superconductor LuNi2B2C

We compare the results of small angle neutron scattering on the flux line lattice (FLL) obtained in the borocarbide superconductor LuNi₂B₂C with the applied field along the c- and a-axes. For H‖c the temperature dependence of the FLL structural phase transition from square to hexagonal symmetry was investigated. Above 10 K the transition onset field. H ₂(T), rises sharply, bending away from H _c2(T) in contradiction to theoretical predictions of the two merging. For H‖a a first order FLL reorientation transition is observed at H _tr=3–3.5 kOe. Below H _tr the FLL nearest neighbor direction is parallel to the b-axis, and above H _tr to the c-axis. This transition cannot be explained using nonlocal corrections to the London model.     

Vortex mass in a superfluid at low frequencies

An inertial mass of a vortex can be calculated by driving it around in a circle with a steadily revolving pinning potential. We show that in the low-frequency limit this gives precisely the same formula that was used by Baym and Chandler, but find that the result is not unique and depends on the force field used to cause the acceleration. We apply this method to the Gross-Pitaevskii model, and derive a simple formula for the vortex mass. We study both the long-range and short-range properties of the solution. We agree with earlier results that the nonzero compressibility leads to a divergent mass. From the short-range behavior of the solution we find that the mass is sensitive to the form of the pinning potential, and diverges logarithmically when the radius of this potential tends to zero.     

H-transfer rates in ion-neutral complexes versus those in intact aliphatic ions

The relative rates of H-transfer between partners in ion-neutral complexes were compared with those in intramolecular rearrangements using results of first differential photoionization mass spectrometry measurements. Complex-mediated H-transfers are inferred to have rates of the same order as those for intramolecular hydrogen rearrangements, suggesting a similar range of motion of the reactive sites in both types of reactions. It is also concluded that at their fastest H-transfers take place between the partners in ion-neutral complexes within at most the time of several rotations of the partners in the complexes. Copyright 1999 John Wiley & Sons, Ltd.     

New high-energy luminescence bands from Co2+ in ZnSe

Three sharp absorption features in the energy range 2.36–2.55 eV have been detected in the transmission spectrum of Co-diffused ZnSe, and a number of luminescence transitions originating from the lowest of these states at 2.361 eV have been observed. Photoluminescence excitation spectra prove that these are high energy excited states of the Co²⁺_Zn impurity, a conclusion confirmed by comparison of measured and predicted luminescence energies. This represents the first identification of luminescence branching from a higher excited state of a transition metal ion in any semiconductor. The sharp, weakly phonon-coupled transitions involve either intra-impurity excitation or transitions from the impurity to localised states split off from a minimum in the conduction band. The implications of these observations for the mechanism of host-impurity energy transfer and for the nature of the excited state wavefunctions are discussed.     

A mean field spin glass with short-range interactions

We formulate and study a spin glass model on the Bethe lattice. Appropriate boundary fields replace the traditional self-consistent methods; they give our model well-defined thermodynamic properties. We establish that there is a spin glass transition temperature above which the single-site magnetizations vanish, and below which the Edwards-Anderson order parameter is strictly positive. In a neighborhood below the transition temperature, we use bifurcation theory to establish the existence of a nontrivial distribution of single-site magnetizations. Two properties of this distribution are studied: the leading perturbative correction to the Gaussian scaling form at the transition, and the (nonperturbative) behavior of the tails.Research supported by the NSF under Grant No. DMR-8314625Research supported by the DOE under Grant No. DE-AC02-83ER13044Research supported by the NSF under Grant No. DMR-8503544Research supported by the NSF under Grant No. DMR-8319301