Analysis of HRTEM images for carbon nanostructure quantification

Image processing algorithms have been developed to extract fringe length, tortuosity and separation from high resolution transmission electron microscopy images. To validate the separation algorithm, a comparison is made between the image-based fringe separation and that obtained by analysis of X-ray diffraction data for a progressively heat-treated carbon black. Agreement is favorable. To illustrate the utility of the analysis parameters for a range of carbon nanostructures, analysis is applied to a series of pyrolytically prepared carbon soots – qualitatively described as containing amorphous, graphitic or fullerenic nanostructure. For all processing, the intermediate image, in the form of a skeletonized binary image of the original high resolution transmission electron micrograph, is shown and found to accurately reflect the nanostructural organization within the carbon as visually observed. Statistical results for each analysis parameter, extracted from the binary images, are presented in the form of histograms and quantitatively distinguish the different carbon nanostructures.     

A comparison of a theoretical model for quasi-statically and dynamically induced environmental vibration from trains with measurements

This paper presents comparisons between a theoretical ground vibration model and measured data at three sites. The model, which is briefly outlined here, encompasses both the quasi-static and dynamic mechanisms of excitation. The vertical dynamics of a number of vehicles travelling at a constant speed on an infinite track are coupled to a semi-analytical model for a three-dimensional layered ground. This model is also used to demonstrate the roles of the two components of vibration at different frequencies and for train speeds below and above the lowest ground wave speed. It is found that, in most practical cases, the dynamic component gives rise to the higher level of vibration.     

Radiation efficiency of unbaffled and perforated plates near a rigid reflecting surface

The accurate prediction of sound radiation from plate-like structures remains a challenging problem. Although the case of a plate set in a rigid baffle can be solved analytically, when the plate radiates sound into free space the problem is more difficult to solve; nevertheless, several approaches have been proposed to determine the sound radiation from an unbaffled plate. The present study extends the consideration to the situation of an unbaffled plate which is located close to a rigid reflecting surface. For this purpose, Laulagnet's model for the radiation efficiency of an unbaffled plate is extended by modifying the Green's function to include an image source due to the reflecting surface. The results show that, depending on the distance between the plate and the rigid surface, the radiation efficiency is considerably reduced at low frequencies. Additional reduction of sound radiation can be achieved by introducing perforation to the plate. However, at higher frequencies, the radiation efficiency is amplified relative to that for the plate in the absence of the rigid surface, both with and without perforation. These results have also been validated experimentally.     

Enhanced reactivity of nanoscale iron particles through a vacuum annealing process

A reactivity study was undertaken to compare and assess the rate of dechlorination of chlorinated aliphatic hydrocarbons (CAHs) by annealed and non-annealed nanoscale iron particles. The current study aims to resolve the uncertainties in recently published work studying the effect of the annealing process on the reduction capability of nanoscale Fe particles. Comparison of the normalized rate constants (m²/h/L) obtained for dechlorination reactions of trichloroethene (TCE) and cis-1,2-dichloroethene (cis-1,2-DCE) indicated that annealing nanoscale Fe particles increases their reactivity ~30-fold. An electron transfer reaction mechanism for both types of nanoscale particles was found to be responsible for CAH dechlorination, rather than a reduction reaction by activated H₂ on the particle surface (i.e., hydrogenation, hydrogenolysis). Surface analysis of the particulate material using X-ray diffraction (XRD) and transmission electron microscopy (TEM) together with surface area measurement by Brunauer, Emmett, Teller (BET) indicate that the vacuum annealing process decreases the surface area and increases crystallinity. BET surface area analysis recorded a decrease in nanoscale Fe particle surface area from 19.0 to 4.8 m²/g and crystallite dimensions inside the particle increased from 8.7 to 18.2 nm as a result of annealing.     

Quantitative measurements of Ge surface segregation during SiGe alloy growth

Ge segregation during the growth of Si_{1 − x}Ge_x alloys (x = 5, 10, 20, and 40%) was studied using X-ray photoelectron spectroscopy. The alloys were grown in thicknesses up to 20.0 nm at 500°C to measure quantitatively the amount of segregated surface Ge. The length of alloy needed to reach steady-state growth edge was found to decrease with increasing alloy concentration (4.8, 2.8, 2.4, and 2.0 nm, respectively). It was found that each alloy had a complete monolayer of Ge on the surface and an increasing amount of segregated Ge in the second layer (20, 55, 80, and 95%, respectively) during steady-state growth. An increase in the temperature of alloy growth (400–750°C) resulted in an increase in the leading edge of alloy growth but did not change the amount of segregated Ge during steady-state growth. We propose that film stress is responsible for the amount of Ge segregation.     

Analytical comparison between the surface current integral equation and the second-order small-slope approximation

This paper is the third in a series discussing a new approximate bistatic model for electromagnetic scattering from perfectly conducting rough surfaces. Our previous approach supplemented the Kirchhoff model through the addition of new terms involving linear orders in slope and surface elevation differences that arise naturally from a second iteration of the surface current integral equation. This completion of the Kirchhoff was shown to provide the correct first-order small perturbation method (SPM-1) in the general bistatic context. The agreement with SPM-1 was achieved because differences of surface heights are no longer expanded in powers of surface slope. While consistent with SPM, our previous formulation fails to reconverge toward the Kirchhoff model, at some incidence and scattered angles, when the illuminated surface satisfies the high frequency roughness condition. This weakness is also shared with the first-order small slope approximation (SSA-1) which is structurally equivalent to our previous formulation where the polarization is independent of surface roughness. The second-order small slope approximation (SSA-2), which satisfies the SPM-1 and second-order small perturbation method (SPM-2) limits by construction, was shown by Voronovich to converge toward the tangent plane approximation of the Kirchhoff model under high frequency conditions. In the present paper, we show that, in addition to the linear orders in our previous model, one must now include cross-terms between slope and surface elevation to ensure convergence toward both high frequency and small perturbation limits. With the inclusion of these terms, our new formulation becomes comparable to the SSA-2 (second-order kernel) without the need to evaluate all the quadratic order slope and elevations terms. SSA-2 is more complete, however, in the sense that it guarantees convergence toward the second-order Bragg limit (SPM-2) in the fully dielectric case in addition to both SPM-1 and Kirchhoff. Our new generalization is shown to explain correctly extra depolarization in specular conditions to be caused by surface curvature and surface autocorrelation for incoherent and coherent scattering, respectively. This result will have large repercussions on the interpretation of bistatically reflected signals such as those from GPS.     

FePt L10 ordering and grain growth using millisecond pulse laser processing

The structural and magnetic properties of ∼12 nm thick FePt thin films grown on Si substrates annealed using a 1064 nm wavelength laser with a 10 ms pulse have been examined. The A1 to L1₀ ordering phase transformation was confirmed by electron and X-ray diffraction. An order parameter near 50% and a maximum coercivity of 12 kOe were obtained with laser energy densities of 25-32 J/cm². Grain growth, quantified by dark field transmission electron microscopy, occurred during chemical ordering at the laser pulse widths studied.     

Three-Body Spectrum of 18C and its Relevance to r-Process Nucleosynthesis

The ¹⁸C spectrum has been studied in a three body n + n +¹⁶C model that includes deformation and the 2⁺ excitation of the ¹⁶C core as well as Pauli projection of forbidden states. The ¹⁶C – n interaction employed in this study has been fitted to reproduce the experimental spectrum of ¹⁷C. The calculations show that two neutron separation energy in ¹⁸C in consistent with three-body structure of this nucleus and predict more states bound with respect to three-body decay. The comparison of their position to known excited states in ¹⁸C is discussed. These calculations suggest also that a few states may exist in astrophysically relevant region between the ¹⁷C+n and ¹⁶C + 2n decay thresholds. The most important of them is 1⁻ as it can give a large E1 resonant contribution to ¹⁷C(n, γ)¹⁸C neutron capture. The calculations also suggest that a virtual s-wave state may exist above the ¹⁷C + n threshold that can give rise to non-negligible M1 contributions to the ¹⁷C(n, γ)¹⁸C reaction rate. The presence of these states in the ¹⁸C spectrum can lead to an increased ¹⁷C(n, γ)¹⁸C reaction rate, which can significantly influence the abundances of uranium and thorium synthesized in the r-process in the supernovae explosions.     

Binaural processing of modulated interaural level differences

Two experiments are presented that measure the acuity of binaural processing of modulated interaural level differences (ILDs) using psychoacoustic methods. In both experiments, dynamic ILDs were created by imposing an interaurally antiphasic sinusoidal amplitude modulation (AM) signal on high-frequency carriers, which were presented over headphones. In the first experiment, the sensitivity to dynamic ILDs was measured as a function of the modulation frequency using puretone, and interaurally correlated and uncorrelated narrow-band noise carriers. The intrinsic interaural level fluctuations of the uncorrelated noise carriers raised the ILD modulation detection thresholds with respect to the pure-tone carriers. The diotic fluctuations of the correlated noise carriers also caused a small increase in the thresholds over the pure-tone carriers, particularly with low ILD modulation frequencies. The second experiment investigated the modulation frequency selectivity in dynamic ILD processing by imposing an interaurally uncorrelated bandpass noise AM masker in series with the interaurally antiphasic AM signal on a pure-tone carrier. By varying the masker center frequencies relative to the signal modulation frequency, broadly tuned, bandpass-shaped patterns were obtained. Simulations with an existing binaural model show that a low-pass filter to limit the binaural temporal resolution is not sufficient to predict the results of the experiments.     

Effects of applied DC/AC fields in electrical fixing process with SBN:60

We present experimental investigations of electrical fixing techniques in Ce:SBN:60. The effect of crystal fatigue on the diffraction efficiency of electrically fixed photorefractive gratings is studied. We observed that applying an ac field to the crystal eliminated crystal fatigue and improved diffraction efficiency. A controllable diffraction efficiency of a photorefractive grating is presented. A reproducible diffraction efficiency of up to 75% is obtained using a write-reveal grating technique with high-voltage pulses of opposite polarity. We also show that the diffraction efficiency can be controlled by varying the intensity of the writing beams incident to the crystal during the recording process. A method of determining the hysteresis loop using the domain-fixing technique is proposed. The dependence of the diffraction efficiency on the direction of the applied electric field while writing the hologram is studied. Our experiments show that, during writing, when the electric field is applied opposite to the c axis the grating can be successfully revealed with both positive and negative dc voltages. However, when the grating is written with a field parallel to the c axis, the grating can be revealed only with a field applied in the opposite direction. Received: 28 October 2002 / Revised version: 28 February 2003 / Published online: 14 May 2003 RID="*" ID="*"Corresponding author. Fax: +1-812/872-6167, E-mail: azad.siahmakoun@rose-hulman.edu