EPR Study of some Copper(II) Coordination Compounds with substituted Biguanides. III

Copper(II) coordination compounds with p-chlorphenylbiguanide of the type: [Cu(Cl-PhBig)₂]X₂ and [Cu(Cl–PhBig)X₂] with X =Cl^?, Br^? NO₃, OH^?, NCS^?, NCO^?, N₃, have been studied by EPR spectroscopy using polycrytalline powders and solutions in DMF. The parameters of the EPR spectra have been used to estimate molecular orbital coefficient, in these compounds and to discuss details of the chemical bonding.     

Reaction of tetrahydrofurfuryl alcohol with dimethylamine and/or hydrogen

Conclusions 1-Pentanol, 1-dimethylaminopentane or 4-penten-1-o1, 1-pentanol, and 1,5-pentanediol are the major products of the hydroamination of tetrahydrofurfuryl alcohol by dimethylamine and the hydrogenation of this alcohol on a promoted, fused reduced iron catalyst.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2847–2849, December, 1987.The authors express their gratitude to V. G. Zaikin and A. I. Mikaya for assistance in interpreting the mass spectral data.     

Researches on synthetic dyes

Reaction of phenyl-ß-naphthylamines with formaldehyde and acetone in the presence of HCl and nitrobenzene in butanol solution leads to cyclization involving the naphthalene and phenyl rings, and formation of N-aryllepidine salts. 15 lepidine and 5, 6-benzoepidine salts are synthesized and characterized by their UV absorption spectra, as well as by their picrates.For Part LIII see [3].     

Chemistry of 1,1,2,2-tetracyanoethane

Conclusions 1-(N,N-Dimethylhydrazino)-4-methyl-2,2,3,3-tetracyanocyclopentane is isomerized reverslbly in solution, with inversion of the configuration of the tetrahedral carbon atom in position 1.For previous communication, see [1].Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1075–1079, May, 1989.     

Crystal and molecular structure of 2-(2′-methylaminophenyl)-4H-3,1-benzoxazine-4-one

A planar structure for molecules of 2-(2-methylaminophenyl)-4H-3,1-benzoxazine-4-one was found by x-ray structural analysis. Shortening of the N-Ph bond and lengthening of the distance between amino- and azine-N atoms in comparison to the tosyl analog was demonstrated to lead to a bathochromic shift of the absorption spectrum and a hypsochromic displacement of the luminescence spectrum. As a result, the Stokes shift of 2-(2-methylaminophenyl)-4H-3,1-benzoxazine-4-one is smaller than that of 2-(2-tosylaminophenyl)-4H-3,1-benzoxazine-4-one. In the crystal, molecules of 2-(2-methylaminophenyl)-4H-3,1-benzoxazine-4-one are stacked with intermolecular interaction energy between molecules in the stack of –12.5 and –14.2 kcal/mole. The stacks are joined into layers parallel to (010).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1781–1785, August, 1989.     

Synthesis and crystal structure of 4-acetoxy-5,6-dihydro-5,5-dinitro-2H-1,3-oxazineN-oxide

A novel heterocyclic compound, 4-acetoxy-5,6-dihydro-5,5-dinitro-2H-1,3-oxazineN-oxide, has been synthesized by the reaction of the dipotassium salt of 1,1,5,5-tetranitro-3-oxapentane with aqueous acetic acid. The synthesized compound has been studied by X-ray diffraction analysis.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2207–2210, December, 1994.We would like to thank G. V. Lagodzinskaya (Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences) for recording and interpreting¹H NMR spectra, A. M. Korolev (Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences) for helpful discussion, and V. I. Fetisov (Institute of Physiologically Active Compounds, Russian Academy of Sciences) for performing quantum-chemical calculations by the AM1 SCF MO LCAO method.