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971.
GAN LiHua School of Chemistry Chemical Engineering Southwest University Chongqing China 《中国科学B辑(英文版)》2009,(5)
Based on the calculated findings that the sizes of encaged clusters determine the structures and the stability of C80-based trimetallic nitride fullerenes (TNFs), more extensive density functional theory calculations were performed on M3N@C68, M3N@C78 and M3N@C80 (M=Sc, Y and La). The calculated results demonstrated that the structures and stability undergo a transition with the increasing of the sizes of the cages and clusters. Sc3N is planar inside the three considered cages, Y3N is slightly pyramidal ins... 相似文献
972.
TIAN Qing-ping LI Peng XIE Ke-chang .Key Laboratory of Coal Science Technology Ministry of Education Shanxi Province Taiyuan University of Technology Taiyuan P.R.China 《高等学校化学研究》2009,25(1)
In order to solve the drawback of poor bioavailability by the oral route and infusion-related side effect for Amphotericin B(AmB), microemulsion vehicles composed of isopropyl myristate(IPM), Tween 80, isopropyl alcohol and water for transdermal delivery of AmB were designed. The pseudo-ternary phase diagrams were constructed by the H2O titration method and the structures of the microemulsion were determined by measuring electrical conducti-vities(σ). The diffusion studies of AmB microemulsion were performed via excised rabbit skin on a drug diffusion apparatus. To obtain a high solubization of AmB, three different methods were tested to incorporate AmB into mi-croemulsion. The result suggests adding AmB in the shape of NaOH solution to the O/W blank microemulsion over the phase inversion temperature(PIT) of the emulsifier obtains the maximum drug content(2.96 mg/mL). The pH value of the system could be adjusted to pH8.5 or pH<5.2, in this range AmB molecules converts from aqueous to the hydrophilic shell of the microemulsion droplets, drug precipitate is no more than 5%, and the formulations were corresponding to the characterizations of microemulsion. At pH 5.14, AmB microemulsion with Km 1:1, O/SC 1:9(mass ratio ofoil phase to surfactant/cosurfactant blend), water content 64.6%, drug content (2.93±0.08) mg/mL,showed the maximum permeation rate(3.255±0.64)μg·cm-2·h-1,which is stable for a long time. 相似文献
973.
Jian Ping LI* Qian Fu LUO Yi Yang SHEN Yu Lu WANG Hong WANG College of Chemistry Environmental Science Henan Normal University Xinxiang Department of Chemistry Luoyang Teacher''''s College Luoyang 《中国化学快报》2001,(2)
The subject of organic solid-state synthesis is a fascinating one. It has many advantages such as high efficiency and selectivity, easy separation and purification, mild reaction conditions, and environmental acceptability1. In recent years, this method has been widely used in a variety of organic reactions including substitution2, condensation3, oxidation-reduction4, rearrangement5 and elimination6. However, the solid state reaction using K3Fe(CN)6/KOH to oxidize substituted semicarbazides… 相似文献
974.
The enlargement of the emitting aperture is usually one of the important methods of increasing vertical- cavity surface-emitting laser (VCSEL) optical output power. However, in a VCSEL with a larger aperture, the inhomogeneity in the injected current often causes inhomogeneous or even no emission. To solve this problem and to increase VCSEL output power, as well as to improve its thermal characteristics, we develop a new type of injected VCSEL with a larger aperture and a reticular electrode, where the conventional circular injection electrode of the P side is turned into a reticular one, and the heat sink is on the N side. The tests of the new VCSEL show an improvement in homogeneity in not only the injected current but also the emission intensity. The optical output power is also considerably increased, and the device optoelectronic performance is improved. 相似文献
975.
A Novel Palladium-Catalyzed Reaction and Its Application in Preparation of Derivatives of Stilbazols
Zhi Yong WANG* Chao JIANG Ji Hui WU Qing Xiang GUO Dept. of Chem. University of Science & Technology of China Hefei 《中国化学快报》2001,(5)
Many derivatives of stilbazoles have strong biological activities and pharmacological actions. For instance, (-substituent-(E)-4-styrylpyridines can be used as cytokinin analogues1. A series of N-substituted tetrahydro (phenylethenyl) pyridine derivatives were reported in vitro against both nicotinic and muscarinic receptors derived from rat cerebral cortax2. Therefore they can be used as candidates to develop new drugs for treatment of some diseases. On the other hand, this kind of compounds… 相似文献
976.
Mei Zhong JIN Li YANG Long Ming WU You Chen LIU Zhong Li LIU* National Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 《中国化学快报》2001,(4)
Reduction of C=N double bonds has been recognized as an important reaction both in organic chemistry and bio-chemistry1. Hantzsch 1,4-dihydropyridine (HEH, one of NADH model compounds) has been reported as a reductive reagent for imines2. However, application of dihydropyridines as practical reducing reagents in organic synthesis is limited because of their instability3. Like NADH models, 2-phenyl-N, N-dimethylbenzimidazoline (PDMBI) is an efficient electron and hydrogen donor (Eox = 0… 相似文献
977.
978.
1 Besicovitch Inner ProductIll this paper, we consider Dirichlet serie8where an, tL = 1, 2,' ', are complex nunlbers. They are Besicovitch almost periodic functionsWe see the 8ystenl {e.(t); e.(t) = e--it Iog 1l, 71 = l, 2,' .} fOrnis a1l orthollor11la1 systelll witl1respect to tI1e BesicovitcI1 iIl1ler productThell we call fOrm the gelleralized trigouolnetrical polynolIlialsAccording to tl1e idea developed il1 [l],[2], auy Dirichlet seriesis weakly convergent over K witll respect to … 相似文献
979.
J. Badier M. Bardadin-Otwinowska C. Bemporad U. Berthon H. Bienvenu J. Boucrot J. Bourotte G. Burgun O. Callot Ph. Charpentier A. M. Cnops M. Cohen F. Constantini M. Crozon D. Décamp P. Delpierre J. F. Detoeuf P. Espigat B. Gandois G. R. Giannini V. Hajjar M. Hansroul Y. Karyotakis P. Lariccia P. Le D? J. Mas A. Michelini G. C. Moneti M. Moniez E. Paré G. Rahal-Callot M. Rumpf O. Runolfsson A. Tilquin S. Weisz NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1986,31(3):341-347
Direct photon production has been studied by an experiment performed with the NA3 spectrometer at CERN, using incident negative and positive beams at 200 GeV/c interacting with an isoscalar Carbon target. Two different triggers have been used; one of them requires the photon conversion. The experiment is sensitive to direct photons produced with 3.0≦P T ≦6 GeV/c and center-of-mass rapidity ?0.4≦y *≦1.2. Inclusive cross sections are given for incident π± and protons, and compared with second order QCD predictions; finally an estimation of the gluon structure function of the nucleon is given. 相似文献
980.
Synthesis and Characterization of A Novel Cholesteric Liquid Crystalline Containing Carboxyl Group 总被引:1,自引:0,他引:1
JingMA YingNanXUAN YongHUANG 《中国化学快报》2005,16(1):127-130
A novel liquid crystal compound with a carboxyl group at one end, cholest-5-en-3-ol-(3β) hydrogen decanedioate (1) was successfuly prepared by the reaction of cholesterol with sebacoxl chloride. Its chemical structure and liquid crystalline properties were characterized by FTIR.CNMR,HNMR,POM and DSC. The compound with an active carboxyl group shows themortropic liquid crystalline behaviour. 相似文献