STUDIES ON cis-trans-ISOMERIZATION AND REACTION KINETICS OF A μ, η~2-VINYL LIGAND IN A TRIOSMIUM CLUSTER

The dihydride cluster H_2O_(s_3)(CO)_(10) reacts with ethyne to give a cis-adduct [O_(s_3)H(μ,η~2-CH=CH_2)(CO)_(10)]. The high deuterated cluster D_2O_(s_3)(CO)_(10), the reaction of D_2O_(s_3)(CO)_(10)with ethyne C_2H_2 to form the vinyl product cluster [O_(s_3)D(μ, η~2-CH=CHD)(CO)_(10)], and thereaction of H_2O_(s_3)(CO)_(10) with the deuterated ethyne C_2D_2 to form [O_(s_3)H(μ,η~2-CD=CDH)(CO)_(10)] have been reported primarily in this paper. The two cis-adducts undergo cis-trans-isomerization of μ,η~2-vinyl ligands under a small amount of the nucleophile pyridine. Usingthe combination of deuteration and dynamic ~1H,~2H NMR spectra, we report the experimen-tal evidence determined by the dynamic ~1H, ~2H NMR spectra, mechanism, and kinetic dataof the isomerization.     

羧甲基壳聚糖/聚乙烯醇/甘油环氧树脂蛇笼型复合螯合膜的制备及对金属离子的吸附性能

以交联甘油环氧树脂交联的聚乙烯醇(PVA)为笼树脂，羧甲基壳聚糖(CCTS)为蛇树脂制备了具有蛇笼结构的复合螯合膜，研究了其对Cu^2 、Ni^2 、Pb^2 、Fe^3 、Zn^2 ，Hg”^2 、Cd^2 等金属离子的吸附性能，研究表明，该树脂对Cu^2 、Ni^2 、Pb^2 有较好的吸附性能，其中PVA是对Cu^2 的吸附的主要贡献者，而CCTS则是在对Ni^2 的吸附中起主要作用。该树脂可以用于含Cu^2 废水的处理。     

Rare numbers

Suppose thatX ₁,X ₂,... is a sequence of iid random variables taking values inZ ⁺. Consider the random sequenceA(X)(X ₁,X ₂,...). LetY _n be the number of integers which appear exactly once in the firstn terms ofA(X). We investigate the limit behavior ofn ^–(1–) Y _n for [0, 1].     

Synthesis of a Mimicking Hybrid of Annonaceous Acetogenin with Steroid for Antitumoral Activity Investigation

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β-榄香烯振动光谱的量子化学从头计算

利用G98及GAMESS从头计算程序的RHF／6－31方法,对β－榄香烯的全部振动基频作了计算,并与实测红外光谱做了对比,归属了它们的振动模式,讨论了它们的特征基频,并对理论计算的振动频率进行了标度校正。     

Coral reef-like polyanaline nanotubes prepared by a reactive template of manganese oxide for supercapacitor electrode

Coral reef-like PANI nanotubes composed of nanopaticles were successfully synthesized by a reactive template of manganese oxide.The structure was characterized by using SEM,TEM,and FT-IR,and the supercapacitive behaviors of these nanotubes were investigated with cyclic voltammetry（CV）,and charge-discharge tests,respectively.A maximum specific capacitance of 533 F/g could be achieved in 1mol/L aqueous H₂SO₄ with the potential range of -0.2 to 0.8 V（vs.the saturated calomel electrode） in a half-cell setup configuration for PANI electrode,suggesting its potential application in the electrode material for electrochemical capacitors.     

RESEARCH ON SOME CHARACTERISTICS AND IMPROVEMENTS OF A 70cm STREAMER CHAMBER

In this paper the influence of various proportion of Ne-He gases and the time delay on the quality of streamer tracks has been studied. The diameterand density of streamers under these mixed-gas conditions have been measured.
The time resolution of this streamer chamber was determined to be 2.1μs in 69% Ne+31% He+8×10^－8 SF₆, and as 177μs in pure neon by using the exponentially decreasing relation of streamer desity with delay time. The spatial resolution was determined to be 0.32mm in Ne+3×10^－8 SF₆ by measuring the streamer diameters, and the method of track standard deviation was also used.
Some results show that the diameter and brightness increase with increasing high voltage, but become rather even when high voltage continues increasing.
Photographs were taken with domestically produced special film (32 DIN, 60 lines/mm), being similar to Kodak SO-143.
A special designed central electrode of the streamer chamber with its wires inlaid in lucite plate is successful for preventing gas from breakdown near wires. Besides, delay time has been reduced to 1.3μs, mainly by the Marx generator and its trigger system the parameters of which have been chosen by a series of experiments.     

Lower bounds for the maximal Lyapunov exponent

Upper bounds for the maximal Lyapunov exponent,E, of a sequence of matrix-valued random variables are easy to come by asE is the infimum of a real-valued sequence. We shall show that under irreducibility conditions similar to those needed to prove the Perron-Frobenius theorem, one can find sequences which increase toE. As a byproduct of the proof we shall see that we may replace the matrix norm with the spectral radius when computingE in such cases. Finally, a sufficient condition for transience of random walk in a random environment is given.     

矩母函数:拟对称概率测度

本文用凸函数的方法研究了概率测度的矩母函数和由C.J.Stone提出的拟对称性,并刻画了Martin边界的法向量.拟对称性在随机游动的比例极限定理中是一个重要的概念.这些结果可应用于Levy过程的研究.     

Riemann曲面上的正常和拟正常复合算子

Riemann曲面M上的平方可测1-形式全体和解析1-形式全体均可构成Hilbert空间。本文讨论Riemann曲面上的解析映射导出的这类Hilbert空间上的复合算子,研究复合算子的正常性、拟正常性的诱导映射特征。特别地,当M有有限三角剖分时,证明了正常复合算子、拟正常复合算子、酉复合算子、等距复合算子和可逆复合算子等价。