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991.
Th. K. Mavrogordatos 《JETP Letters》2017,106(12):815-820
We highlight the importance of quantum fluctuations in organizing a dissipative quantum phase transition for the driven Jaynes–Cummings interaction with variable qubit-cavity detuning. The system response presents a substantial difference from the predictions of the semiclassical theory, the extent of which is revealed in the properties of quantum bistability, and visualized with the help of quasi-distribution functions for the cavity field, subject to an appropriate scale parameter. States anticipated by the neoclassical theory of radiation coexist in the quantum picture, following the occurrence of spontaneous dressed-state polarization and phase bistability at resonance. 相似文献
992.
M. Burianek M. Mühlberg M. Woll M. Schmücker Th. M. Gesing H. Schneider 《Crystal Research and Technology》2009,44(10):1156-1162
Pure and homogeneous single crystals of orthorhombic mullite‐type Bi2M4O9 (M = Al3+, Ga3+, Fe3+), and a mixed Bi2Fe1.7Ga2.3O9 crystal from an equimolar Ga/Fe composition were grown by the top seeded solution growth (TSSG) method. All these compounds melt incongruently in the range of about 800 and 1100 °C. In case of bismuth gallate and ferrate inclusion‐free crystals with dimensions up to several cubic centimeters can be grown. Limited solubility in Bi2O3 and the high steepness of the liquidus curve are the reasons for getting only small imperfect bismuth aluminate crystals. In contrast to ceramic materials preparation reported in literature, divalent calcium and strontium could not be incorporated into the mullite‐type structure during the melt growth process. Several fundamental physical properties like heat capacity, thermal expansion, heat conductivity, elastic constants, high‐pressure behavior and oxygen diffusivity were determined by different research groups using single‐crystalline samples from the as‐grown materials. Furthermore, the refractive indices of Bi2Ga4O9 were measured in the range of 0.430 and 0.700 μm. Such as many other bismuth containing compounds the refractive indices of Bi2Ga4O9 are larger than 2, and Bi2Ga4O9 is an optic biaxial positive crystal. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
993.
Sp.G. Pantelakis Th.B. Kermanidis G.N. Haidemenopoulos 《Theoretical and Applied Fracture Mechanics》1996,25(2):139
Paint removal is required in a series of aeronautical procedures such as maintenance and repair. Today's paint stripping processes which are based on application of chemicals and abrasion are inadequate for modern aircraft structures in addition to environmental contamination. several alternative techniques are in progress. However, the aspect of material property degradation when developing novel, alternative paint stripping techniques has not been properly faced up to present. The influence of two novel paint stripping processes on the mechanical properties of the substrate 2024 7351 aluminium alloy has been investigated. The paint stripping processes included laser radiation with excimer, CO2, TEA-C02 and YAG laser sources as well as plasma etching. These processes have been applied for the removal of polyurethane coating which is a typical aeronautical paint system. The results indicated no significant degradation in yield strength and ultimate tensile strength. However a significant degradation in tensile ductility and toughness is observed with the application of all paint stripping processes, the highest degradation being associated with the ultraviolet excimer laser and plasma etching. On the other hand there is a considerable extension in fatigue life, which depends on the paint stripping process and the applied stress amplitude. At high stress there is no appreciable effect while at low stress there is an order of magnitude life extension associated with CO2 laser paint stripping. At moderate stresses, there is an up to sixfold life extension associated with the excimer laser processing. 相似文献
994.
Sónia S. Nobre Olivier Renard Christian Lombard Théo Chevallier Brigitte Pépin‐Donat Gilles Le Blevennec 《固体物理学:研究快报》2014,8(4):349-352
The precursor (AgIn)x Zn2(1–x)(S2CN(C2H5)2)4 was used to prepared AgInS2–ZnS nanocrystals with different compositions (x = 0.4 and x = 0.7) and with different time of reaction (10 min and 75 min). The photoluminescence features of the nanocrystals were addressed by combining steady‐state spectroscopy and light‐induced electron paramagnetic resonance. Both techniques showed the contribution of at least two components for the emission, previously assigned to surface and intrinsic states. Light‐induced electron paramagnetic resonance allowed detection of the photocreation both of irreversible paramagnetic species that are likely responsible for the nano‐crystals degradation assigned to surface states and of reversible paramagnetic species assigned to intrinsic states. Moreover, reversible bistable paramagnetic states were observed. This Letter provides a scheme that might be useful in addressing the well‐known problem of aging of the nanocrystals. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
995.
Atmospheric Plasma Jet Machining (PJM) is a technology for non‐mechanical ultra‐precision surface shape generation, shape error correction and smoothing based on atmospheric plasma jets. PJM is favorably applied to generate optical surfaces like aspheres, acylinders, or free‐forms but also to improve the surface shape accuracy in a very fast and cost‐efficient way. For that purpose a mainly fluorine containing plasma jet is brought into contact with a surface to locally remove material by a chemical reaction forming volatile products. Hence, the technology is limited to materials like silicon, fused silica and similar, or silicon carbide. Furthermore, the etch profile results from a convolution of the radical and the temperature distribution at the surface. Since the temperature distribution is also influenced by the plasma jet this leads to a non‐linear dependence of the removal function of the plasma tool on its velocity. Using the dwell‐time algorithm for deterministic surface machining by superposition of the local removal function of the plasma tool an advanced process simulation is necessary. In a first local approximation the velocity dependence of the removal function, which has to be determined previously, must be incorporated. Second order thermal effects due to inhomogeneous heating caused by the part geometry and the tool path can be managed by a sophisticated calculation of the surface temperature evolution during machining based on the Finite Element Method (FEM). With the help of this procedure the accuracy and convergence of the machining process can be significantly improved. In the article several examples of surface processing using plasma jet machining are presented. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
996.
el-Malah T Rolf S Weidner SM Thünemann AF Hecht S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(19):5837-5842
Folded dendrimers with peripheral ether side chains show a thermally induced hierarchical aggregation process, in which the transition temperature and the dimensions of the aggregates can readily be tuned via the generation number (see figure). 相似文献
997.
Versace F Uppugunduri CR Krajinovic M Théorêt Y Gumy-Pause F Mangin P Staub C Ansari M 《Analytical and bioanalytical chemistry》2012,404(6-7):1831-1838
The role of busulfan (Bu) metabolites in the adverse events seen during hematopoietic stem cell transplantation and in drug interactions is not explored. Lack of availability of established analytical methods limits our understanding in this area. The present work describes a novel gas chromatography-tandem mass spectrometric assay for the analysis of sulfolane (Su) in plasma of patients receiving high-dose Bu. Su and Bu were extracted from a single 100 μL plasma sample by liquid-liquid extraction. Bu was separately derivatized with 2,3,5,6-tetrafluorothiophenolfluorinated agent. Mass spectrometric detection of the analytes was performed in the selected reaction monitoring mode on a triple quadrupole instrument after electronic impact ionization. Bu and Su were analyzed with separate chromatographic programs, lasting 5?min each. The assay for Su was found to be linear in the concentration range of 20-400?ng/mL. The method has satisfactory sensitivity (lower limit of quantification, 20?ng/mL) and precision (relative standard deviation less than 15?%) for all the concentrations tested with a good trueness (100?±?5?%). This method was applied to measure Su from pediatric patients with samples collected 4?h after dose 1 (n?=?46), before dose 7 (n?=?56), and after dose 9 (n?=?54) infusions of Bu. Su (mean?±?SD) was detectable in plasma of patients 4?h after dose 1, and higher levels were observed after dose 9 (249.9?±?123.4?ng/mL). This method may be used in clinical studies investigating the role of Su on adverse events and drug interactions associated with Bu therapy. 相似文献
998.
Tyborski T Merschjann C Orthmann S Yang F Lux-Steiner MC Schedel-Niedrig T 《J Phys Condens Matter》2012,24(16):162201
Polymeric derivatives of dicyandiamide were synthesized via a bulk thermal condensation method, using a range of process temperatures between 400 and 610 °C. The obtained carbon nitride powders exhibit an optical transition in the UV-green range that has been assigned to the direct bandgap of a semiconductor-like material. Within this context, the apparent bandgap is linearly tunable with increasing process temperatures, showing a temperature coefficient of - 1.7(1) meV K(-1) between 2.5 and 3.0 eV. The obtained results show a predominant optical transition within the tri-s-triazine unit of the polymer, with a bathochromic shift originating from a gradually increasing degree of polymerization. 相似文献
999.
1000.
S. Mayer M. Boschung H. Hoedlmoser Th. Buchillier C. Bailat B. Bitterli 《Radiation measurements》2012,47(8):634-639
An intercomparison of the response of different photon and neutron detectors was performed in several measurement positions around a spent fuel cask (type TN 12/2B) filled with 4 MOX and 8 UO2 15 × 15 PWR fuel assemblies at the nuclear power plant Gösgen (KKG) in Switzerland. The instruments used in the study were both active and passive, photon and neutron detectors calibrated either for ambient or personal dose equivalent.The aim of the measurement campaign was to compare the responses of the radiation instruments to routinely used detectors.It has been shown that especially the indications of the neutron detectors are strongly dependent on the neutron spectra around the cask due to their different energy responses. However, routinely used active photon and neutron detectors were shown to be reliable instruments. 相似文献