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101.
Hiramatsu H Kamiya T Tohei T Ikenaga E Mizoguchi T Ikuhara Y Kobayashi K Hosono H 《Journal of the American Chemical Society》2010,132(42):15060-15067
LaCuOSe is a wide band gap (~2.8 eV) semiconductor with unique optoelectronic properties, including room-temperature stable excitons, high hole mobility ~8 cm(2)/(Vs), and the capability of high-density hole doping (up to 1.7 × 10(21) cm(-3) using Mg). Moreover, its carrier transport and doping behaviors exhibit nonconventional results, e.g., the hole concentration increases with decreasing temperature and the high hole doping does not correlate with other properties such as optical absorption. Herein, secondary ion mass spectroscopy and photoemission spectroscopy reveal that aliovalent ion substitution of Mg at the La site is not the main source of hole doping and the Fermi level does not shift even in heavily doped LaCuOSe:Mg. As the hole concentration increases, the subgap optical absorption becomes more intense, but the increase in intensity does not correlate quantitatively. Transmission electron microscopy indicates that planar defects composed of Cu and Se deficiencies are easily created in LaCuOSe. These observations can be explained via the existence of a degenerate low-mobility layer and formation of complex Cu and Se vacancy defects with the assistance of generalized gradient approximation band calculations. 相似文献
102.
Tomohiro Narukawa Takayoshi Kuroiwa Izumi Narushima Yasujiro Jimbo Toshihiro Suzuki Koichi Chiba 《Analytical and bioanalytical chemistry》2010,397(2):493-499
Arsenate [As(V)] solution reference material, National Metrology Institute of Japan (NMIJ) certified reference material (CRM)
7912-a, for speciation of arsenic species was developed and certified by NMIJ, the National Institute of Advanced Industrial
Science and Technology. High-purity As2O3 reagent powder was dissolved in 0.8 M HNO3 solution and As(III) was oxidized to As(V) with HNO3 to prepare 100 mg kg-1 of As(V) candidate CRM solution. The solution was bottled in 400 bottles (50 mL each). The concentration of As(V) was determined
by four independent analytical techniques—inductively coupled plasma mass spectrometry, inductively coupled plasma optical
emission spectrometry, graphite furnace atomic absorption spectrometry, and liquid chromatography inductively coupled plasma
mass spectrometry—according to As(V) calibration solutions, which were prepared from the arsenic standard of the Japan Calibration
Service system and whose species was guaranteed to be As(V) by NMIJ. The uncertainties of all the measurements and preparation
procedures were evaluated. The certified value of As(V) in the CRM is (99.53 ± 1.67) mg kg-1 (k = 2). 相似文献
103.
Satoshi Migita Akito Tateishi Kari Keinänen Tetsuya Haruyama 《Analytical and bioanalytical chemistry》2010,396(3):1153-1157
Bioassay models of neural functions must lend themselves to high-throughput analysis in neural drug discovery. However, smart
analysis methods for these functions have not yet been fully established. Here, we describe the development of a synapse model
for cell-based biosensing. The engineered synapse model cell expresses ionotropic glutamate receptor on its surface, like
the neural postsynaptic membrane. The advantages of the model cell are the ease of handling and reproducibility as compared
with the cultured neural cell, and it can be employed to evaluate receptor function through ion flux analysis. The agonist-induced
sodium influx was monitored as an agonist concentration-dependent increase in the observed fluorescence signal. Furthermore,
we found that our model cell enables the correction of uneven cellular signal levels using a reporter system. Our engineered
synapse model cell can be employed as a powerful tool for the screening of lead substances in pharmaceutical high-throughput
analysis. 相似文献
104.
The magnetic property of Co2B2O5 and the optical property of M2B2O5 (M = Mn, Co) were investigated. Co2B2O5 showed antiferromagnetic behavior below the Néel temperature of TN ≈ 45 K, and the Weiss temperature was TW = +7.7 K. The effective magnetic moment of Co was 4.96 μB, which indicated that Co was divalent and in a high-spin state. Absorptions attributed to the d–d transitions in Mn2+ and Co2+ ions were observed at 250–650 nm in the diffuse reflection spectra. The optical absorption edges of Mn2B2O5 and Co2B2O5 were at 243 nm (5.11 eV) and 299 nm (4.15 eV), respectively. 相似文献
105.
Tanaka H Kawai T Adachi Y Ohno N Takahashi T 《Chemical communications (Cambridge, England)》2010,46(43):8249-8251
In this report, we describe the convergent synthesis of β(1,3) oligosaccharides containing an aminoalkyl group. The branched heptadecasaccharide and linear hexadecasaccharide acted as ligands of dectin-1 whose binding affinity was only 10-fold weaker than that of natural SPG and exhibited dectin-1 agonist activity. 相似文献
106.
107.
Tetsuya Masuda Katsuhisa Mimachi Yoshiomi Nakagami Masatoshi Noumi Yutaka Saburi Kimio Ueno 《Letters in Mathematical Physics》1990,19(3):187-194
Real forms of the quantum universal enveloping algebraU
q
(sl(2)) and a topological quantum group associated with this algebra are discussed. 相似文献
108.
109.
Prediction of the lifetime of nitrile-butadiene rubber by FT-IR. 总被引:3,自引:0,他引:3
A quantitative measurement method with FT-IR was proposed for a thermal degradation analysis of nitrile-butadiene rubber (NBR). An NBR film was prepared as a model sample on a barium fluoride (BaF2) crystal plate, which was subjected to a heat treatment. The absorbances of various functional groups were measured directly by FT-IR after thermal degradation at high temperatures. By measuring the absorbances, it was possible to readily determine quantitatively each of the functional groups after the degradation of NBR. By assuming that the NBR lifetime was the point at which the absorbance of a carbon-carbon double bond reaches 45% of that prior to thermal treatment, a method for predicting the lifetime of NBR heated below 150 degrees C was proposed, by using an Arrhenius plot of the heating time versus heating temperature. 相似文献
110.
Hitoshi Osawa Toshiaki IwazumiHiroko Tokoro Shin-ichi OhkoshiKazuhito Hashimoto Hironobu ShojiEiju Hirai Tetsuya NakamuraSusumu Nanao Yasuhito Isozumi 《Solid State Communications》2003,125(5):237-241
The thermal phase transition of RbMnFe(CN)6 has been observed by Mn and Fe 3p-1s X-ray emission spectroscopy (XES) and 1s X-ray absorption spectroscopy (XAS). The thermal variations of the spin states and the valences of Mn and Fe were determined to be Mn2+(S=5/2)-NC-Fe3+(S=1/2) for the high-temperature (HT) phase and Mn3+(S=2)-NC-Fe2+(S=0) for the low-temperature (LT) phase. These transitions are thus caused by charge transfer between Mn and Fe. The temperature dependences of Mn and Fe 3p-1s XES and 1s XAS were observed as the composition of the spectra of the HT and LT phases. The ratios of the HT component in each spectrum show good agreement with the thermal transition curves observed with magnetic susceptibility measurements. 相似文献