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941.
Environment‐Sensitive Fluorescent Probe: A Benzophosphole Oxide with an Electron‐Donating Substituent 下载免费PDF全文
Eriko Yamaguchi Chenguang Wang Prof. Dr. Aiko Fukazawa Prof. Dr. Masayasu Taki Dr. Yoshikatsu Sato Taeko Sasaki Dr. Minako Ueda Prof. Dr. Narie Sasaki Prof. Dr. Tetsuya Higashiyama Prof. Dr. Shigehiro Yamaguchi 《Angewandte Chemie (International ed. in English)》2015,54(15):4539-4543
Electron‐donating aryl groups were attached to electron‐accepting benzophosphole skeletons. Among several derivatives thus prepared, one benzophosphole oxide was particularly interesting, as it retained high fluorescence quantum yields even in polar and protic solvents. This phosphole‐based compound exhibited a drastic color change of its fluorescence spectrum as a function of the solvent polarity, while the absorption spectra remained virtually unchanged. Capitalizing on these features, this phosphole‐based compound was used to stain adipocytes, in which the polarity of subcellular compartments could then be discriminated on the basis of the color change of the fluorescence emission. 相似文献
942.
Majority‐Rules‐Type Helical Poly(quinoxaline‐2,3‐diyl)s as Highly Efficient Chirality‐Amplification Systems for Asymmetric Catalysis 下载免费PDF全文
Dr. Tetsuya Yamada Prof. Dr. Michinori Suginome 《Angewandte Chemie (International ed. in English)》2015,54(32):9333-9337
A highly efficient majority‐rules effect of poly(quinoxaline‐2,3‐diyl)s (PQXs) bearing 2‐butoxymethyl chiral side chains at the 6‐ and 7‐positions was established and attributed to large ΔGh values (0.22–0.41 kJ mol?1), which are defined as the energy difference between P‐ and M‐helical conformations per chiral unit. A PQX copolymer prepared from a monomer derived from (R)‐2‐octanol (23 % ee) and a monomer bearing a PPh2 group adopted a single‐handed helical structure (>99 %) and could be used as a highly enantioselective chiral ligand in palladium‐catalyzed asymmetric reactions (products formed with up to 94 % ee), in which the enantioselectivity could be switched by solvent‐dependent inversion of the helical PQX backbone. 相似文献
943.
A Phosphole Oxide Based Fluorescent Dye with Exceptional Resistance to Photobleaching: A Practical Tool for Continuous Imaging in STED Microscopy 下载免费PDF全文
Dr. Chenguang Wang Prof. Dr. Aiko Fukazawa Prof. Dr. Masayasu Taki Dr. Yoshikatsu Sato Prof. Dr. Tetsuya Higashiyama Prof. Dr. Shigehiro Yamaguchi 《Angewandte Chemie (International ed. in English)》2015,54(50):15213-15217
The development of stimulated emission depletion (STED) microscopy represented a major breakthrough in cellular and molecular biology. However, the intense laser beams required for both excitation and STED usually provoke rapid photobleaching of fluorescent molecular probes, which significantly limits the performance and practical utility of STED microscopy. We herein developed a photoresistant fluorescent dye C‐Naphox as a practical tool for STED imaging. With excitation using either a λ=405 or 488 nm laser in protic solvents, C‐Naphox exhibited an intense red/orange fluorescence (quantum yield ΦF>0.7) with a large Stokes shift (circa 5900 cm?1). Even after irradiation with a Xe lamp (300 W, λex=460 nm, full width at half maximum (FWHM)=11 nm) for 12 hours, 99.5 % of C‐Naphox remained intact. The high photoresistance of C‐Naphox allowed repeated STED imaging of HeLa cells. Even after recording 50 STED images, 83 % of the initial fluorescence intensity persisted. 相似文献
944.
Tetsuya Ohashi R.I. Barabash J.W.L. Pang G.E. Ice O.M. Barabash 《International Journal of Plasticity》2009
We compare experimental measurements of inhomogeneous plastic deformation in a Ni bicrystal with crystal plasticity simulations. Polychromatic X-ray microdiffraction, orientation imaging microscopy and scanning electron microscopy, were used to characterize the geometrically necessary dislocation distribution of the bicrystal after uniaxial tensile deformation. Changes in the local crystallographic orientations within the sample reflect its plastic response during the tensile test. Elastic strain in both grains increases near the grain boundary. Finite element simulations were used to understand the influence of initial grain orientation and structural inhomogeneities on the geometrically necessary dislocations arrangement and distribution and to understand the underlying materials physics. 相似文献
945.
Lanlan?Jiang Yu?LiuEmail author Yongchen?Song Mingjun?Yang Ziqiu?Xue Yuechao?Zhao Jiafei?Zhao Yi?Zhang Tetsuya?Suekane Zijian?Shen 《Experiments in fluids》2015,56(5):91
A clear understanding of two-phase flows in porous media is important for investigating CO2 geological storage. In this study, we conducted an experiment of CO2/brine flow process in porous media under sequestration conditions using X-ray CT technique. The flow properties of relative permeability, porosity heterogeneity, and CO2 saturation were observed in this experiment. The porous media was packed with glass beads having a diameter of 0.2 mm. The porosity distribution along the flow direction is heterogeneous owing to the diameter and shape of glass beads along the flow direction. There is a relationship between CO2 saturation and porosity distribution, which changes with different flow rates and fractional flows. The heterogeneity of the porous media influences the distribution of CO2; moreover, gravity, fractional flows, and flow rates influence CO2 distribution and saturation. The relative permeability curve was constructed using the steady-state method. The results agreed well with the relative permeability curve simulated using pore-network model. 相似文献
946.
Tetsuya Miyaoka 《International Journal of Computational Fluid Dynamics》2013,27(10):677-686
The purpose of this article is to present a technique to optimally control river flood using a drainage basin considering a moving boundary. The main theme of this article is to obtain outflow discharge from the drainage basin that maintains the water level at a downstream point and empties the drainage basin as soon as possible. The water flow phenomenon inside the drainage basin when a river flood occurs is considered. This phenomenon can be analysed by the finite element method considering a moving boundary. The optimal control theory can be implemented to obtain the optimal control discharge. The finite element analysis with a moving boundary is introduced in the optimal control theory. A new boundary condition on the downstream side of the river is proposed. This condition is formulated by the solitary wave condition based on the basic water level being capable of representing natural water surface. As a numerical study, optimal control of shallow water flow is carried out for the Tsurumi River and its drainage basin model. 相似文献
947.
Julián López-Gómez Toshitaka Nagai Tetsuya Yamada 《Archive for Rational Mechanics and Analysis》2013,207(1):159-184
We consider the Cauchy problem for a parabolic–elliptic system in ${\mathbb{R}^2}$ , which is amathematical model of chemotaxis and also amodel of self-attracting particles. In the critical mass case, we determine the basin of attraction of the steady-states for the Cauchy problem through a Lyapunov functional. 相似文献
948.
Ryuji Yoneda Tetsuya Kimura Junko Kinomoto Shinya Harusawa Takushi Kurihara 《Journal of heterocyclic chemistry》1996,33(6):1909-1913
Ring expansion of azetopyridoindole 11 via the [1,2]-Meisenheimer rearrangement of the corresponding N-oxide 12 gave azocinoindole 14 , which was converted into the N-benzoylenaminone 18 in 5 steps. Intramolecular cyclization of 18 was accomplished by a modified Heck reaction followed by reductive desulfonylation to provide the indole analog 2, 5H -isoindolo[2′,1′;1,2]azocino[5,6-b]indole, of magallanesine 1 . 相似文献
949.
Tetsuya Homma Hiroyasu Kondo Msaya Sakamoto Masahiro Nomoto Kazuaki Inohara Yuji Ariyama Masahiro Itoh Hideo Takahashi 《Optical Review》2000,7(6):505-510
A thin-film optical waveguide using a fluorinated silicon oxide (SiOF) as a core layer was investigated. An organic spin-on-glass (SOG) film was used for a cladding layer. The SiOF films were formed at 23°C by a liquid-phase deposition (LPD) technique using a supersaturated hydrofluosilicic acid (H2SiF6) aqueous solution. A thin-film optical waveguide structure for single mode was designed and fabricated, based on the dispersion properties of refractive indices for the LPD-SiOF and organic SOG films. The refractive indices at a wavelength of 632.8 nm were 1.430 and around 1.400 for the LPD-SiOF and organic SOG films, respectively. The thickness of LPD-SiOF films deposited was 1.18 μm. Thicknesses of cladding organic SOG films cured at 300 and 400°C were 1.28 and 1.31μm, respectively. The effective refractive indices for single mode were 1.4169 and 1.4158 at a wavelength of 632.8 nm for the cladding organic SOG films cured at 300 and 400°C, respectively, and differences between the measured and calculated incident angles were 0.84° and 1.29° for the cladding organic SOG films cured at these respective temperatures. A streak of guided-light was observed for the LPD-SiOF/SOG structure optical waveguide. The transmission loss was 7.6-7.9 dB/cm. 相似文献
950.
Shoji Yoshimoto Fumihiko Ohashi Tetsuya Kameyama 《Macromolecular rapid communications》2004,25(19):1687-1691
Summary: Conducting polyaniline (PANI) and montmorillonite (MMT) nanocomposites were prepared from aniline sulfate and MMT by a mechanochemical synthesis route. X‐Ray diffraction analysis confirmed that, by controlling the aniline sulfate content, mechanochemical synthesis led to two types of different formations. After polymerization, the mechanochemical route synthesized much more PANI between the clay layers compared to a solution method. The electrical conductivities of the synthesized PANI‐MMT nanocomposites in pressed pellets ranged in the order of between 10−4 and 10−3 S · cm−1.