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51.
Robin A. Krüger Terry J. Gordon Todd C. Sutherland Thomas Baumgartner 《Journal of polymer science. Part A, Polymer chemistry》2011,49(5):1201-1209
A series of polythiophenes doped with dithieno[3,2‐b:2′,3′‐d]phosphole units at varying levels (0–17%) were synthesized and characterized. Polymer work up provided two series of polymers from chloroform (C) and hexanes (H) for each doping level, respectively. Systematic structure–property studies revealed that the C‐series polymers generally had higher molecular weights than the H‐series, but also slightly higher relative dithienophosphole concentrations, both having a significant impact on the photophysical and electrochemical properties of the polymers. Furthermore, the presence of the dithienophosphole units also stabilizes the LUMO levels, whereas the HOMO levels remain dominated by the thiophene units, resulting in desirable electronics for an interaction with acceptor materials, such as 1‐(3‐methoxycarbonyl)propyl‐1‐phenyl[6,6]C61. Importantly, increasing amount of dithienophosphole doping results in increased conductivities for the polymers in their oxidized state, while concurrently significantly stabilizing the neutral polythiophenes toward oxidation under environmental conditions. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
52.
Lowe Terry C. Bishop Alan Burns Carol Hartford Allen Parkin Don Trewhella Jill 《Journal of nanoparticle research》2000,2(3):249-266
Research in the emerging field of nanoscale science and technology has grown steadily at Los Alamos National Laboratory since 1990. This article summarizes some of this work, examining research highlights within the seven key categories of nanoscience in which Los Alamos has ongoing projects, capabilities, and facilities: (1) Materials and chemistry, (2) Theory and modeling, (3) Bioscience, (4) Investigative tools and facilities, (5) Sensors and devices, (6) Synthesis and fabrication, and (7) Education and outreach. Future research horizons are indicated throughout while institutional strategies for advancing nanoscale science are summarized at the end. 相似文献
53.
Terry Bradfield 《General Relativity and Gravitation》1989,21(7):665-675
In this paper we present a new method for constructing theories of gravitation which exhibit spontaneously broken conformal symmetry. It does not require introducing nongeometric terms (i.e., auxiliary gauge fields or potential terms for the conformal field) into the Lagrangian. It is based on a theory which initially is locally both Lorentz invariant and Weyl gauge invariant inD dimensions. It is shown that, if the field Lagrangian contains terms quadratic in curvature in addition to the Ricci scalar, then the field equations allow both the dilation field and some connection components to have nonvanishing vacuum values. Both Lorentz and Weyl symmetries are thereby broken simultaneously. 相似文献
54.
K.A. Schmidt M. Bergström G.B. Hagemann B. Herskind G. Sletten P.G. Varmette J. Domscheit H. Hübel S.W. Ødegård S. Frattini A. Bracco B. Million M.P. Carpenter R.V.F. Janssens T.L. Khoo T. Lauritsen C.J. Lister S. Siem I. Wiedenhöver D.J. Hartley L.L. Riedinger A. Maj W.C. Ma R. Terry 《The European Physical Journal A - Hadrons and Nuclei》2001,12(1):15-28
High-spin properties of the nucleus 169Hf have been studied through the fusion evaporation reaction 96Zr(76Ge,3n)169Hf at a beam energy of 310 MeV. The known rotational bands have been extended considerably and 6 new bands have been established,
four of which form coupled bands with pronounced M1 connections. Quasiparticle assignments are suggested for the new band structures, and it appears that coupling to vibrational
degrees of freedom plays a role. Both coupled bands involve the excitation of quasiprotons. In the region of highest spin,
a large alignment gain is interpreted in terms of a mixed crossing where an h
9/2 and an h
11/2 quasiproton provide the two signatures of the aligning configuration.
Received: 23 March 2001 / Accepted: 20 September 2001 相似文献
55.
A. G. Pinkus Ravi Subramanyam Sandra L. Clough Terry C. Lairmore 《Journal of polymer science. Part A, Polymer chemistry》1989,27(13):4291-4296
Polymandelide was prepared in 77% yield by reaction of α-bromophenylacetic acid and triethylamine. The product was characterized by 1H- and 13C-NMR and IR spectra and isolation and identification of mandelic acid from hydrolysis of the polymer. The NMR spectra indicate the presence of tacticity at CH in the polymer. Molecular weights were determined by GPC and viscosity measurements; n values of 12–20 are comparable to those reported for polymandelides prepared by other methods. The x-ray powder diffraction pattern showed the product to be completely amorphous. Thermal decomposition was studied using DSC. 相似文献
56.
Joann Huber Robert G.K. Donald Sang Ho Lee Lisa Wang Jarantow Michael J. Salvatore Xin Meng Ronald Painter Russell H. Onishi James Occi Karen Dorso Katherine Young Young Whan Park Stephen Skwish Michael J. Szymonifka Tim S. Waddell Lynn Miesel John W. Phillips Terry Roemer 《Chemistry & biology》2009,16(8):837-848
57.
Models for locating a firm's production facilities while simultaneously determining production levels at these facilities and shipping patterns so as to maximize the firm's profits are presented. In these models, existing firms, are assumed to act in accordance with an appropriate model of spatial equilibrium. A proof of existence of a solution to the combined location-equilibrium problem is provided. 相似文献
58.
Terry Bradfield 《General Relativity and Gravitation》1990,22(2):217-231
Some new effective actions are suggested for theories in which the affine connection is not completely specified by the metric. The new actions lead to models in which the metric, torsion, and Weyl vector fields all propagate. The dimensionally reduced versions do not contain third derivatives of the gauge potentials in the field equation. Some simple models which exhibit simultaneous breaking of Weyl andD-dimensional Lorentz symmetry are investigated. It is shown that it is possible for this effect to occur in any model in which the field action contains the Einstein-Hilbert term. This is due to the fact that the contortion occurs in this object as part of an indefinite quadratic form. 相似文献
59.
Bin Wan Terry A.Ring 《中国颗粒学报》2006,4(5):243-249
For many processes of industrial significance, due to the strong coupling between particle interactions and fluid dynamics, the population balance must be solved as part of a computational fluid dynamics (CFD) simulation. In this work, a CFD based population balance model is tested using a batch crystallization reactor. In this CFD model, the population balance is solved by the standard method of moments (SMOM) and the quadrature method of moments (QMOM). The results of these simulations are compared to analytical solutions for the population balance in a batch tank where 1) nucleation, 2) growth, 3) aggregation, and 4) breakage are taking place separately. The results of these comparisons show that the first 6 moments of the population balance are accurately predicted for nucleation, growth, aggregation and breakage at all times. 相似文献
60.
Robert E. Jamison characterized chordal graphs by the edge set of every k-cycle being the symmetric difference of k−2 triangles. Strongly chordal (and chordal bipartite) graphs can be similarly characterized in terms of the distribution of triangles (respectively, quadrilaterals). These results motivate a definition of ‘strongly chordal bipartite graphs’, forming a class intermediate between bipartite interval graphs and chordal bipartite graphs. 相似文献