全文获取类型
收费全文 | 3598篇 |
免费 | 315篇 |
国内免费 | 1218篇 |
专业分类
化学 | 3934篇 |
晶体学 | 30篇 |
力学 | 101篇 |
综合类 | 10篇 |
数学 | 398篇 |
物理学 | 658篇 |
出版年
2023年 | 12篇 |
2022年 | 40篇 |
2021年 | 52篇 |
2020年 | 41篇 |
2019年 | 41篇 |
2018年 | 33篇 |
2017年 | 26篇 |
2016年 | 84篇 |
2015年 | 79篇 |
2014年 | 78篇 |
2013年 | 382篇 |
2012年 | 415篇 |
2011年 | 405篇 |
2010年 | 199篇 |
2009年 | 313篇 |
2008年 | 223篇 |
2007年 | 200篇 |
2006年 | 188篇 |
2005年 | 233篇 |
2004年 | 556篇 |
2003年 | 393篇 |
2002年 | 370篇 |
2001年 | 111篇 |
2000年 | 60篇 |
1999年 | 72篇 |
1998年 | 79篇 |
1997年 | 65篇 |
1996年 | 54篇 |
1995年 | 22篇 |
1994年 | 11篇 |
1993年 | 16篇 |
1992年 | 21篇 |
1991年 | 13篇 |
1990年 | 11篇 |
1989年 | 14篇 |
1988年 | 8篇 |
1987年 | 15篇 |
1986年 | 14篇 |
1985年 | 18篇 |
1984年 | 12篇 |
1983年 | 10篇 |
1982年 | 11篇 |
1981年 | 13篇 |
1980年 | 10篇 |
1979年 | 8篇 |
1978年 | 10篇 |
1977年 | 8篇 |
1976年 | 13篇 |
1974年 | 7篇 |
1973年 | 8篇 |
排序方式: 共有5131条查询结果,搜索用时 156 毫秒
61.
62.
Di Pietro C Serroni S Campagna S Gandolfi MT Ballardini R Fanni S Browne WR Vos JG 《Inorganic chemistry》2002,41(11):2871-2878
The synthesis and characterization of two dinuclear ruthenium polypyridyl complexes based on the bridging ligands 5,5'-bis(pyridin-2' '-yl)-3,3'-bis(1H-1,2,4-triazole) and 5,5'-bis(pyrazin-2' '-yl)-3,3'-bis(1H-1,2,4-triazole) and of their mononuclear precursors are reported. The dinuclear compounds have been prepared by a Ni(0) catalyzed coupling of a mononuclear ruthenium(II) polypyridyl complex containing a brominated triazole moiety. Electrochemical and photophysical studies indicate that, in these dinuclear complexes, the protonation state of the bridge may be used to tune the intercomponent interaction between the two metal centers and that these species act as proton driven three-way molecular switches that can be read by electrochemical or luminescence techniques. 相似文献
63.
64.
键连接性指数的建构及其在有机体系中的应用研究 总被引:3,自引:0,他引:3
以化学键为基础建构了键连接性指数及分子键连接性指数,该指数同时考虑顶 点原子的化学特征及键的性质.对于任意化学键,键连接性指数Si=1+△I/R·[( Z1-h1)m2/n1+(Z2-h2)m1/n2],分子键连接性指数S为∑i=1^m√Si或∑i=1^m1/√ Si,其中,Z1,Z2为化学键键连原子的价电子数;n1,n2成键原子的价层最高主量 子数;m1,m2为成键原子的氧化数;h1,h2为与成键原子相连的氢原子个数;△I 为成键原子的电负性差(△I≥0);R为化学键的相对键长.与以顶点为基础的价连 接性指数不同,该指数不仅能方便而有效地应用于饱和碳氢体系亦能有效地应用于 含多重键的不饱和体系及含杂原子的有机体系.研究了饱和碳氢体系标准生成焓, 不饱和碳氢体系和酮、醚、酯体系在水中的溶解度和辛醇/水分配系数,卤代甲烷 体系的标准生成焓,卤代苯体系辛醇/水分配系数,均取得比较满意的结果。 相似文献
65.
Optimisation of Supercritical Carbon Dioxide Systems for Complexation of Naproxen : Beta-Cyclodextrin 总被引:1,自引:0,他引:1
Susana Junco Teresa Casimiro Nuno Ribeiro Manuel Nunes Da Ponte Helena M. Cabral Marques 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):69-73
Supercritical carbon dioxide (scCO2)offers several attractive scenarios for thepharmaceutical processing as an alternativeto aqueous and organic solvents. In thiswork naproxen, a widely used non steroidalanti-inflammatory drug with analgesic andanti-inflammatory properties, was chosenas a model drug. Its complexation with cyclodextrinsimproves the rate and extent of dissolutionof the drug, increase its rate of absorption and mayreduce the unpleasant side-effects of the drug.The interest in using this supercritical technologyled us to develop an experimental unit for the useof supercritical CO2 as a processing medium forthe complexation of naproxen with beta cyclodextrin (CD). 相似文献
66.
A new triterpenoid saponin with novel sugar moiety (1), a new trisaccharide derivative (2), as well as a known monosaccharide derivative (3), were isolated from the dried stem of Epigyhum aurilum. The structures of compounds 1 and 2 were determined by MS and NMR spectram analyses. 相似文献
67.
68.
69.
70.
Smain Bousalem Claire Mangeney Mohamed M. Chehimi Teresa Basinska Beata Miksa Stanislaw Slomkowski 《Colloid and polymer science》2004,282(12):1301-1307
N-Succinimidyl ester functionalized polypyrrole-coated polystyrene latex particles (PSE-PPyNSE) were prepared by the in situ copolymerization of pyrrole and the active ester-functionalized pyrrole (pyrrole-NSE) in the presence of polystyrene latex particles. Polystyrene microspheres were prepared by emulsion polymerization (PSE) leading to particles having a diameter of 450 nm. These PSE particles were precoated with poly(N-vinylpyrrolidone) prior to the in situ copolymerization of pyrrole and pyrrole-NSE. The initial comonomer concentration fractions were 25/75, 50/50 and 75/25 for pyrrole and pyrrole-NSE, respectively. The PPy-coated PSE particles were characterized in terms of morphology, particle size, electrophoretic mobility and chemical composition. The study of morphology by means of scanning electron microscopy showed roughening of the underlying PSE particles owing to the addition of PPyNSE, the overlayer thickness of which was estimated to be around 7 nm. Moreover, loading PPyNSE overlayers resulted in a shift of the electrophoretic mobility from –5.31 m cm/V s to a very small but positive value (0.082–0.112 m cm/V s). X-ray photoelectron spectroscopy and IR spectroscopy permitted the detection of pyrrole-NSE repeat units at the surface indicating that pyrrole and pyrrole-NSE did indeed copolymerize. The PSE-PPyNSE particles were further evaluated as bioadsorbents of human serum albumin used as a test protein. For this study, PSE-PPyNSE50 particles, synthesized from a comonomer feed ratio of 50/50 in pyrrole/pyrrole-NSE, were used and were shown to attach efficiently human serum albumin macromolecules with a maximum amount of 0.2 mg m–2.
相似文献
Mohamed M. ChehimiEmail: |