A New Strategy to Identify and Eliminate the Inner Filter Effects by Outer Filter Technique

To identify and eliminate the inner filter effects (IFEs), prepositive and side cells containing absorbents are fixed beside the fluorescer contained cell. In this way, excitation and emission lights can be quenched by primary and secondary outer filter effects respectively, depending on absorbent concentration and cell length. Herein the quenching of emission fluorescence caused by IFEs can be equally reduced by outer filter effects (OFEs) and the interference of IFEs was eliminated. This approach was experimentally used for identifying the interaction mode and mechanism between BSA and nanoAg. Results showed that the quenching of BSA fluorescence and synchronous fluorescence mainly attributes to IFEs, instead of static/dynamic fluorescent quenching. In view of the above, the elimination of the interference of IFEs by the design of OFEs plays an important part in the precise application of fluorescence detector.     

医用生物材料的低温保存研究

生物材料的低温保存一般都要经历降温过程、低温储存过程及复温过程,其中降温过程中对生物细胞的影响最大.每一种生物细胞都有自己合适的降温速率,如能满足其这种降温速率,细胞所受到的低温损伤最小,则生物细胞的复活率最高.文中介绍程序控制变速降温装置的主要结构及几种典型生物体的降温过程.最后,对器官的低温保存进行分析讨论.     

Visible photoluminescence of nanometer-sized SiGe/Si heterostructure fabricated by ion implantation

An innovative fabrication technique for the nanometer-sized SiGe/Si heterostructure was developed in this study. Ge was induced in Si substrate by two-step ion implantation. The spherical SiGe nanoclusters are self-assembled in the Si substrate by subsequent rapid thermal annealing at 1,100 °C. The diameter of the spherical SiGe nanoclusters is 5–7 nm. Visible photoluminescence from this nanometer-sized SiGe/Si heterostructure at room temperature was investigated. We found three peak energies of visible luminescence spectra at 1.97, 2.13, and 2.16 eV, respectively. The luminescence intensity depends on the number of the nanoclusters and will be decreased because of the micro-defects around the heterostructure, which is discussed in detail.     

<Emphasis Type="Italic">B</Emphasis><Subscript><Emphasis Type="Italic">c</Emphasis></Subscript> meson rare decays in the light-cone quark model

We investigate the rare decays \(B_{c} \rightarrow D_{s}(1968)\ell \overline{\ell}\) and \(B_{c}\rightarrow D_{s}^{*}(2317) \ell \overline{\ell}\) in the framework of the light-cone quark model (LCQM). The transition form factors are calculated in the space-like region and then analytically continued to the time-like region via exponential parametrization. The branching ratios and longitudinal lepton polarization asymmetries (LPAs) for the two decays are given and compared with each other. The results are helpful for investigating the structure of B _c meson and for testing the unitarity of CKM quark mixing matrix. All these results can be tested in the future experiments at the LHC.     

基于无基底焦平面阵列红外热像仪的理论模型分析

基于双材料微悬臂梁热变形原理的光学读出非制冷红外探测阵列经历了从有基底结构向无基底结构的发展过渡,无基底阵列的红外成像结果和有限元模型分析均表明无基底阵列不满足恒温基底条件.本文结合电学比拟的方法,提出了一种新的基于无基底焦平面阵列(focal plane Array,FPA)的热传递分析的理论模型.分析采用整体考虑的思路,避开了无基底FPA阵列各单元热传递互相影响所产生的复杂热分布分析,并考虑了框架对热量的吸收与传递.理论模型采用外边框与环境等温的边界条件,虽不及有限元方法对边界条件的处理灵活,但也已取 关键词： 光学读出 无基底 非制冷红外成像 焦平面阵列     

Synchronization of complex community networks with nonidentical nodes and adaptive coupling strength

In this Letter, the complex dynamical networks with community structure and nonidentical nodes are considered. The globally asymptotical synchronization of the time-delayed complex community networks onto any uniformly smooth state is studied. Some simple and useful criteria are derived by constructing an effective control scheme and adjusting automatically the adaptive coupling strength. Finally, the developed techniques are applied to two complex community networks which are respectively synchronized to a chaotic trajectory and a periodic orbit, and numerical simulations are provided to show the feasibility of the developed methods.     

SOME RESULTS ABOUT COVERING PROPERTIES OF PRODUCTS

ＳＯＭＥ ＲＥＳＵＬＴＳ ＡＢＯＵＴ ＣＯＶＥＲＩＮＧ ＰＲＯＰＥＲＴＩＥＳ ＯＦ ＰＲＯＤＵＣＴＳ ￥ＪＩＡＮＧＪＩＧＵＡＮＧ;ＴＥＮＧＨＵＩＡｂｓｔｒａｃｔ：Ｔｈｅｆｏｌｌｏｗｉｎｇｒｅｓｕｌｔｓａｒｅｐｒｏｖｅｄ：１．ＬｅｔＸｂｅａｓｃｒｅｅｎ...     

Chiral N-phosphonyl imine chemistry:asymmetric additions of glycine enolate to diphenyl diamine-based phosphonyl imines

Diphenyl diamine-based phosphonyl imines attached by the N-isopropyl group in the auxiliary have been synthesized in good yields under convenient reaction conditions.These new chiral N-phosphonyl imines can react with glycine enolate smoothly to give chiral α-β diamino esters in good yields(72%-90%) and up to excellent diastereoselectivity(>99:1 dr).By treatment with HBr,the chiral auxiliary can be readily removed.The absolute structure has been unambiguously determined by converting a product to a known sa...     

Conjugated copolymers comprised cyanophenyl‐substituted spirobifluorene and tricarbazole‐triphenylamine repeat units for blue‐light‐emitting diodes

A series of conjugated blue‐light‐emitting copolymers, PTC‐1 , PTC‐2 , and PTC‐3, comprised different ratios of electron‐withdrawing segments (spirobifluorene substituted with cyanophenyl groups) and electron‐donating segments (tricarbazole‐triphenylamines), has been synthesized. The structures of these polymers were characterized and their thermal, photophysical, electrochemical, and electroluminescence properties were measured. Incorporation of rigid spirobifluorene units into the copolymers led to blue‐shifted absorption peaks in dilute toluene solution. Cyclic voltammetric measurement indicated the bandgaps of the polymers were in the range of 2.77–2.94 eV. It was found that increasing cyanophenyl‐spirobifluorene content in the polymer backbone lowered both the HOMO and LUMO energy levels of the copolymers, which was beneficial for electron injection/transporting in the polymer layer of the device. OLED device evaluation indicated that all the polymers emitted sky blue to deep blue light when the pure polymers were used as the emissive layers in the devices with a configuration of ITO/PEDOT:PSS/polymers/CsF/Ca/Al. The devices have been optimized by doping 30 wt % PBD into the polymer layers. Among the doped devices, PTC‐2 showed the best performance with the turn‐on voltage of 3.0 V, maximum brightness of 7257 cd/m², maximum current efficiency of 1.76 cd/A, and CIE coordinates of (0.15, 0.14). © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 292–301, 2010     

微观结构对膜换湿能力影响研究

对多孔膜换湿过程进行了理论分析,得到了透湿量和湿阻的计算式.同时对三种膜包括PVDF,PES和纤维素膜进行了湿阻的测量实验,通过对实验数据的回归处理,得到了多孔膜的结构参数.结果表明,膜厚、孔径分布、孔隙率及曲折因子对膜的换湿特性都有较大影响,在平均孔径相同的情况下,其它因素仍然导致了不同膜换湿能力的较大差距。在所获得的结构参数基础上,通过数值模拟的方法研究了平均孔径对膜换湿能力的影响。结果表明湿阻随平均孔径的增大而减小,减小趋势逐渐平缓最后趋向一定值。