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71.
A class of chiral ketone was synthesized for asymmetric epoxidation. High ee values have been obtained for a number of cis olefin and trans olefin. The epoxidation was stereospecific with no isomerizatiom observed in the epoxidation of acyclic system. Encourageingly high ee value has also been obtained for a number of terminal olefins. Mechanistic studies show that electronic interactions play an important role in the stereodifferentiation. O O O O O O NBoc O O t-BuO2CH2CN O O O … 相似文献
72.
A New Triterpene from the Orchid Pholidota yunnanensis 总被引:2,自引:0,他引:2
ZhiMingBI ZhengTaoWANG LuoShanXU 《中国化学快报》2004,15(10):1179-1181
A new triterpene, 25-methylenecyclopholidonyl p-hydroxy-trans-cinnamate, was isolated from a orchid Pholidota yunnanensis. The structure elucidation and ^1H, ^13C-NMR assignments were achieved by spectral and chemical method. 相似文献
73.
Gui Hong YAN Da XING* Shi Ci TAN Institute of Laser Life Science South China Normal University Guangzhou 《中国化学快报》2004,15(1):101-104
Electrochemiluminescence (ECL), like other chemiluminescence technique, offers high signal-to-noise ratio. Furthermore, it has the advantage over other chemiluminescence techniques of being initiated by a voltage potential. Thus, it provides a better-controlled luminescence. This technique has been used in measuring many kinds of organic and inorganic matters, and analyzing many kinds of antigen, antibody and hapten, such as carcinoembryonic antigen and alpha-fetoprotein, etc1-6. The ele… 相似文献
74.
JianXinCAO YiFengWANG GuoFangLAI ShiDeLUO 《中国化学快报》2004,15(7):797-800
From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis. 相似文献
75.
76.
Let f be a smooth map between unit spheres of possibly different dimensions. We prove the global existence and convergence of the mean curvature flow of the graph of f under various conditions. A corollary is that any area‐decreasing map between unit spheres (of possibly different dimensions) is isotopic to a constant map. © 2004 Wiley Periodicals, Inc. 相似文献
77.
A simple model has been developed to describe the Zeeman patterns of far-infrared laser magnetic resonance spectra of the monobromomethyl radical CH2Br observed at 447.3 and 671.1μm. A satisfactory agreement between the experimental spectra of the radical and their simulation with this simple model has been achieved. This approach can be used to gain further information about the structure and the spectrum of this interesting radical. 相似文献
78.
Tao Liu Zuxiong Xu Zhongtao Zhao Ruzhang Ma Tiandou Hu Yaning Xie Yinghuan Guo 《中国科学A辑(英文版)》1997,40(4):395-399
The role of magnetoelastic coupling effects in nanocrystalline ferromagnets is investigated by means of high-field magnetization and Doppler-broadening spectrum measurements. For the nanocrystalline Fe73 5Cu1Nb3Si13.5B9 alloy, the results show that the pinning effects resulting from the quasidislocation dipole intensely influence the movement of domain wall; by coupling with the magnetostriction the defects-induced stress fields determine the magnetic properties at the early stage of crystallization. In view of the effective anisotropy and magnetoelastic coupling energy the optimal annealing conditions of alloys are discussed. 相似文献
79.
High-level ab initio calculations are carried out to study the relative stability of the two hydrogen bonded structures of water-hydrogen sulfide complex, one with water as the proton donor (A) and the other with hydrogen sulfide as the proton donor (B). The results show that structure A is considerably more stable than B at the correlated level, which is in contrast with previous results obtained from Hartree-Fock calculations. 相似文献
80.
罗尔定理证明一类存在性问题 总被引:1,自引:0,他引:1
提出罗尔定理证明一类存在性问题的方法,采用拉格朗日中值定理或柯西中值定理来证明这类问题往往需要构造精巧的辅助函数,我们还指出了这种方法的一般性. 相似文献