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Photocatalysis has been extensively studied due to its potential ability to avoid the excessive use of chemical reagents and reduce the energy consumption by employing solar energy. Moreover, to alleviate the reduction in the membrane permeation selectivity, separation efficiency, and membrane service life caused by the emerging micro-pollutants and membrane fouling, membrane technology is often coupled with microbial, electrochemical, and catalytic processes. However, although physical/chemical cleaning and membrane module replacement can overcome the inherent limitations caused by membrane fouling and other membrane separation processes, high operating costs limit their practical applications. In this review, common preparation methods for TiO2 photocatalytic membranes are described in detail, and the main approaches to enhancing their photocatalytic performance are discussed. More importantly, the mechanism of the TiO2 photocatalytic membrane antifouling process is elucidated, and some applications of photocatalytic membranes in other areas are described. This review systematically outlines future research directions in the field of photocatalytic membrane modification, including metal and non-metal doping, fabrication of heterojunction structures, control over reaction conditions, increase in hydrophilicity, and increase in membrane porosity. 相似文献
243.
Fashui?HongEmail author Xuefeng?Wang Chao?Liu Guoxing?Su Weiping?Song Kang?Wu Ye?Tao Guiwen?Zhao 《中国科学B辑(英文版)》2003,46(1):42-50
It was studied by spectroscopy that PSII reaction center complex consisting of three polypeptides, D1, D2 and Cytb559, were purified from PSII particle of CeCl3 treated spinach. The results of the experiment show that Ce3+ could improve the growth of spinach, and accelerate electron transport of PSII particles. Of chl-a of UV-Vis spectrum of
D1/D2/Cytb559 complex, Soret band was blue-shifted by 3 nm and Q band by 2 nm, respectively, and the fluorescence emission
peak was blue-shifted by 5 nm in CeCl3-treated spinach compared with the one in control. By the extended X-ray absorption fine structure (EXAFS) spectroscopy methods,
it has been found that Ce3+ is coordinated with 8 nitrogen atoms in the first coordination shell with Ce-N bond length of 0.253 nm, and Ce3+ with 6 oxygen atoms in the second coordination shell with Ce-O bond length of 0.32 nm. However, the secondary structure of
D1/D2/Cytb559 complex by circular dichroism (CD) spectroscopy has no significant change after CeCl3 treated. It might be that Ce3+ binds to porphyrin rings of chlorophyll and oxygen of amino acid residue of polypeptide in D1/D2/Cytb559 complex, and then
accelerates the primary reaction of PSII, intensifies function of P680+ primary electron donor of D1/D2/Cytb559, but there is little change in conformation of PSII reaction center complex. 相似文献
244.
This paper presents the results of an experimental study of natural convection heat transfer between a horizontal cylindrical envelope and an internal concentric heated square cylinder with two slots. The internal cylinder was a hollow one with horizontal slots on its top and bottom surfaces. The ratio of slot widthS to the side heightH was 0.0612 and 0.3878. The ratio of the envelope inner diameterD
o
to the side heightH was 2.653. Air was used as the working fluid. The range of Ray-leigh number was 1.77×1028.72×106 forS/H=0.0612 and 1.32×1026.25×106 forS/H=0.3878. The results show that there are three different heat transfer regimes in different Ray-leigh number regions, i.e. pure conduction regime, transition regime and convection regime. The average heat transfer results were correlated into two empirical equations. Comparison was made with the non-slotted case. It is found that slots of the internal cylinder can significantly enhance the heat transfer.
Nomenclature C p specific heat at constant pressure, J/(kg·K) - D i diameter of the related circular cylinder whose circumferential area is equal to that of the unslotted square cylinder, m - D o internal diameter of the outer circular envelope, m - F i surface area of the inner two slot cylinder, m - g gravitational acceleration, m/s2 - H distance between the opposite sides of the square cylinder with two slots, m - K eq dimensionless equivalent thermal conductivity - L axial length of the test section, m - m ratio of the area of the unslotted square cylinder surface to that of the slotted square cylinder - P pressure in the enclosure, Pa - Q total power input to the enclosure, W - Q cond radial heat conduction, W - Q conv convective heat transfer, W - Q r radiation heat transfer, W - Q los end heat dissipation, W - R air gas constant, J/(kg·K) - Ra Rayleigh number - S slot width, m - T i wall temperature of the inner cylinder, K - T o wall temperature of the outer envelope, K - T m mean temperature, K - T temperature difference=T i –T o , K - W maximum gap width of the test annuli=(D o –H)/2 for the square case, m Greek symbols 0 black body radiation constant, W/(m2·K4) - s equation system emissivity - air thermal conductivity, W/(m·K) - eq equivalent thermal conductivity, W/(m·K) - air dynamic viscosity, kg/(m·s) This work was supported by the National Natural Science Foundation of China. 相似文献
Experimentelle Untersuchung des Wärmeübergangs bei natürlicher Konvektion zwischen einer horizontalen zylindrischen Außenhülle und einem konzentrischen, beheizten, quadratischen Prisma mit zwei Schlitzen
Zusammenfassung In der Arbeit werden die Ergebnisse einer experimentellen Untersuchung des Wärmeübergangs bei natürlicher Konvektion zwischen einer horizontalen zylindrischen Außenhülle und einem beheizten quadratischen Prisma mit zwei Schlitzen vorgestellt. Das Prisma selbst ist hohl und weist in der oberen und unteren Begrenzungsfläche je einen horizontalen Längsschlitz auf. Das Verhältnis von SchlitzweiteS zu SeitenhöheH beträgt 0,0612 und 0,3878, das des HülleninnendurchmessersD o zur SeitenhöheH beträgt 2,653. Als Arbeitsmedium diente Luft. Die Rayleigh-Zahlen variierten zwischen 1,7·102 und 8,72·106 fürS/H=0,0612 und zwischen 1,32·102 und 6,25·106 fürS/H=0,3878. Die Ergebnisse belegen die Existenz dreier unterschiedlicher Wärmeübergangsregime in den verschiedenen Rayleigh-Zahl-Bereichen, und zwar reiner Leitungsbereich, Übergangsgebiet und Konvektionsbereich. Die Ergebnisse für den Wärmeübergang werden im Vergleich mit jenen für ein Prisma ohne Schlitze durch zwei Korrelationbeziehungen dargestellt. Es zeigt sich, daß durch Anbringung von Schlitzen am Innenprisma der Wärmeübergang wesentlich verstärkt werden kann.
Nomenclature C p specific heat at constant pressure, J/(kg·K) - D i diameter of the related circular cylinder whose circumferential area is equal to that of the unslotted square cylinder, m - D o internal diameter of the outer circular envelope, m - F i surface area of the inner two slot cylinder, m - g gravitational acceleration, m/s2 - H distance between the opposite sides of the square cylinder with two slots, m - K eq dimensionless equivalent thermal conductivity - L axial length of the test section, m - m ratio of the area of the unslotted square cylinder surface to that of the slotted square cylinder - P pressure in the enclosure, Pa - Q total power input to the enclosure, W - Q cond radial heat conduction, W - Q conv convective heat transfer, W - Q r radiation heat transfer, W - Q los end heat dissipation, W - R air gas constant, J/(kg·K) - Ra Rayleigh number - S slot width, m - T i wall temperature of the inner cylinder, K - T o wall temperature of the outer envelope, K - T m mean temperature, K - T temperature difference=T i –T o , K - W maximum gap width of the test annuli=(D o –H)/2 for the square case, m Greek symbols 0 black body radiation constant, W/(m2·K4) - s equation system emissivity - air thermal conductivity, W/(m·K) - eq equivalent thermal conductivity, W/(m·K) - air dynamic viscosity, kg/(m·s) This work was supported by the National Natural Science Foundation of China. 相似文献
245.
246.
van den Brand JF Ent R Anthony PL Arnold RG Arrington J Beise EJ Belz JE Bosted PE Bulten H Chapman MS Coulter KP Dietrich FS Epstein M Filippone BW Gao H Gearhart RA Geesaman DF Hansen J Holt RJ Jackson HE Jones CE Keppel CE Kinney ER Kuhn S Lee K Lorenzon W Lung A Makins NC Margaziotis DJ McKeown RD Milner RG Mueller B Napolitano J Nelson J O'Neill TG Papavassiliou V Petratos GG Potterveld DH Rock SE Spengos M Szalata ZM Tao LH van Bibber K Wasson DA White JL Zeidman B 《Physical review D: Particles and fields》1995,52(9):4868-4871
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248.
Makins NC Ent R Chapman MS Hansen J Lee K Milner RG Nelson J Arnold RG Bosted PE Keppel CE Lung A Rock SE Spengos M Szalata ZM Tao LH White JL Coulter KP Geesaman DF Holt RJ Jackson HE Papavassiliou V Potterveld DH Zeidman B Arrington J Beise EJ Belz E Filippone BW Gao H Lorenzon W Mueller B McKeown RD O'Neill TG Epstein M Margaziotis DJ Napolitano J Kinney E Anthony PL van Bibber K Dietrich FS Gearhart RA Patratos GG Kuhn SE van den Brand JF Bulten H Jones CE 《Physical review letters》1994,72(13):1986-1989
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