全文获取类型
收费全文 | 27999篇 |
免费 | 5001篇 |
国内免费 | 3808篇 |
专业分类
化学 | 19876篇 |
晶体学 | 368篇 |
力学 | 1933篇 |
综合类 | 214篇 |
数学 | 2975篇 |
物理学 | 11442篇 |
出版年
2024年 | 107篇 |
2023年 | 574篇 |
2022年 | 1018篇 |
2021年 | 1064篇 |
2020年 | 1200篇 |
2019年 | 1141篇 |
2018年 | 1046篇 |
2017年 | 945篇 |
2016年 | 1504篇 |
2015年 | 1402篇 |
2014年 | 1727篇 |
2013年 | 2105篇 |
2012年 | 2701篇 |
2011年 | 2634篇 |
2010年 | 1859篇 |
2009年 | 1771篇 |
2008年 | 2013篇 |
2007年 | 1739篇 |
2006年 | 1522篇 |
2005年 | 1316篇 |
2004年 | 961篇 |
2003年 | 774篇 |
2002年 | 760篇 |
2001年 | 634篇 |
2000年 | 531篇 |
1999年 | 525篇 |
1998年 | 405篇 |
1997年 | 353篇 |
1996年 | 384篇 |
1995年 | 350篇 |
1994年 | 278篇 |
1993年 | 210篇 |
1992年 | 218篇 |
1991年 | 203篇 |
1990年 | 180篇 |
1989年 | 141篇 |
1988年 | 115篇 |
1987年 | 84篇 |
1986年 | 71篇 |
1985年 | 66篇 |
1984年 | 48篇 |
1983年 | 40篇 |
1982年 | 25篇 |
1981年 | 23篇 |
1980年 | 10篇 |
1978年 | 3篇 |
1974年 | 4篇 |
1972年 | 3篇 |
1966年 | 2篇 |
1957年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
41.
C.X. Gao F.C. Yu S.Y. Jeong A.R. Choi P. Parchinskiy D.J. Kim H.J. Kim Y.E. Ihm C.G. Kim C.S. Kim 《Journal of magnetism and magnetic materials》2006
GaMnN and Be-codoped GaMnN were grown via molecular beam epitaxy using a single GaN precursor and their structural and magnetic properties were examined. X-ray diffraction and superconducting quantum interference device (SQUID) measurements revealed that the grown layers are homogeneous without precipitates. The saturation magnetization of GaMnN has increased from ∼4 to ∼16 emu/cm3 via codoping of Be. The d–d exchange interaction between Mn atoms was discussed for the ferromagnetism of GaMnN. 相似文献
42.
43.
The effect of γ-ray irradiation on the magnetic properties of NdFeB and Fe–Cr–Co permanent magnets has been investigated. The magnetic flux loss of two kinds of magnets before and after irradiation was measured. Results show that the effect of γ-ray irradiation on the magnetic properties of sintered NdFeB is not so obvious as that on Fe–Cr–Co magnet. Irradiation-induced damage from γ-ray for the Fe–Cr–Co magnets was characterized for the first time. The decline of permanent magnetic properties of Fe–Cr–Co magnet induced by γ-ray irradiation is reversible except for the maximum energy product (BH)max. The difference of coercivity mechanism between these two kinds of permanent magnets is responsible for the different dependence of magnetic properties loss induced by γ-ray irradiation. 相似文献
44.
分形维数与城市规模分布评析 总被引:3,自引:1,他引:2
本在分形概念的基础上,指出城市规模分布是基于统计意义上的一种分形分布,并计算了安徽省1978~1998年城市规模分布的分维值,评析了安徽省城市规模分布变化的特征。 相似文献
45.
Xiao Huang Bishwa Ranjan Nayak Tao Lu Lowe 《Journal of polymer science. Part A, Polymer chemistry》2004,42(20):5054-5066
A series of novel multifunctional hydrogels that combined the merits of both thermoresponsive and biodegradable polymeric materials were designed, synthesized, and characterized. The hydrogels were copolymeric networks composed of N‐isopropylacrylamide (NIPAAM) as a thermoresponsive component, poly(L‐lactic acid) (PLLA) as a hydrolytically degradable and hydrophobic component, and dextran as an enzymatically degradable and hydrophilic component. The chemical structures of the hydrogels were characterized by an attenuated total reflection–Fourier transform infrared spectroscopy (ATR–FTIR) technique. The hydrogels were thermoresponsive, showing a lower critical solution temperature (LCST) at approximately 32 °C, and their swelling properties strongly depended on temperature changes, the balance of the hydrophilic/hydrophobic components, and the degradation of the PLLA component. The degradation of the hydrogels caused by hydrolytic cleavage of ester bonds in the PLLA component was faster at 25 °C below the LCST than at 37 °C above the LCST, determined by the ATR–FTIR technique. Due to their multifunctional properties, the designed hydrogels show great potential for biomedical applications, including drug delivery and tissue engineering. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5054–5066, 2004 相似文献
46.
Urn模型的离散概率分布被用于构造逼近格式,具有Bernstein多项式的许多特性。本文用B网技术对Urn模型概率分布给出新的解释,指出了Urn模型B网的诸多性质,导出分布函数曲线的导数公式,构造了Urn分布的对偶基及与此相关的拟插值算子。 相似文献
47.
We describe one convenient synthesis route to boron nitride (BN) nanotube by the reaction of boron powder, iron oxide, and ammonium chloride at 600 °C for 12 h. Characterized by XRD, FTIR, XPS, TEM and SAED, the composition and morphology of the products are confirmed. The possible reaction mechanism is also discussed. 相似文献
48.
X. Y. Yang H. C. Gao X. L. Tan H. Z. Yuan G. Z. Cheng S. Z. Mao S. Zhao L. Zhang J. Y. An J. Y. Yu Y. R. Du 《Colloid and polymer science》2004,282(3):280-286
1H chemical shift changes of sodium 4-decyl naphthalene sulfonate (SDNS) at 313 K show that its critical micellar concentration lies between 0.82 and 0.92 mmol/dm3, which is in the same range as that of the previous study at 298 K. The spin–lattice relaxation time, spin–spin relaxation time and two-dimensional nuclear Overhauser enhancement spectroscopy experiments give information about the structure of the SDNS micelle and the dynamics of the molecules in the micelle. The size of the SDNS micelle remains almost unchanged in the temperature range from 298 to 313 K as deduced by analyzing the self-diffusion coefficient. Special arrangement of the naphthyl rings of SDNS in the micelles affects the packing of these hydrophobic chains. The methylene groups of the alkyl chain nearest the naphthalene groups penetrate into the aromatic region, which results in a more tightly packed hydrophobic micellar core than that of sodium dodecyl sulfonate. 相似文献
49.
A method has been described for the determination of arsenic species (arsenite and arsenate) by hydride generation-atomic fluorescence spectrometry (HG-AFS). The experimental conditions that influence the fluorescence intensity and the reduction of arsenic were investigated and optimized, and the influences from foreign ions and their elimination were studied. The detection limit was found to be 79.7 ng L(-1). The proposed method was applied to the determination of arsenic species in water leachate of traditional Chinese medicines with a recovery range of 91.1-109.5%. 相似文献
50.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献