全文获取类型
收费全文 | 261篇 |
免费 | 14篇 |
国内免费 | 3篇 |
专业分类
化学 | 166篇 |
晶体学 | 1篇 |
力学 | 20篇 |
数学 | 37篇 |
物理学 | 54篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 29篇 |
2021年 | 19篇 |
2020年 | 12篇 |
2019年 | 16篇 |
2018年 | 12篇 |
2017年 | 8篇 |
2016年 | 14篇 |
2015年 | 9篇 |
2014年 | 6篇 |
2013年 | 15篇 |
2012年 | 22篇 |
2011年 | 18篇 |
2010年 | 12篇 |
2009年 | 15篇 |
2008年 | 19篇 |
2007年 | 9篇 |
2006年 | 6篇 |
2005年 | 4篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 3篇 |
2000年 | 5篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有278条查询结果,搜索用时 15 毫秒
11.
Sajid Muhammad Munir Shad Naveed Akthar Javed Yasir Khan Sadaf Bashir Zhang Zhengjun Amin Nasir 《Research on Chemical Intermediates》2020,46(2):1201-1215
Research on Chemical Intermediates - We prepared unique BiVO4/reduce graphene oxide (BiVO4/rGO) nanocomposite with enhanced photocatalytic ability by hydrothermal method applying... 相似文献
12.
Hicham Mahfoz Kotb Mohamad Mahmoud Ahmad Sajid Ali Ansari Tarek S. Kayed Adil Alshoaibi 《Molecules (Basel, Switzerland)》2022,27(3)
In the current study, we report on the dielectric behavior of colossal-dielectric-constant Na1/2La1/2Cu3Ti4O12 (NLCTO) ceramics prepared by mechanochemical synthesis and spark plasma sintering (SPS) at 850 °C, 900 °C, and 925 °C for 10 min. X-ray powder diffraction analysis showed that all the ceramics have a cubic phase. Scanning electron microscope observations revealed an increase in the average grain size from 175 to 300 nm with an increase in the sintering temperature. SPS NLCTO ceramics showed a room-temperature colossal dielectric constant (>103) and a comparatively high dielectric loss (>0.1) over most of the studied frequency range (1 Hz–40 MHz). Two relaxation peaks were observed in the spectra of the electrical modulus and attributed to the response of grain and grain boundary. According to the Nyquist plots of complex impedance, the SPS NLCTO ceramics have semiconductor grains surrounded by electrically resistive grain boundaries. The colossal dielectric constant of SPS NLCTO ceramics was attributed to the internal barrier layer capacitance (IBLC) effect. The high dielectric loss is thought to be due to the low resistivity of the grain boundary of SPS NLCTO. 相似文献
13.
M. Sajid 《Numerical Methods for Partial Differential Equations》2010,26(1):221-228
This article investigates the analytic solution for the flow of a third grade fluid past an infinite porous plate. The method of parameter differentiation is used to linearized the governing flow equation. The solution of the obtained linear equation is developed by differential transform method in combination with the method of superposition. The obtained results are compared with existing results in the literature and an excellent agreement is found. This shows that the parameter differentiation is a powerful technique for solving nonlinear problems. © 2009 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2010 相似文献
14.
A complete normal coordinate analysis was performed for five-coordinate non-rigid triarylantimony diester SbPh3(O2CR)2, known to be a bioactive molecule, using Wilson G-F matrix method and Urey Bradley force field. The study of vibrational
dynamics was performed using the concept of group frequencies and band intensities.
相似文献
15.
Afaq Shagufta Khan Sadia Kazmi Mehdi Hassan Fatima Itrat Malik Abdul Inamullah Farah Farhad Zahid Abbas Tanveer Tareen Rasool Bakhsh 《Chemistry of Natural Compounds》2021,57(2):269-273
Chemistry of Natural Compounds - Armatans A (1) and B (2), new isoflavans, have been isolated from the EtOAc-soluble fraction of the MeOH extract of Colutea armata Hemsl. & Lace, along with... 相似文献
16.
Kinetics of D-mannose oxidation by cerium (IV) was studied in a sulfuric acid medium at 40℃ both in absence and presence of ionic micelles. In both cases, the rate of the reaction was first-order in D-mannose and in cerium(Ⅳ), which decreased with increasing [H2SO4]. This suggested that the redox reaction followed the same mechanism. The reaction proceeded through formation of an intermediate complex, which was proved by kinetic method. The complex underwent slow unimolecular decomposition to a free radical that reacted with cerium (Ⅳ) to afford the product. The catalytic role of cationic cetyltrimethylammonium bromide (CTAB) micelles was best explained by the Menger-Portnoy model. The study of the effect of CTAB also indicated that a negatively charged species was reactive form of cerium (Ⅳ). From the kinetic data, micelle-cerium (Ⅳ) binding and rate constants in micellar medium were evaluated.The anionic micelle of sodium dodecyl sulfate plays no catalytic role. The oxidation has the rate expression: --d[Ce(Ⅳ)]= k1Kcl[D-mannose] [Ce(Ⅳ)]dt Different activation parameters for micelle catalyzed and uncatalyzed paths were also calculated and discussed. 相似文献
17.
This article looks at the hydrodynamic elastico-viscous fluid over a stretching surface. The equations governing the flow are reduced to ordinary differential equations, which are analytically solved by applying an efficient technique namely the homotopy analysis method (HAM). The solutions for the velocity components are computed. The numerical values of wall skin friction coefficients are also tabulated. The present HAM solution is compared with the known exact solution for the two-dimensional flow and an excellent agreement is found. 相似文献
18.
This Letter looks at the rotating flow of a second grade fluid past a porous shrinking surface. The fluid is electrically conducting in the presence of a constant applied magnetic field. The governing partial differential equations are first reduced into ordinary differential equations and then solved by homotopy analysis method (HAM). Convergence of the series solution is shown explicitly. In addition, the obtained results are illustrated graphically to indicate the effects of the pertinent physical parameters. 相似文献
19.
We have theoretically investigated two-dimensional atom localization using the absorption spectra of birefringence beams of light in a single wavelength domain.The atom localization is controlled and modified through tunneling effect in a conductive chiral atomic medium with absorption spectra of birefringent beams.The significant localization peaks are investigated in the left and right circularly polarized beam.Single and double localized peaks are observed in different quadrants with minimum uncertainty and significant probability.The localized probability is modified by controlling birefringence and tunneling conditions.These results may be useful for the capability of optical microscopy and atom imaging. 相似文献
20.
Tanveer Hussain Bokhari Muhammad Bilal Butt Saira Hina Munawar Iqbal Muhammad Daud Muhammad Imran 《Journal of Radioanalytical and Nuclear Chemistry》2017,314(3):1487-1496
The field of therapeutic nuclear medicine is emerging rapidly as choice of treatment in oncology and other cellular malignancies. The growth of this branch of nuclear medicine is greatly facilitated by the introduction of a number of new radiopharmaceuticals and radionuclides. 90Y-radiopharmaceuticals have confirmed their worth in medical and clinical areas in a very short span of time. The 90Y is a radioisotope widely used for therapeutic purposes and considerable perfection has been made to understand the chemistry of 90Y-labeled radiopharmaceuticals. The development of these radiopharmaceuticals can be made favorable by using appropriate buffer, incubation period, optimal pH, specific activity and reaction temperature. In this review, we have discussed the preparation of range of 90Y transporting biological molecules such as antibodies radiolabeled peptides, antigens and microsphere with their clinical applications. 相似文献