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191.
Nobuhiro Kosugi Toshihiko Yokoyama Kiyotaka Asakura Haruo Kuroda 《Chemical physics》1984,91(2):249-256
To elucidate the origin of the shoulder structure which is known to appear about half-way up the Cu K-edge in the X-ray absorption spectra of Cu(II) compounds, polarized X-ray absorption spectra were measured on the single crystal of (creatinium)2CuCl4 by using synchrotron radiation. The transition responsible for the shoulder structure was found to be exclusively polarized in the direction normal to the molecular plane of the CuCl42? ion. The polarization dependence of other structures in the XANES spectra was also examined and compared with the results of ab initio SCF CI calculation. It is shown that the structure half-way up the Cu K-edge is due to the shake-down accompanying the 1s-4p= excitation, arising from the ligand-to-metal charge transfer induced by the core-hole creation. Structures attributable to the shake-down accompanying the 1s-4pσ and 1s-5p=, σ excitations were also found. 相似文献
192.
In the X (3872) decay, both of the ${{J/{\psi\pi\pi}}}$ and ${{J/{\psi\pi\pi\pi}}}$ branching fractions are observed experimentally, and their sizes are comparable to each other. In order to clarify the mechanism to cause such a large isospin violation, we investigate X(3872) employing a model of coupled-channel two-meson scattering with a ${{\rm c}\bar{c}}$ core. The two-meson states consist of ${{D^0\overline{D}^{*0}}}$ , D + D *?, ${{J/{\psi\rho}}}$ , and ${{J/{\psi\omega}}}$ . The effects of the ρ and ω meson width are also taken into account. We calculate the transfer strength from the ${{{\rm c}\bar{c}}}$ core to the final two-meson states. It is found that very narrow ${{J/{\psi\rho}}}$ and ${{J/{\psi\omega}}}$ peaks appear very close to the ${{D^0\overline{D}^{*0}}}$ threshold for a wide range of variation in the parameter sets. The size of the ${{J/{\psi\rho}}}$ peak is almost the same as that of ${{J/{\psi\omega}}}$ , which is consistent with the experiments. The large width of the ρ meson makes the originally small isospin violation by about five times larger. 相似文献
193.
Giant platinum-acetylides dendrimers were precisely synthesized by a divergent method; the sixth generation dendrimer, the diameter of which is larger than 10 nm, has 189 Pt atoms per molecule, and its molecular weight is as high as 139750. 相似文献
194.
195.
A hexapeptide motif, RKLPDA, that recognizes the surface of titanium was identified from a peptide phage selection. Mutational analyses showed electrostatic interaction was a major factor in the binding, paving a new way to modify the surface of Ti with active biomolecules. 相似文献
196.
197.
Matsushima Y Onitsuka K Takahashi S 《Dalton transactions (Cambridge, England : 2003)》2004,(4):547-553
The reaction of planar-chiral cyclopentadienyl-ruthenium complexes with Bu4NI resulted in the formation of iodo complexes with high diastereoselectivity (up to >99%de). The stereochemistry of the ruthenium center in the starting material did not influence the diastereoselectivity of the products. Epimerization of a diastereomerically pure sample gave a mixture of two diastereomers in the same ratio as with the ligand-exchange reaction, suggesting that the selectivity is determined by the difference in thermodynamic stability between the diastereomeric pair of iodo complexes. The ratio of the products depends on the nature of the substituent on the cyclopentadienyl ring and P ligands on the ruthenium atom. A combination of small substituents on the cyclopentadienyl group and small P ligands with strong electron-donating ability favored the formation of 2-I. The bulkiness of the substituents on the cyclopentadienyl group or of the P ligands, and low electron-donating ability of the P ligands increased the ratio of 2-II complexes to 2-I isomer. 相似文献
198.
N. Tsuchihashi T. Enomoto K. Tanikawa A. Tajiri und M. Hatano 《Colloid and polymer science》1977,255(11):1141
Ohne Zusammenfassung 相似文献
199.
200.
Metallophthalocyanine derivatives with polymerizable vinyl groups were synthesized, characterized and polymerized. Preliminary results on their Langmuir-Blodgett (LB) film formation and the electronic properties of (Indium-Tin Oxide/LB-film/Al) Schottky devices were reported. 相似文献