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991.
Dr. Man‐Sheng Chen Xiong‐Wen Tan Dr. Chun‐Hua Zhang Dai‐Zhi Kuang 《无机化学与普通化学杂志》2011,637(9):1220-1223
A new three‐dimensional (3D) porous framework [Zn(INAIP)] · DMA · H2O ( 1 ) [INAIP = 5‐(isonicotinamido)isophthalate, DMA = N,N′‐dimethylacetamide] was synthesized by solvothermal methods and characterized by single‐crystal and powder X‐ray diffraction, as well as thermogravimetric analysis. The results of X‐ray diffraction analyses revealed that complex 1 has an unusual 3D architecture with the (3,6)‐connected rutile ( rtl ) topology. The adsorption behavior shows that compound 1 exhibits selective adsorptions of CO2 over N2 after the removal of the solvent molecules within the pores. 相似文献
992.
Noorzalila Muhammad Niza Kok Tat Tan Zainal Ahmad Keat Teong Lee 《Chemical Papers》2011,65(5):721-729
In this study, biodiesel has been successfully produced by transesterification using non-catalytic supercritical methanol
and methyl acetate. The variables studied, such as reaction time, reaction temperature and molar ratio of methanol or methyl
acetate to oil, were optimised to obtain the optimum yield of fatty acid methyl ester (FAME). Subsequently, the results for
both reactions were analysed and compared via Response Surface Methodology (RSM) analysis. The mathematical models for both
reactions were found to be adequate to predict the optimum yield of biodiesel. The results from the optimisation studies showed
that a yield of 89.4 % was achieved for the reaction with supercritical methanol within the reaction time of 27 min, reaction
temperature of 358°C, and methanol-to-oil molar ratio of 44. For the reaction in the presence of supercritical methyl acetate,
the optimum conditions were found to be: reaction time of 32 min, reaction temperature of 400°C, and methyl acetate-to-oil
molar ratio of 50 to achieve 71.9 % biodiesel yield. The differences in the behaviour of methanol and methyl acetate in the
transesterification reaction are largely due to the difference in reactivity and mutual solubility of Jatropha curcas oil and methanol/methyl acetate. 相似文献
993.
The mechanical properties of hybrid framework materials, including both nanoporous metal-organic frameworks (MOFs) and dense inorganic-organic frameworks, are discussed in this critical review. Although there are relatively few studies of this kind in the literature, major recent advances in this area are beginning to shed light on the fundamental structure-mechanical property relationships. Indeed research into the mechanical behavior of this important new class of solid-state materials is central to the design and optimal performance of a multitude of technological applications envisaged. In this review, we examine the elasticity of hybrid frameworks by considering their Young's modulus, Poisson's ratio, bulk modulus and shear modulus. This is followed by discussions of their hardness, plasticity, yield strength and fracture behavior. Our focus is on both experimental and computational approaches. Experimental work on single crystals and amorphized monoliths involved primarily the application of nanoindentation and atomic force microscopy to determine the elastic moduli and hardness properties. The compressibility and bulk moduli of single crystals and polycrystalline powders were studied by high-pressure X-ray crystallography in the diamond anvil cell, while in one instance spectroscopic ellipsometry has also been used to estimate the elastic moduli of MOF nanoparticles and deposited films. Theoretical studies, on the other hand, encompassed the application of first principles density-functional calculations and finite-temperature molecular dynamics simulations. Finally, by virtue of the diverse mechanical properties achievable in hybrid framework materials, we propose that a new domain be established in the materials selection map to define this emerging class of materials (137 references). 相似文献
994.
Cai X Tan S Lin M Xie A Mai W Zhang X Lin Z Wu T Liu Y 《Langmuir : the ACS journal of surfaces and colloids》2011,27(12):7828-7835
A water-soluble brilliant blue/reduced graphene oxide/tetradecyltriphenylphosphonium bromide composite (BB-rGO-TTP) was prepared by using noncovalent brilliant blue-functionalized reduced graphene oxide (BB-rGO) as the tetradecyltriphenylphosphonium bromide (TTP) carrier. Antibacterial performance of this novel composite was investigated for both Gram-positive and Gram-negative bacteria. The results showed that the novel BB-rGO-TTP, combing the advantages of graphene and TTP, displayed excellent synergistic antibacterial activity, specific targeting capability, water solubility, and mild cytotoxicity, suggesting the great potential application as sprayable graphene-based antibacterial solutions. 相似文献
995.
Gang Lian Xiao Zhang Lingling Zhu Miao Tan Deling Cui Qilong Wang 《Research on Chemical Intermediates》2011,37(2-5):369-374
In this paper, combining the hydrothermal method and halide species-inducing effect, we reported cubic-phase BN microcrystals synthesized in hydrothermal condition with N(CH3)3 as nitrogen source. These polyhedral microcrystals presented nearly regular octahedral shapes of 0.5?C1.5 ??m in average size. 相似文献
996.
Zhang Y Qin W Tang H Yan F Tan L Xie Q Ma M Zhang Y Yao S 《Colloids and surfaces. B, Biointerfaces》2011,87(2):346-352
CdSe/ZnS core-shell quantum dots (QDs) were efficiently tethered onto polyamidoamine dendrimer-modified multi-walled carbon nanotubes (MWCNTs) by covalent linkage and mercapto-mediated assembly. The obtained MWCNT-QD hybrids were both photophysically and morphologically characterized. The QDs are well-distributed on single nanotube surface in high density and the assembly of QDs onto MWCNTs does not change the fluorescence emission wavelength of QDs but significantly decreases the emission density. Cytotoxicity of MWCNT-QD hybrids to HeLa cells and their fluorescence property in living cell system were evaluated in detail. The hybrids show a little effect on cell viability even at very high concentration (100 μg mL(-1)). Moreover, they possess intense red fluorescence signal under optical fluorescence microscopy and good fluorescence stability over 72-h exposure in living cell system. 相似文献
997.
Jing?Zhao Zi-Tao?JiangEmail author Jin?Tan Rong?Li 《Journal of Sol-Gel Science and Technology》2011,58(2):436-441
Monolithic titania materials with macro-mesoporosity bimodal texture have been prepared through a template-free sol–gel approach,
based on the reaction of hydrolysis and polycondensation of titanium isopropoxide promoted by the slow released water from
esterification between acetic acid and methanol under a strong acidic condition. With the coarsening of the titania oligomers,
phase separation and sol–gel transition processes take place so as to form a homogeneous gel system that will change into
a monolith after aging, drying and heat treatment. The synthesized titania monolith possesses a specific surface area of 77 m2 g−1 (calcined at 350 °C), an anatase with partly rutile crystallite structure and great mechanical strength. The synthesis method
applied here is simple and easy to implement as no extra chemical modifier such as poly(ethylene oxide) (PEO) and formamide
is needed to control the process. The properties of biomodal porous structure, satisfactory surface area and high mechanical
strength will enable the monolith to be served as a chromatography column to separate phosphorus organo-compounds. 相似文献
998.
以内源荧光光谱和荧光相图法研究了脲和盐酸胍诱导的卵清溶菌酶分子的去折叠过程,结果表明,当变性液中脲和盐酸胍的浓度分别约为4.0和3.0 mol/L时,卵清溶菌酶分子的去折叠过程均存在一个折叠中间态,这两个去折叠过程均符合"三态模型".在卵清溶菌酶分子"三态"去折叠过程的基础上,通过变性剂分子和卵清溶菌酶分子之间的缔合一... 相似文献
999.
Uncaria sinensis (Oliv.) Havil (Rubiaceae) has been used as an important Traditional Chinese Medicine (TCM) herb for the treatment of fevers and various nervous disorders. The major bioactive secondary metabolites from different classes of chemical compounds, i.e. organic acid, flavonoid and alkaloid, present in this TCM herb, namely catechin, caffeic acid, epicatechin and rhynchophylline, were extracted by microwave-assisted extraction (MAE) method with ultra-pure water as the extraction solvent. The optimal extraction conditions for this green solvent MAE method were found to be 100 °C for 20 min. The recoveries of the compounds were found to be comparable to that of heating under reflux using ultra-pure water for 60 min. The method precision (RSD, n = 6) was found to vary from 0.19% to 5.60% for the proposed method on different days for the secondary metabolites. Simultaneously, the key primary metabolites such as sucrose and phenylalanine for the biosynthesis of bioactive secondary metabolites were successfully characterized by GC-MS. Furthermore, an approach using the combination of primary and secondary metabolite profiling based on their chemical fingerprints with Principal Component Analysis (PCA) was successfully developed to evaluate the quality of U. sinensis obtained from different sources. This approach was shown to be feasible in discriminating U. sinensis from different origins and thus a potential application for the quality control of other medicinal herbs. 相似文献
1000.