全文获取类型
收费全文 | 94538篇 |
免费 | 2549篇 |
国内免费 | 145篇 |
专业分类
化学 | 55862篇 |
晶体学 | 467篇 |
力学 | 1779篇 |
综合类 | 3篇 |
数学 | 17026篇 |
物理学 | 22095篇 |
出版年
2022年 | 697篇 |
2021年 | 1030篇 |
2020年 | 1316篇 |
2019年 | 1137篇 |
2018年 | 1848篇 |
2017年 | 1569篇 |
2016年 | 2897篇 |
2015年 | 2405篇 |
2014年 | 2536篇 |
2013年 | 5450篇 |
2012年 | 4907篇 |
2011年 | 5172篇 |
2010年 | 3172篇 |
2009年 | 2735篇 |
2008年 | 4703篇 |
2007年 | 4503篇 |
2006年 | 4046篇 |
2005年 | 3842篇 |
2004年 | 3212篇 |
2003年 | 2727篇 |
2002年 | 2448篇 |
2001年 | 1923篇 |
2000年 | 1864篇 |
1999年 | 1326篇 |
1998年 | 1081篇 |
1997年 | 1025篇 |
1996年 | 1235篇 |
1995年 | 991篇 |
1994年 | 1104篇 |
1993年 | 1098篇 |
1992年 | 1019篇 |
1991年 | 831篇 |
1990年 | 896篇 |
1989年 | 762篇 |
1988年 | 749篇 |
1987年 | 689篇 |
1986年 | 663篇 |
1985年 | 980篇 |
1984年 | 940篇 |
1983年 | 793篇 |
1982年 | 837篇 |
1981年 | 843篇 |
1980年 | 731篇 |
1979年 | 679篇 |
1978年 | 730篇 |
1977年 | 687篇 |
1976年 | 672篇 |
1975年 | 599篇 |
1974年 | 587篇 |
1973年 | 602篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
71.
A. Ferreira da Silva I. Pepe S.A. Tomás W.M. de Azevedo R. Ahuja 《Applied Surface Science》2006,252(15):5365-5367
In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO2) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO2 thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO2 absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO2 are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO2 films prepared for undoped sol-gels and by sputtering is performed. 相似文献
72.
von Eynatten G. Ritter T. Bömmel H. E. Dransfeld K. 《Zeitschrift für Physik B Condensed Matter》1987,65(3):341-345
A new model is presented which explains well the dramatic decrease of the Mössbauer line intensities with raising temperatures for freely dispersed iron microscrystals. In contrast to other theories which consider mainly vibration to be responsible we discuss here the decrease in terms of large amplitude diffusive rotational or translational jumps of the particles. Such diffusive jumps lead — in agreement with the observation — to a strong reduction of the Mössbauer-intensity without broadening the line width in a noticeable way. The typical potential well for a diffusing particle in an equilibrium position is derived quantitatively to be 13 meV. The model might be important also for a new understanding of the dynamics of catalytic clusters either in contact with each other or with larger solid surfaces.Part of this work was supported by the DFG Sonderforschungsbereich 306, Konstanz 相似文献
73.
Márton Kiss 《Acta Mathematica Hungarica》2006,110(3):253-259
Summary New results for the eigenvalue ratios of vibrating strings are presented partially in connection with previous results concerning
Schr?dinger operators. 相似文献
74.
In this note we study uncertainty sequencing situations, i.e., one-machine sequencing situations in which no initial order
is specified. We associate cooperative games with these sequencing situations, study their core, and provide links with the
classic sequencing games introduced by Curiel et al. (Eur J Oper Res 40:344–351, 1989). Moreover, we propose and characterize
two simple cost allocation rules for uncertainty sequencing situations with equal processing times. 相似文献
75.
N. Hegyvári 《Acta Mathematica Hungarica》1989,53(1-2):149-154
76.
In [3] it was shown that a (real) signed measure on a cyclic coarse-grained quantum logic can be extended, as a signed measure,
over the entire power algebra. Later ([9]) this result was re-proved (and further improved on) and, moreover, the non-negative
measures were shown to allow for extensions as non-negative measures. In both cases the proof technique used was the technique
of linear algebra. In this paper we further generalize the results cited by extending group-valued measures on cyclic coarse-grained
quantum logics (or non-negative group-valued measures for lattice-ordered groups). Obviously, the proof technique is entirely
different from that of the preceding papers. In addition, we provide a new combinatorial argument for describing all atoms
of cyclic coarse-grained quantum logics. 相似文献
77.
Specific molecules in cardiac tissue of spontaneously hypertensive rats are studied by using time-of-flight secondary ion mass spectrometry (TOF-SIMS). The investigation determines phospholipids, cholesterol, fatty acids and their fragments in the cardiac tissue, with special focus on cardiolipin. Cardiolipin is a unique phospholipid typical for cardiomyocyte mitochondrial membrane and its decrease is involved in pathologic conditions. In the positive polarity, the fragments of phosphatydilcholine are observed in the mass region of 700-850 u. Peaks over mass 1400 u correspond to intact and cationized molecules of cardiolipin. In animal tissue, cardiolipin contains of almost exclusively 18 carbon fatty acids, mostly linoleic acid. Linoleic acid at 279 u, other fatty acids, and phosphatidylglycerol fragments, as precursors of cardiolipin synthesis, are identified in the negative polarity. These data demonstrate that SIMS technique along with Au3+ cluster primary ion beam is a good tool for detection of higher mass biomolecules providing approximately 10 times higher yield in comparison with Au+. 相似文献
78.
We study the spectral properties of a large class of compact flat Riemannian manifolds of dimension 4, namely, those whose
corresponding Bieberbach groups have the canonical lattice as translation lattice. By using the explicit expression of the
heat trace of the Laplacian acting on p-forms, we determine all p-isospectral and L-isospectral pairs and we show that in this class of manifolds, isospectrality on functions and isospectrality on p-forms for all values of p are equivalent to each other. The list shows for any p, 1 ≤ p ≤ 3, many p-isospectral pairs that are not isospectral on functions and have different lengths of closed geodesics. We also determine
all length isospectral pairs (i.e. with the same length multiplicities), showing that there are two weak length isospectral
pairs that are not length isospectral, and many pairs, p-isospectral for all p and not length isospectral.
Mathematics Subject Classifications (2000): 58J53, 58C22, 20H15. 相似文献
79.
Summary The gas chromatographic behaviour of crosslinked macroporous 2-hydroxyethyl methacrylate grafted with 2-methyloxazoline was
investigated and the range of applicability of the copolymer was assessed. Retention index values were measured on this copolymer
and compared with those obtained on the terpolymer 2-hydroxyethyl methacrylate-ethylene dimethacrylate-acrylonitrile. Rohrschneider
constants and efficiency data for selected sorbates are given. The use of this type of polymer in the separation of various
types of compounds is documented by various examples. 相似文献
80.
Leong‐Huat Gan Palaniswamy Ravi Bao Wei Mao Kam‐Chiu Tam 《Journal of polymer science. Part A, Polymer chemistry》2003,41(17):2688-2695
Polymerization of 2‐(diethylamino)ethyl methacrylate (DEAEMA) via homogeneous atom transfer radical polymerization under various reaction conditions is described. The effects of the initiators and solvents were examined. With 1,1,4,7,10,10‐hexamethyl triethylenetetramine/copper(I) chloride/p‐toluenesulfonyl chloride as the ligand/catalyst/initiator system in methanol, poly(DEAEMA) with a polydispersity index as low as 1.07 was synthesized. Kinetic studies demonstrated the polymerization was very well controlled and exhibited the living characteristic of the process. Well‐defined block copolymers of DEAEMA and tert‐butyl methacrylate (tBMA) were successfully synthesized. The copolymers could be synthesized with equally good results by starting with either p(DEAEMA) or p(tBMA) as the macroinitiators. However, only the macroinitiators terminated with chlorine should be used. The corresponding macroinitiators with bromine as a transferable group did not yield well‐defined copolymers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2688–2695, 2003 相似文献