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61.
Pál Sohár Gábor Bernáth Géza Stájer Angela E. Szabo 《Magnetic resonance in chemistry : MRC》1989,27(9):872-876
Pentacyclic isoxazolines were obtained by the cycloaddition of benzonitrile oxide to norbornene-azetidinone-fused 3,1-oxazines. The constitutions of two of the isomers obtained, and the configurations and conformations of all products, were determined by means of 1H and 13C NMR spectroscopy and DNOE experiments. 相似文献
62.
63.
We present a new verified optimization method to find regions for Hénon systems where the conditions of chaotic behaviour
hold. The present paper provides a methodology to verify chaos for certain mappings and regions. We discuss first how to check
the set theoretical conditions of a respective theorem in a reliable way by computer programs. Then we introduce optimization
problems that provide a model to locate chaotic regions. We prove the correctness of the underlying checking algorithms and
the optimization model. We have verified an earlier published chaotic region, and we also give new chaotic places located
by the new technique. 相似文献
64.
Potential for micromachined actuation of ultra-wide continuously tunable optoelectronic devices 总被引:1,自引:0,他引:1
H. Hillmer J. Daleiden C. Prott F. Römer S. Irmer V. Rangelov A. Tarraf S. Schüler M. Strassner 《Applied physics. B, Lasers and optics》2002,75(1):3-13
Tailored scaling represents a principle of success that, both in nature and in technology, allows the effectiveness of physical
effects to be enhanced. Mutation and selection in nature are imitated in technology, e.g. by model calculation and design.
Proper scaling of dimensions in natural photonic crystals and our fabricated artificial 1D photonic crystals (DBRs, distributed
Bragg reflectors) enable efficient diffractive interaction in a specific spectral range. For our optical microsystems we illustrate
that tailored miniaturization may also increase the mechanical stability and the effectiveness of spectral tuning by thermal
and electrostatic actuation, since the relative significance of the fundamental physical forces involved considerably changes
with scaling. These basic physical principles are rigorously applied in micromachined 1.55-μm vertical-resonator-based devices.
We modeled, implemented and characterized 1.55-μm micromachined optical filters and vertical-cavity surface-emitting laser
devices capable of wide, monotonic and kink-free tuning by a single control parameter. Tuning is achieved by mechanical actuation
of one or several air-gaps that are part of the vertical resonator including two ultra-highly reflective DBR mirrors of strong
refractive index contrast: (i) Δn=2.17 for InP/air-gap DBRs (3.5 periods) using GaInAs sacrificial layers and (ii) Δn=0.5
for Si3N4/SiO2 DBRs (12 periods) with a polymer sacrificial layer to implement the air-cavity. In semiconductor multiple air-gap filters,
a continuous tuning of >8% of the absolute wavelength is obtained. Varying the reverse voltage (U=0–5 V) between the membranes
(electrostatic actuation), a tuning range of >110 nm was obtained for a large number of devices. The correlation of the wavelength
and the applied voltage is accurately reproducible without any hysteresis. In two filters, tuning of 127 and 130 nm was observed
for about ΔU=7 V. The extremely wide tuning range and the very small voltage required are record values to the best of our
knowledge. For thermally actuated dielectric filters based on polymer sacrificial layers, Δλ/ΔU=-7 nm/V is found.
Received: 10 May 2002 / Published online: 8 August 2002 相似文献
65.
66.
Electronic properties of model quantum-dot structures in zero and finite magnetic fields 总被引:1,自引:0,他引:1
H. Saarikoski E. Räsänen S. Siljamäki A. Harju M.J. Puska R.M. Nieminen 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,26(2):241-252
We have computed electronic structures and total energies of circularly confined two-dimensional quantum dots and their lateral
dimers in zero and finite uniform external magnetic fields using different theoretical schemes: the spin-density-functional
theory (SDFT), the current-and-spin-density-functional theory (CSDFT), and the variational quantum Monte Carlo (VMC) method.
The SDFT and CSDFT calculations employ a recently-developed, symmetry-unrestricted real-space algorithm allowing solutions
which break the spin symmetry. Results obtained for a six-electron dot in the weak confinement limit and in zero magnetic
field as well as in a moderate confinement and in finite magnetic fields enable us to draw conclusions about the reliability
of the more approximative SDFT and CSDFT schemes in comparison with the VMC method. The same is true for results obtained
for the two-electron quantum dot dimer as a function of inter-dot distance. The structure and role of the symmetry-breaking
solutions appearing in the SDFT and CSDFT calculations for the above systems are discussed.
Received 16 October 2001 and Received in final form 17 January 2002 相似文献
67.
W. Hufenbach R. Böhm A. Langkamp L. Kroll T. Ritschel 《Mechanics of Composite Materials》2006,42(2):151-162
The basic damage and failure models of multiaxially reinforced composites with a thermoplastic matrix are presented and verified.
Within the framework of continuum damage mechanics, a phenomenological model is introduced, where the damage is defined as
a change in the elasticity tensor. For damage identification, a specific ultrasonic device was developed. A combination of
an immersion set-up and a contact coupling device formed a system for an efficient determination of stiffness-tensor components
from convenient sets of velocity measurements. Linked to a tensile machine, it allowed us to measure the anisotropic damage
of the new materials group caused by tensile loading.
Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 2, pp. 221–234, March–April, 2006. 相似文献
68.
Let T be a suitable system of classical set theory. We will show, that the Σ1 spectrum of T, i.e. the set of ordinals having good Σ1 definition in T is an initial segment of the ordinals.
Received: 11 October 1999 / Published online: 12 December 2001 相似文献
69.
Csilla Bujtás 《Discrete Applied Mathematics》2007,155(11):1395-1407
For a mixed hypergraph H=(X,C,D), where C and D are set systems over the vertex set X, a coloring is a partition of X into ‘color classes’ such that every C∈C meets some class in more than one vertex, and every D∈D has a nonempty intersection with at least two classes. A vertex-orderx1,x2,…,xn on X (n=|X|) is uniquely colorable if the subhypergraph induced by {xj:1?j?i} has precisely one coloring, for each i (1?i?n). We prove that it is NP-complete to decide whether a mixed hypergraph admits a uniquely colorable vertex-order, even if the input is restricted to have just one coloring. On the other hand, via a characterization theorem it can be decided in linear time whether a given color-sequence belongs to a mixed hypergraph in which the uniquely colorable vertex-order is unique. 相似文献
70.
L. Kováč 《Applied magnetic resonance》2007,31(1-2):11-28
The life course of the physicist and biologist George Feher may be seen as an epitome of science of the second half of the 20th century and the beginning of the 21st century. Feher, a native of Slovakia, barely escaped Nazism and communism and became a scientist in the USA. The Nazi concentration camps and the communist gulags have become a symbol of the 20th century. This symbol stands here to pose a question: How the two totalitarian systems, fraught with irrationality, may have arisen and thrived in parallel with an unprecedented expansion of science, the paragon of rationalism? The question has become even more urgent in the 21st century. The Ground Zero, an empty spot left after the collapse of the twin towers of the World Trade Center on 11 September 2001, has become the symbol of the entrance of humankind into the new millennium. We can do much, but we understand too little about who we are and what we are doing — this is a message that the two symbols convey about the precarious stage of our evolution. The second message concerns the role of artifacts, specifically scientific instruments, in the advancement of science. Human cultural evolution has been steadily progressing, in a form of a ratchet, only because artifacts have been continually evolving. Contrary to the common Popperian wisdom, the demarcation in science may not consist in the amenability to theoretical falsification, but rather in the amenability to instrumental grasping. Scientific instruments have empowered humans for impressive feats of manipulation with Nature and themselves. Knowledge arising in the course of autonomous evolution of artifacts may surpass the horizon of human understanding and grasping. New knowledge may still be power, but no longer the power of humans. We may need a revision of some fundamental ideas of European thought. Our understanding of the human mind may entirely reshape our comprehension of the nature of physical knowledge, and vice versa. 相似文献