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61.
62.
利用全量子理论的方法,研究了存在相位退相干时多光子T-C模型中两个二能级原子与二项式光场相互作用系统中两原子的布居数反转。讨论了相位退相干系数、二项式光场系数、最大光子数、跃迁光子数对原子布居数反转的影响。结果表明:相位退相干减少了原子布居数反转的振幅、破坏了原子的量子特性。改变跃迁光子数,可以改变原子间布居数反转演化周期及演化强度。当二项式光场的最大光子数增大时,原子布居差的崩塌-回复现象就会逐渐消失。相位退相干因子不变时, 二项式光场从相干态过渡到数态过程中,原子布居的振荡频率由大变小,周期性的崩塌与回复现象逐渐消失。 相似文献
63.
We investigate the thermoelectric properties of GaN with p-and n-type doping by the first principles calculation and the semi-classical Boltzmann theory. We find that the power factors (S2σof p-type GaN (-3500 W/mK2) is about twice that of the n-type (-1750 W/mK2), which indicates the thermoelectric properties of p-type GaN would be better. Thermal conductivity of GaN crystal decreases rapidly as the temperature increases, but it is still too large for thermoelectric applications. The figure of merit (ZT) estimated at 1500 K is 0.134 for p-type GaN crystal and 0.062 for the n-type. 相似文献
64.
In recent years nanostructures have been widely used in industry, for example in nanoelectromechanical systems (NEMS); knowledge of the mechanical behavior of nanostructured materials is therefore important. In the work discussed in this paper, the non-dimensional buckling load of rectangular nano-plates was determined for general boundary conditions. Non-local theory was used to derive the governing equation, and this equation was then solved, by use of the finite-difference method, by applying different combinations of boundary conditions. To verify the proposed method, the non-dimensional buckling load determined for a simply supported plate was compared with results obtained by use of local theory and with results reported in the literature. When the method was used to calculate the buckling load of nano-beams, results were in good agreement with literature results. As a novel contribution of the work, non-symmetric boundary conditions were also studied. The non-dimensional buckling load was obtained for several values of aspect ratio, non-local variables, and different types of boundary condition. For better understanding, mode shapes are also depicted. The finite-difference method could be a powerful means of determination of the mechanical behavior of nanostructures, with little computational effort, and the results could be as reliable as those obtained by use of other methods. The ability to deal with a combination of boundary conditions illustrates the advantages of this method compared with other methods. 相似文献
65.
G.R. AnsarifarH.A. Talebi H. Davilu 《Communications in Nonlinear Science & Numerical Simulation》2012,17(1):414-425
This paper presents a new algorithm for designing dynamic sliding-mode controllers. The proposed controller is based on dynamic sliding manifolds to circumvent the difficulties associated with the conventional sliding mode controllers in the face of non-minimum phase systems. Unlike previous works, a proper and easy to implement algorithm is presented for designing the dynamic sliding manifold which facilitates the design of the controller. The output tracking problem in nonlinear non-minimum phase systems with matched and unmatched disturbances and matched nonlinearities is addressed. Then, the performance of the dynamic sliding mode controller is significantly improved by combining the given dynamic sliding manifold with online parameter adaptation. Simulations results are presented to demonstrate the effectiveness of the proposed sliding mode controller in terms of performance, robustness and stability. 相似文献
66.
Threes G. M. Smijs Stan Pavel Mojgan Talebi Joke A. Bouwstra 《Photochemistry and photobiology》2009,85(3):733-739
Dermatophytes are fungi that cause infections of keratinized tissues. We have recently demonstrated the susceptibility of the dermatophyte Trichophyton rubrum to photodynamic treatment (PDT) with 5,10,15-Tris(4-methylpyridinium)-20-phenyl-[21 H ,23 H ]-porphine trichloride (Sylsens B) in 5 m m citric acid/sodium citrate buffer (pH 5.2, formulation I). In this work, we examined the penetration of Sylsens B in healthy and with T. rubrum infected skin and we investigated the susceptibility of T. rubrum to PDT using formulation I and UVA-1 radiation (340–550 nm). Skin penetration studies were performed with formulations I and II (Sylsens B in PBS, pH 7.4) applied on dermatomed skin, human stratum corneum (SC), disrupted SC by T. rubrum growth and SC pretreated with a detergent. No penetration was observed in healthy skin. Disruption of SC by preceding fungal growth caused Sylsens B penetration at pH 7.4, but not at pH 5.2. However, chemically damaged SC allowed Sylsens B to penetrate also at pH 5.2. UVA-1 PDT was applied ex vivo during two fungal growth stages of two T. rubrum strains (CBS 304.60 and a clinical isolate). Both strains could be killed by UVA-1 alone (40 J/cm2 ). Combined with formulation I (1 and 10 μ m Sylsens B for, respectively, CBS 304.60 and the clinical isolate), only 18 J/cm2 UVA-1 was required for fungal kill. Therefore, PDT with 10 μ m Sylsens B (formulation I) and 18 J/cm2 UVA-1 could be considered as effective and safe. This offers the possibility to perform clinical studies in future. 相似文献
67.
In this work the intrinsic viscosity of poly(ethylene glycol)/poly(vinyl pyrrolidone) blends in aqueous solutions were measured at 283.1–313.1 K. The expansion factor of polymer chain was calculated by use of the intrinsic viscosities data. The thermodynamic parameters of polymer solution (the entropy of dilution parameter, the heat of dilution parameter, theta temperature, polymer–solvent interaction parameter and second osmotic virial coefficient) were evaluated by temperature dependence of polymer chain expansion factor. The obtained thermodynamic parameters indicate that quality of water was decreased for solutions of poly(ethylene oxide), poly(vinyl pyrrolidone) and poly(ethylene oxide)/poly(vinyl pyrrolidone) blends by increasing temperature. Compatibility of poly(ethylene oxide)/poly(vinyl pyrrolidone) blends were explained in terms of difference between experimental and ideal intrinsic viscosity and solvent–polymer interaction parameter. The results indicate that the poly(ethylene glycol)/poly(vinyl pyrrolidone) blends were incompatible. 相似文献
68.
QCD PERTURBATION THEORY AND NUCLEI (1) THE ENERGY SHIFTS OF HADRENS AND HADRONS MASS DIFFERENCE MASS DIFFERENCE
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QCD perturbation theory for confined quarks and gluons (inhadrons) is discussed.Based on the equivalent potential for the quark-gluon interaction derived, the energyshifts of hadrons and hadron mass difference in MIT bag (cavity) model and correcpond-ing approximation of the w. f. with Gassian form are calculated. 相似文献
69.
In the framework of density functional theory (DFT), the electronic excitations and nonlinear optical (NLO) properties of six binuclear transition metal cluster anions with the formula of [Ch2M-(μ-Ch)2-M'CN]^2- (M = Mo, W; Ch = S, Se; M' = Cu, Ag) have been systemically investigated at both cases of gas phase and DMF solution. The obtained electronic absorption spectra reveal that the element replacements of metals M and ligands Ch have significant influence on the absorptions, especially on the low-lying ones. In addition, the transitions of μ-Ch→M are dominant for the low-lying excitations, whereas the transitions of M'→M as well as Ch→M are mainly responsible for the higher excitations. The calculated molecular first and second hyperpolarizabilities present the remarkable element substitution and solvent effects. The analyses show that the transitions involving μ-Ch→M charge transfer make the critical contributions to the first hyperpolarizability t, and that the charge transfers from the moieties of MCh4 to M'CN as well as those of μ-Ch→M and M'→M are responsible for the second hyperpolarizability y. Moreover, the introduction of solvent leads to the results that the transitions within the moieties of MCh4 and M'CN make larger contributions to the hyperpolarizability, especially to γ. 相似文献
70.