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201.
We consider the magnetic Schrödinger operators on the Poincaré upper half plane with constant Gaussian curvature ?1. We assume the magnetic field is given by the sum of a constant field and the Dirac δ measures placed on some lattice. We give a sufficient condition for each Landau level to be an infinitely degenerated eigenvalue. We also prove the lowest Landau level is not an eigenvalue if the above condition fails. In particular, the infinite degeneracy of the lowest Landau level is equivalent to the infiniteness of the zero-modes of the two-dimensional Pauli operator. 相似文献
202.
Kotohiro Nomura 《中国化学会会志》2012,59(2):139-148
Recent examples for synthesis and reaction chemistry with (imido)vanadium(V)‐alkyl, ‐alkylidene complexes have been briefly summarized. (Arylimido)vanadium(V) dichloride complexes especially containing aryloxo ligands exhibited notable activities for ethylene polymerization, and the reacition pathways for the polymerization/dimerization using (imido)vanadium(V) dichloride complexes containing (2‐anilidomethyl)pyridine ligands can be tuned by modification of the steric bulk in the imido substituents; the adamantylimido analogues exhibited exceptionally high both activity and selectivity in the dimerization. These vanadium(V)‐alkyl complexes showed unique reactivity toward phenols; the reaction proceeds via coordination of phenols to the vanadium. The vanadium(V)‐alkylidene complexes were generated by α‐hydrogen elimination from the dialkyl analogues in the presence of PMe3 etc.; the subsequent 1,2‐C‐H bond activation of benzene with (arylimido)vanadium(V)‐alkylidene containing 1,3‐(2′,6′‐diiso‐propylphenyl)imidazolin‐2‐iminato (ImDIPPN) ligand took place cleanly. 相似文献
203.
Takuo Sugioka Allan S. Hay 《Journal of polymer science. Part A, Polymer chemistry》2001,39(8):1149-1155
Novel fully lower‐rim, carbonate‐bridged calix[8]arene derivatives were successfully synthesized in high yield by the condensation of p‐alkyl substituted calix[8]arenes with triphosgene. Different bases and catalysts were used for the preparation depending on the p‐alkyl substituted groups of the calix[8]arenes. The conformational features of the derivatives were examined by 1H NMR analysis. Thermosetting formulations were prepared from a mixture of bisphenol A polycarbonate with calix[8]arene carbonate derivatives using sodium benzoate as a catalyst. Their crosslinking behaviors were studied using differential thermal/thermogravimetric analysis. No glass‐transition temperatures were observed after annealing at 280–300 °C. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1149–1155, 2001 相似文献
204.
Tannin-like p-tert-butylcalix[4]arene 1,3-digallate was synthesized, and its conformational property was investigated by dynamic (1)H NMR and X-ray crystallography. It was found that the 3-OH (or 5-OH) group of the galloyl group in p-tert-butylcalix[4]arene 1,3-digallate is placed at the position where an unusual nonbonded close contact is observed between the OH group and the aromatic ring of the galloyl group facing each other. The calixarene 1,3-diesters of various hydroxybenzoic acids were also prepared, and the conformational properties of those calixarenes were compared with that of p-tert-butylcalix[4]arene 1,3-digallate. A significant contribution of the 3- and 5-OH groups in pendant groups toward the close contact was found. It was suggested that the conformation of p-tert-butylcalix[4]arene 1,3-digallate was stabilized by intramolecular hydrogen bonds including OH.O and OH-pi interactions. 相似文献
205.
Optical Review - Increasing efficiency and productivity in the field of agriculture is important to provide sufficient food to the world’s increasing population. It is important to monitor... 相似文献
206.
T. Shimmura H. Nomura H. Hock E. Fritz E. S. Grumell J. G. King E. G. Bailey F. Heathcoat W. Franke F. Eck I. A. Davies R. Vondráček D. Florentin C. Holthaus W. A. Selvig W. D. Pohle G. Speckhardt A. R. Powell C. C. Russell E. L. Skau I. L. Newell F. H. Gibson 《Analytical and bioanalytical chemistry》1934,99(3-4):148-153
207.
Kojiro Kawada Yuya Uchida Ikuo Takahashi Takahito Nomura Yasuyuki Sasaki Tadao Asami Shunsuke Yajima Shinsaku Ito 《Molecules (Basel, Switzerland)》2020,25(23)
Strigolactones (SLs) are carotenoid-derived plant hormones involved in the development of various plants. SLs also stimulate seed germination of the root parasitic plants, Striga spp. and Orobanche spp., which reduce crop yield. Therefore, regulating SL biosynthesis may lessen the damage of root parasitic plants. Biosynthetic inhibitors effectively control biological processes by targeted regulation of biologically active compounds. In addition, biosynthetic inhibitors regulate endogenous levels in developmental stage- and tissue-specific manners. To date, although some chemicals have been found as SL biosynthesis inhibitor, these are derived from only three lead chemicals. In this study, to find a novel lead chemical for SL biosynthesis inhibitor, 27 nitrogen-containing heterocyclic derivatives were screened for inhibition of SL biosynthesis. Triflumizole most effectively reduced the levels of rice SL, 4-deoxyorobanchol (4DO), in root exudates. In addition, triflumizole inhibited endogenous 4DO biosynthesis in rice roots by inhibiting the enzymatic activity of Os900, a rice enzyme that converts the SL intermediate carlactone to 4DO. A Striga germination assay revealed that triflumizole-treated rice displayed a reduced level of germination stimulation for Striga. These results identify triflumizole as a novel lead compound for inhibition of SL biosynthesis. 相似文献
208.
209.
A numerical procedure for solving the time-dependent, incompressible Navier-Stokes equations is presented. The present method is based on a set of finite element equations of the primitive variable formulation, and a direct time integration method which has unique features in its formulation as well as in its evaluation of the contribution of external functions. Particular processes regarding the continuity conditions and the boundary conditions lead to a set of non-linear recurrence equations which represent evolution of the velocities and the pressures under the incompressibility constraint. An iteration process as to the non-linear convective terms is performed until the convergence is achieved in every integration step. Excessively artificial techniques are not introduced into the present solution procedure. Numerical examples with vortex shedding behind a rectangular cylinder are presented to illustrate the features of the proposed method. The calculated results are compared with experimental data and visualized flow fields in literature. 相似文献
210.
T. Yatsui Y. Nakajima W. Nomura M. Ohtsu 《Applied physics. B, Lasers and optics》2006,84(1-2):265-267
We propose a novel method to increase the resolution of imprint lithography by introducing strong localization of the optical
near-field intensity, depending on the mold structure. By optimizing the thickness of the metallic film on a SiO2 line-and-space (LS) mold without a sidewall coating, we confirmed that the optical near-field strongly localizes at the edge
of the mold, using a finite-difference time-domain calculation method. Based on the calculated results, we performed optical
near-field imprint lithography using a mold with metallized (20-nm-thick Al without a sidewall coating) SiO2 LS with a 300-nm half-pitch that was 200-nm deep with illumination using the g-line (λ=436 nm), and obtained features as
narrow as 50 nm wide.
PACS 81.16.Nd; 81.16.Rf 相似文献