Untersuchungen an Chitin. 2. Mitt. Einflu? der Deacetylierung auf die L?slichkeit

Ohne Zusammenfassung     

Polyoxazolidones

Polyurethans with chloromethyl side chains were prepared by the polyaddition reaction of bischlorohydrins and diisocyanates. The polyurethans had inherent viscosities in a range of 0.22–0.60 and gave transparent films by solution casting. These polyurethans were easily converted to the polyoxazolidones by treatment with sodium methoxide. The polyoxazolidones had inherent viscosities up to 0.51, and gave transparent films by solution casting.     

Near-infrared diode laser spectroscopy of the HCSi radical

The , , and band spectra of HCSi radical were investigated by means of near-infrared diode laser spectroscopy to determine precise molecular constants for the and states. The detailed analysis of the rotationally resolved band spectra, studied for the first time in the present investigation, leads to the precise determination of molecular constants for the state associated with the Renner-Teller interaction. We obtained −0.15126663(53) and 495.00698(30) cm⁻¹ as the Renner-Teller parameter ε and the bending vibrational frequency ω₂, respectively. Based on the molecular constants for the and states, the rotational levels of the state were analyzed to obtain molecular constants and information on upper state perturbations. Using the available spectroscopic data, valence force fields for both the and states were estimated to aid in understanding the vibrational energy levels of the HCSi radical.     

Analysis of texture characteristics associated with visual complexity perception

In our previous work we determined that five important characteristics affect the perception of visual complexity of a texture: regularity, roughness, directionality, density, and understandability. In this paper, a set of objective methods for measuring these characteristics is proposed: regularity is estimated by an autocorrelation function; roughness is computed based on local changes; directionality is measured by the maximum line-likeness of edges in different directions; and density is calculated from the edge density. Our analysis shows a significant correlation between the objective measures and subjective evaluations. In addition, for the estimation of understandability, a new approach is proposed. We asked the respondents to name each texture, and then we sorted all these names into different types, including names that were similar. We discovered that understandability is affected by two factors of a texture: the maximum number of similar names assigned to a specific type and the total number of types.     

Terminal Redox‐Site Effect on the Long‐Range Electron Conduction of Fe(tpy)2 Oligomer Wires on a Gold Electrode

This article completes our comprehensive understanding of the electron transport properties of our original π‐conjugated redox‐active molecular wires comprising Fe bridged by p‐phenylene linkers (tpy=2,2′:6′,2′′‐terpyridine). The Fe(tpy)₂ oligomer wires comprise three types of tpy ligands: the anchor tpy ligand ( A series) makes a junction between the wire and electrode, the bridging bis‐tpy ligand ( L series) connects the Fe(tpy)₂ units, and the terminal tpy ligand ( T series) possesses a redox site as a probe for the long‐range electron transport ability. Taking advantage of the precise tunability of the composition of the Fe(tpy)₂ oligomer wires, thus far we investigated how A and L impacted on the electron‐transport ability. The excellent long‐range electron transport ability with ultrasmall attenuation constants (β^d, 0.002 Å^?1 as the minimum) depends on L significantly [Chem. Asian J. 2009 , 4, 1361], whereas A is unrelated to the β^d value, but influences the zero‐distance electron‐transfer rate constant, k_et⁰ [J. Am. Chem. Soc. 2010 , 132, 4524]. Herein we study the influence of terminal ligand T ^x (x=1–3). β^d is independent of T , however, T³ , with a cyclometallated Ru complex as the redox site, gives rise to a k_et⁰ value greater than T¹ and T² with ferrocene. This series of simple but definitive conclusions indicates that we have reached the stage of being able to precisely design molecular wires to attain desirable single‐molecule electron conduction.     

Charge transfer in duplex DNA containing mismatch

A theory for charge transfer between the electrode and the donor/acceptor molecule coupled through a DNA bridge in solution is developed. We explore the crossover between the coherent tunneling and the incoherent sequential transfer regimes by varying the electrode potential and discuss the effects of single-base mismatches in DNA duplex in both regimes. In the former regime a single-base mismatch in DNA duplex causes a reduction in the charge transfer rate simply by decreasing the electron tunneling matrix element, however, in the latter regime the effects are rather complicated.     

Approximate formulas of average distances associated with regions and their applications to location problems

This study is concerned with the problem of measuring average distances between two points in two different coplanar regions. The objectives are: (1) to derive the approximated average distances associated with circular regions and to check their accuracy; and (2) to apply these approximated distances to location problems. Results show that the simple approximate formulas are accurate and useful. The approximated average distances can be applied to the analyses of varied kinds of movement phenomena in cities.     

Reliable Polymer-Stabilized Ferroelectric Liquid Crystal Device Using Thin Plastic Substrates

We developed a rollable polymer-stabilized ferroelectric liquid crystal (FLC) display device using thin plastic substrates. In a device using 200-μm-thick substrates which are fastened by polymer walls and networks made by photopolymerization-induced phase separation, disorder of the FLC alignment was caused by exfoliation of these walls in curvature radii of under 30 mm. Otherwise, the uniformity of the FLC alignment was maintained even after a device using 100-μm-thick substrates was bent at a radius of 7 mm. The enhanced bending tolerance does not depend on the FLC alignment direction, and the device could be bent both convexly and concavely without any FLC alignment change. A rollable device with a size of 100 × 100 mm exhibited uniform grayscale display operation between crossed polarizers when bent with a radius of 15 mm.