Phonon density of states and compression behavior in iron sulfide under pressure

We report the partial phonon densities of states (DOS) of iron sulfide, a possible component of the rocky planet's core, measured by the 57Fe nuclear resonant inelastic x-ray scattering and calculate the total phonon DOS under pressure. From the phonon DOS, we drive thermodynamic parameters. A comparison of the observed and estimated compressibilities makes it clear that there is a large pure electronic contribution in the observed compressibility in the metallic state. Our results present the observation of thermodynamic parameters of iron sulfide with the low-spin state of an Fe2+ ion at the high density, which is similar to the condition of the Martian core.     

Ascent of open-circuit voltage on diamond-like carbon photovoltaic cell by infrared heating-assisted pulsed-laser deposition

Phosphorus-doped diamond-like carbon (DLC) films were deposited on quartz and p-type silicon (p-Si) substrates by pulsed-laser deposition. Open-circuit voltage (V _oc) and short-circuit density (I _sc/cm²) from a heating process converted from one type of electrode to another and the two types of electrode pattern are shown by the V–I characteristics. The first heating process was by a ceramic heater, and the other was by an infrared heater. We adopted two electrode patterns, from a bipectinate electrode and a plot pattern electrode, to measure electric photovoltaic characteristics. We were able to upgrade V _oc and I _sc/cm² to 35∼45 mV, and 0.24 μA/cm², respectively, under infrared heating. V _oc by the plot pattern electrode was over 2 V under infrared heating and ceramic heating did not match this on deposition by the PLD method.     

Pulse laser ablation at water–air interface

We studied a new pulse laser ablation phenomenon on a liquid surface layer, which is caused by the difference between the refractive indices of the two materials involved. The present study was motivated by our previous study, which showed that laser ablation can occur at the interface between a transparent material and a gas or liquid medium when the laser pulse is focused through the transparent material. In this case, the ablation threshold fluence is reduced remarkably. In the present study, experiments were conducted in water and air in order to confirm this phenomenon for a combination of two fluid media with different refractive indices. This phenomenon was observed in detail by pulse laser shadowgraphy. A high-resolution film was used to record the phenomenon with a Nd:YAG pulse laser with 10-ns duration as a light source. The laser ablation phenomenon on the liquid surface layer caused by a focused Nd:YAG laser pulse with 1064-nm wavelength was found to be followed by the splashing of the liquid surface, inducing a liquid jet with many ligaments. The liquid jet extension velocity was around 1000 m/s in a typical case. The liquid jet decelerated drastically due to rapid atomization at the tips of the ligaments. The liquid jet phenomenon was found to depend on the pulse laser parameters such as the laser fluence on the liquid surface, laser energy, and laser beam pattern. The threshold laser fluence for the generation of a liquid jet was 20 J/cm². By increasing the incident laser energy with a fixed laser fluence, the laser focused area increased, which eventually led to an increase in the size of the plasma column. The larger the laser energy, the larger the jet size and the longer the temporal behavior. The laser beam pattern was found to have significant effects on the liquid jet’s velocity, shape, and history.     

Predictions and experimental studies of the tail pipe noise of an automotive muffler using a one dimensional CFD model

The tail pipe noise from a commercial automotive muffler was studied experimentally and numerically under the condition of wide open throttle acceleration in the present research. The engine was accelerated from 1000 to 6000 rpm in 30 s at the warm up condition. The transient acoustic characteristics of its exhaust muffler were predicted using one dimensional computational fluid dynamics. To validate the results of the simulation, the transient acoustic characteristics of the exhaust muffler were measured in an anechoic chamber according to the Japanese Standard (JIS D 1616). It was found that the results of simulation are in good agreement with experimental results at the 2nd order of the engine rotational frequency. At the high order of engine speed, differences between the computational and experimental results exist in the high revolution range (from 5000 to 6000 rpm at the 4th order, and from 4200 to 6000 rpm at the 6th order). According to these results, the differences were caused by the flow noise which was not considered in the simulation. Based on the theory of one dimensional CFD model, a simplified model which can provide an acceptable accuracy and save more than 90% of execution time compared with the standard model was proposed for the optimization design to meet the demand of time to market.     

Radial breathing modes of single-walled carbon nanotubes in resonance Raman spectra at high temperature and their chiral index assignment

Radial breathing modes (RBMs) in resonance Raman spectra from single-walled carbon nanotubes (SWCNTs) on a SiO₂/Si (0 0 1) substrate are studied between 25 and 720 °C. A change in the relative intensity of each RBM peak with temperature is observed, which originates from the temperature dependence of the resonance condition of nanotubes. For 25 °C, each RBM peak is reasonably assigned on the basis of data in the literature [J. Maultzsch, H. Telg, S. Reich, F. Hennrich, C. Thomsen, Phys. Rev. B 72 (2005) 205438]. By taking into account the temperature-dependent behavior of the relative intensity of the RBM peaks, each RBM peak is successfully assigned even for 720 °C. It is found that most of the observed RBM peaks for a laser excitation energy of E_exc = 1.96 eV are from chiral SWCNTs. These results make it possible to discuss further details of the chirality-dependent growth behavior observed for in situ Raman spectroscopy.     

Development of an engineering model for ferromagnetic shape memory alloys

This paper presents a relationship among stress, temperature and magnetic properties of a ferromagnetic shape memory alloy. In order to derive an engineering model of ferromagnetic shape memory alloys, we have developed a measuring system of the relationship among stress, temperature and magnetic properties. The samples used in this measurement are Fe68–Ni10–Cr9–Mn7–Si6 wt% ferromagnetic shape memory alloy. They are thin ribbons made by rapid cooling in air. In the measurement, the ribbon sample is inserted into a sample holder winding consisting of the B-coil and compensation coils, and magnetized in an open solenoid coil. The ribbon is stressed with attachment weights and heated with a heating wire. The specific susceptibility was increased by applying tension, and slightly increased by heating below the Curie temperature.     

The polarized reflection and absorption spectra of perylene crystals in monomeric and dimeric forms

The electronic absorption spectra of perylene crystals in the α- and β-forms were measured by the normal incidence reflection method in the spectral region from 20 000 to 60 000 cm^?1. From the absorption spectrum polarized perpendicular to [1$\text{1}$0] axis of the α-form crystal, the bands around 24 000 cm^?1 were determined to be polarized along the long molecular axis. Two strong bands with different polarizations were observed around 50 000 cm^?1 for each of the α- and β-perylene crystals and were assigned to the transitions to the ¹B_2u and ¹B_3u states. The observed polarized absorption spectra as a whole were consistent with the theoretical results by Hummel and Ruedenberg and the reflection method was found to be suitable to the polarized absorption measurement of strong bands of crystals. The observed factor-group splittings were compared with the theoretical values, the oriented gas model being found to be applicable to the β-form crystal.     

A rigorous control of logarithmic corrections in four-dimensional ϕ4 spin systems

Using Gawedzki and Kupiainen's rigorous block spin transformation method, we study critical phenomena in ⁴ spin systems in four dimensions. In Part I of this work we investigate in detail the renormalization group trajectory of the system not exactly at the critical point.     

Spacetime correlation functions of dynamic speckles produced by a series of moving phase screens

Spacetime correlation functions of the time-varying speckle intensity have been evaluated for the case where speckle patterns are produced in the Fresnel diffraction region by light propagating through a series of moving random-phase screens. The correlation functions are given by a set of recursion formulae which are useful for numerical computations. Three statistical quantities relating to the motion of speckle patterns are derived to examine the relationship between the velocity distribution of the phase screens and the temporal behaviour of resultant speckle patterns. It is found that the velocity differences between the phase screens have a strong effect on both the decorrelation of speckle patterns and the fluctuating speed of the speckle intensity.     

SDiff(2) Toda equation — Hierarchy,Tau function,and symmetries

A continuum limit of the Toda lattice field theory, called the SDiff(2) Toda equation, is shown to have a Lax formalism and an infinite hierarchy of higher flows. The Lax formalism is very similar to the case of the self-dual vacuum Einstein equation and its hyper-Kähler version, however now based upon a symplectic structure on a cylinderS ¹×R. An analogue of the Toda lattice tau function is introduced. The existence of hidden SDiff(2) symmetries are derived from a Riemann-Hilbert problem in the SDiff(2) group. Symmetries of the tau function turn out to have commutator anomalies, hence give a representation of a central extension of the SDiff(2) algebra.