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11.
Masaharu Asano Jinhua Chen Yasunari Maekawa Takahiro Sakamura Hitoshi Kubota Masaru Yoshida 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2624-2637
A novel process comprising the UV‐induced photografting of styrene into poly(tetrafluoroethylene) (PTFE) films and subsequent sulfonation has been developed for preparing proton‐conducting membranes. Although under UV irradiation the initial radicals were mainly generated on the surface of the PTFE films by the action of photosensitizers such as xanthone and benzoyl peroxide, the graft chains were readily propagated into the PTFE films. The sulfonation of the grafted films was performed in a chlorosulfonic acid solution. Fourier transform infrared and scanning electron microscopy were used to characterize the grafted and sulfonated membranes. With a view to use in fuel cells, the proton conductivity, water uptake, and mechanical properties of the prepared membranes were measured. Even through the degree of grafting was lower than 10%, the proton conductivity in the thickness direction of the newly prepared membranes could reach a value similar to that of a Nafion membrane. In comparison with γ‐ray radiation grafting, UV‐induced photografting is very simple and safe and is less damaging to the membranes because significant degradation of the PTFE main chains can be avoided. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2624–2637, 2007 相似文献
12.
Infrared and nuclear magnetic resonance (NMR) spectroscopies have been applied for quantitative comparison on unsaturated bonds in tetrafluoroethylene (TFE)-propylene (P)-vinylidene fluoride (VdF) terpolymers. These spectroscopies have led to consistent results while they are based on completely different principles. It is shown that the absolute concentration can be evaluated from NMR measurements. The behavior of unsaturation has been discussed in terms of after-treatment such as wet and dry treatments. The result obtained here can give the important information to improve the performance of fluoroelastomer based on TFE-P-VdF terpolymers. 相似文献
13.
Tetsuro Saeki Takahiro Tamesue Shizuma Yamaguchi Kazuya Sunada 《Applied Acoustics》2004,65(2):203-210
This paper focuses on masking speech with meaningless steady noise as a way of realizing a comfortable sound environment. As a basis for research, meaningless steady noise at minimum sound pressure levels for masking of male or female meaningful speech is considered, based on psychological experiments using a method of adjustment. From the results, band-limited pink noise can be selected as the most effective noise for masking of speech. In the case of speech with a lower sound pressure level, the sound pressure level of the meaningless steady noise needs to be a little higher. 相似文献
14.
Kichi-Suke Saito 《Integral Equations and Operator Theory》1991,14(2):251-275
In [16], we introduced the notion of Toeplitz operators associated with analytic crossed products. In this paper, we study the structure of invariant subspaces with respect to the analytic crossed products. We also investigate the inner-outer factorization problems for analytic Toeplitz operators, the factorization problem for non-negative Toeplitz operators and Szegö's infimum problem.This work was supported in part by a Grant-in-Aid for Scientific Research from the Japanese Ministry of Education. 相似文献
15.
16.
In this paper we study higher Chow groups of smooth, projective surfaces over a field k of characteristic zero, using some new Hodge theoretic methods which we develop for this purpose. In particular we investigate the subgroup of CH
r+1 (X,r) with r = 1,2 consisting of cycles that are supported over a normal crossing divisor Z on X. In this case, the Hodge theory of the complement forms an interesting variation of mixed Hodge structures in any geometric deformation of the situation. Our main result is a structure theorem in the case where X is a very general hypersurface of degree d in projective 3-space for d sufficiently large and Z is a union of very general hypersurface sections of X. In this case we show that the subgroup of CH
r+1 (X,r) we consider is generated by obvious cycles only arising from rational functions on X with poles along Z. This can be seen as a generalization of the Noether–Lefschetz theorem for r = 0. In the case r = 1 there is a similar generalization by Müller-Stach, but our result is more precise than it, since it is geometric and not only cohomological. The case r = 2 is entirely new and original in this paper. For small d, we construct some explicit examples for r = 1 and 2 where the corresponding higher Chow groups are indecomposable, i.e. not the image of certain products of lower order groups. In an appendix Alberto Collino constructs even more indecomposable examples in CH
3 (X,2) which move in a one-dimensional family on the surface X.Contribution to appendix. 相似文献
17.
18.
Simulation of electron bunch generation by an ultrashort-pulse high-intensity laser-driven wakefield
M. Yamagiwa S. V. Bulanov T. Zh. Esirkepov J. Koga M. Kando Y. Ueshima K. Saito D. Wakabayashi 《Laser Physics》2006,16(2):252-258
Electron acceleration due to a wakefield excited by a ultrashort-pulse intense laser propagating through a finite-length underdense plasma layer is studied by two-dimensional particle-in-cell simulation. The electron energy distribution is analyzed for moderate to high intensity. For the electron density, where the pulse length is almost half of the plasma wavelength, dramatic changes of the density structure occur with cavity and bunch formation with an increase in the laser intensity, also leading to the appearance of a fast electron component well confined in phase space. The analytical form of the fast electron energy spectrum is also presented. 相似文献
19.
Tomohiro Kyotani Sonoko Kakui Takehito Mizuno Naoto Shimotsuma Soushi Inoue Junji Saito 《Analytical sciences》2006,22(7):1031-1034
A zeolite NaA (LTA) membrane supported by an alumina porous support tube for pervaporation (PV) dehydration of ethanol was characterized by transmission electron microscopy (TEM) using a focused ion beam (FIB) thin-layer specimen preparation technique and by Fourier transform infrared attenuated total reflectance method (FTIR-ATR) using a diamond prism as the waveguide. FIB-TEM clearly presented cross-section images up to about 15 microm depth from the membrane surface. FTIR-ATR monitored the Si-O asymmetric stretching vibration spectrum. The Si-O spectrum was compared with the TEM image and their relationships were discussed. By combining the two methods, we could study the thickness of surface LTA crystals, the grain boundary, the LTA/alumina interface structure and the crystallinity and density of materials inside of the alumina porous support. Consequently, fine structure changes of the LTA membrane corresponding to the hydrothermal synthesis condition could be sensitively detected. 相似文献
20.
P. Periasamy K. Tatsumi N. Kalaiselvi M. Shikano T. Fiyieda Y. Saito T. Sakai M. Mizukata A. Kajinami S. Deki 《Ionics》2002,8(5-6):453-460
A series of gel polymer electrolytes containing PVdF as homo polymer, a mixture of 1:1 Ethylene Carbonate (EC) : Propylene
Carbonate (PC) as plasticizer and lithium-bistrifluoromethane sulphone imide [imide — LiN (CF3SO2)2] has been developed. Amounts of polymer (PVdF), plasticizer and the imide lithium salt have been varied as a function of
their weight ratio composition in this regard. Dimensionally stable films possessing appreciable room temperature conductivity
values have been obtained with respect to certain weight ratio compositions. However, conductivity data have been recorded
at different possible temperatures, i.e., from 20 °C to 65 °C. XRD and DSC studies were carried out to characterize the polymer
films for better amorphicity and reduced glass transition temperature, respectively. The electrochemical interface stability
of the PVdF based gel polymer electrolytes over a range of storage period (24 h – 10 days) have been investigated using A.C.
impedance studies. Test cells containing Li/gel polymer electrolyte (GPE)/Li have been subjected to undergo 50 charge-discharge
cycles in order to understand the electrochemical performance behaviour of the dimensionally stable films of superior conductivity.
The observed capacity fade of less than 20% even after 50 cycles is in favour of the electrochemical stability of the gel
polymer electrolyte containing 27.5% PVdF −67.5 % EC+PC −5% imide salt. Cyclic voltammetry studies establish the possibility
of a reversible intercalation — deintercalation process involving Li+ ions through the gel polymer electrolyte. 相似文献