Acetylation of beta-cyclodextrin surface-functionalized cellulose dialysis membranes with enhanced chiral separation

The enhanced enantiomeric separation of racemic phenylalanine solution has been demonstrated by the membrane-based chiral resolution method using an acetylated beta-cyclodextrin-immobilized cellulose dialysis membrane. Beta-cyclodextrin (CD) was first immobilized onto the surface of commercial cellulose dialysis membranes, followed by the acetylation reaction through the treatment of the membranes with acetic anhydride to form the chiral selective acetylated beta-cyclodextrin-immobilized cellulose dialysis membrane. The acetylated CD-immobilized membrane exhibits enantioselectivity in the range of 1.26-1.33 depending on the acetylation time. The improvement in enantioselectivity after acetylation was mainly attributed to the better discrimination ability of acetylated CD and the decrease in membrane pore size. Molecular modeling simulations indicate that the acetylation of hydroxyl groups would result in a CD conformation with torus distortions and would create higher steric hindrance for penetrants. As a result, compared to the original CD, the acetylated CD may have less effective binding but better discrimination of enantiomers. The energy drop is only 3 kcal/mol between different enantiomers before and after the binding of phenylalanine with an unmodified CD. The energy drop increases to 10 kcal/mol if acetylated CD is employed as the chiral selector, showing stronger characteristics for chiral selection.     

Visualization of Crevice Flow in an Engine Using Laser-Induced Fluorescence

A simultaneous visualization technique of reacting and unburned zones using laser-induced fluorescence (LIF) was applied to a high-pressure combustion field in an engine cylinder. Crevice flow from a crevice between a piston and a cylinder wall of a spark ignition gas engine was visualized by LIF of OH and acetone. OH was excited simultaneously with acetone that was seeded into fuel as a tracer by an excitation light at 283.92 nm. Fluorescence signals from each species were detected individually by two intensified CCD cameras using optical band-pass filters which transmit fluorescence wavelength of OH and acetone, respectively. Pressure- and temperature-dependence of LIF signals from each species were evaluated. From the visualized images, it was clarified that oxidation of the crevice flow is stopped at the time of exhaust valve opening. Effects of exhaust port pressure on the oxidation process were investigated.     

水热法合成纳米花状二硫化钼及其微观结构表征

本文以钼酸钠、硫代乙酰胺为前驱体, 硅钨酸为添加剂, 成功用水热法合成高纯度纳米花状二硫化钼. 产物特性用X射线衍射(XRD)、能量色散谱(EDS)、扫描电子显微镜(SEM)进行表征. XRD和EDS图显示实验产物为二硫化钼, 且其结晶度和层状堆垛良好. SEM图谱则表明二硫化钼为纳米花状结构, 颗粒直径300 nm左右, 由几十上百片花瓣组成, 每片花瓣厚度十个纳米左右. 通过以硅钨酸为变量的梯度实验, 研究发现, 硅钨酸对于纳米花状MoS₂的形成具有重要作用, 不添加硅钨酸, 无法形成纳米花状MoS₂, 此外, 硅钨酸的剂量会影响合成MoS₂的大小和形貌. 本文还对纳米花状二硫化钼的形成机理做了初步的讨论.     

Analysis for the Data of Singly Strange Particle Production in 200AGeVpp,pS and SS Reactions

We have used the event generator LUCIAE to analyse the data of singly strange particle production in pp,pS,and SS reactions at 200AGeV.The results seem to indicate that in comparing with the pp and the pS minimum bias event,the SS center collision seems having stronger final state interaction,shorter fomation time of strange particles,and larger s quark pair suppression factor.The strangeness enhancement evidence from pp to pS and to SS could be explained without the introduction of quark-gluon plasma formation.     

关于Krull的一个猜测

<正> §1. 本文所谓的Krull猜测,是指一个偏序交换群Γ,如果它是阿基米德的,则Γ将序同构于某个阿基米德向量群的子群,这一推广的形式,是A.H.Clifford在[3]中所使用的。在本文中,我们主要就Γ是个以加法为运算的交换格序群(或称l-群),并且只有有限多个极大l-闭上类的情形来考虑     

早籼稻数量性状遗传相关的研究

本试验以我国南方广泛栽培的20个早籼稻品种为材料,通过对其主要数量性状的平均数、变异系数、遗传力、遗传变异系数、相关系数、遗传进度、以及相关遗传进度等的探讨,考察其遗传及遗传相关的动态,为早籼稻新品种的选育工作,提供实用的参考信息。     

Effect of the Linking Structure of Nonlinear Optical Side Groups on the Phase Behavior of an Aromatic Polyester Backbone

Summary: The phase behavior of poly(p‐phenylene terephthalate)s (PPT) with pendant side groups, N‐(4‐nitrophenyl)ethylaminoethanol (NPE) and N‐(4‐nitrophenyl)‐L ‐prolinol (NPP) has been studied by using differential scanning calorimetry (DSC), wide‐angle X‐ray scattering (WAXS), and second harmonic generation (SHG). PPT‐NPE showed a layered liquid crystalline morphology while PPT‐NPP showed a completely amorphous structure. Compressive or shear stress applied on the polymer melt surface at 210 °C induced a more prominent layered structure of PPT‐NPE whereas the amorphous structure of PPT‐NPP remained unchanged under the stress. In order to understand this phase difference in terms of the repeat structure, we attempted theoretical ab initio Hartree‐Fock, and DFT calculations for the monomers and molecular dynamics for the bulk state. The results indicated that molecular configurations are a good way of microscopically understanding the phases of rigid backbone polymers with functional side groups: The NPT (constant particle number, pressure, and temperature) simulation data at 210 °C agree qualitatively with the experimental data and the difference between PPT‐NPE and PPT‐NPP could be understood using rotational energy barrier, steric hindrance and inter‐chain interactions. X‐ray diffractometer (XRD) simulation patterns for the oligomers are also in qualitative agreement with the experimental WAXS data and the structural parameters of stacks of PPT‐NPE chains are estimated to be layer distance (4.6 Å), backbone distance (21.5 Å), and side distance (12 Å).

     

Crystal Structure of 〔PrAl(CF_3COO)_2(CF_3CHOO)(C_2H_5)_2(C_4H_8O)_2〕_2

１ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｒｅｃｅｎｔｙｅａｒｓ,ａｓｅｒｉｅｓｏｆｌａｎｔｈａｎｉｄｅ ａｌｕｍｉｎｉｕｍｃｏｍｐｌｅｘｅｓｗｈｉｃｈａｒｅａｃｔｉｖｅｆｏｒｐｏｌｙ ｍｅｒｉｚａｔｉｏｎｏｆｏｌｆｉｎｓ〔１〕ｈａｖｅｂｅｅｎｒｅｐｏｒｔｅｄ．...     

Measurements of wall shear stress of a turbulent boundary layer using a micro-shear-stress imaging chip

Measurements of wall shear-stress streaks of a turbulent boundary layer in the channel flow were carried out using a MEMS-based micro-shear-stress imaging chip, which contains about 100 sensors. The chip is designed and fabricated by surface micromachining technology. One arrray of 25 micro-shear-stress sensors in the chip that covers a length of 7.5 mm is used to measure the instantaneous spanwise distribution of the surface shear stress. The statistics of high shear-stress streaks were established. Based on the measurement, the physical quantities associated with the high shear-stress streaks, such as their length, width and peak shear-stress level, were obtained. We found out that a high correlation exists between the peak shear-stress level and front-end shear-stress slope of a high shear-stress streak. This important property is currently being applied to the deisgn of a real-time flow control logic.     

158A?GeV/c?Pb+Pb碰撞中J/ψ是反常压低吗?

用含有领头粒子能量衰减、J/ψ先驱体在弦色场中离解和物理J/ψ的强子吸收等三种机制的强子和弦级联模型,JPCIAE,计算了200AGeV/c的PA和AB轻的弹核)反应以及Pb+Pb反应中J/ψ压低因子,取得与NA38及NA50数据全面地较好符合; 从而对Pb+Pb反应中J/ψ是反常压低的说法提出质疑.