Synthesis of novel axially chiral cyclic benzopolysulfides

Novel axially chiral benzopentathiepins were synthesized by sulfurization of dithiastannole. Naphthyl moiety was introduced near the pentathiepin ring by Suzuki-Miyaura cross-coupling reaction. Pentathiepins were found as diastereomeric mixture. Rotational energy barrier for C-C bond was estimated by theoretical calculation. Energy barrier for the inversion of pentathiepin ring was experimentally determined by variable temperature ¹H NMR.     

Accelerated phosphodiester cleavage of bis( p -nitrophenyl)-phosphate by receptors

Phosphodiester cleavage of BNPP can be accelerated by various degradative receptors including enzymes. In the hydrolytic cleavage of BNPP, a bell-shaped receptor concentration-rate profile composed of a positive-catalysis phase at low receptor concentrations and a negative-catalysis phase at excess receptor concentration was observed. The negative catalysis can be explained by nonproductive binding, leading to an increase of the activation energy barrier and a decrease of the reaction rate.     

Optical study of implantation damage recovery from Si-implanted GaN

Comprehensive and systematic optical activation studies of Si-implanted GaN grown on sapphire substrates have been made as a function of ion dose and anneal temperature. Silicon ions were implanted at 200 keV with doses ranging from 1×10¹³ to 5×10¹⁵ cm⁻² at room temperature. The samples were proximity cap annealed from 1250 to 1350 °C with a 500-Å-thick AlN cap in a nitrogen environment. The results of photoluminescence measurements made at 3 K show a very sharp neutral-donor-bound exciton peak along with a sharp donor-acceptor pair peak after annealing at 1350 °C for 20 s, indicating excellent implantation damage recovery. The results also indicate the AlN cap protected the implanted GaN layer very well during high temperature annealing without creating any significant anneal-induced damage. This observation is consistent with the electrical activation results for these samples.     

Integration of immunoassay into extended nanospace

We report on the first successful miniaturization of sandwich immunoassay into an extended nanospace channel for the detection of alpha-fetoprotein. A fused silica microchip with a nanochannel flanked by two microchannels, to facilitate liquid handling, was constructed using photo- and electron beam lithography, ICP and thermal bonding. Reagents could be selectively introduced into the nanochannel and the flow be stopped by using a pressure controller that alternatively opened and closed inlet and outlet ports. The construction and handling of the nano-in-microchip device for immunoassay is described.     

Liquid chromatography at the critical condition: Thermodynamic significance and influence of pore size

Liquid chromatography at the critical condition (LCCC) is a high performance liquid chromatography (HPLC) technique that lies between size exclusion chromatography and adsorption-based interaction chromatography, where the elution of polymers becomes independent of polymer molecular weight. At LCCC, the balance between the entropic exclusion and the enthalpic adsorption interactions between polymers and stationary phases results in the simultaneous HPLC elution of polymers regardless of molecular weight. Using C18-bonded silica chromatographic columns with 5 μm particle size and different average pore size (diameter = 300 Å, 120 Å, 100 Å, and 50 Å), we report (1) the thermodynamic significance of LCCC conditions and (2) the influence of column pore size on the determination of critical conditions for linear polymer chains. Specifically, we used mixtures of monodisperse polystyrene samples ranging in molecular weight from 162 to 371,100 g/mol and controlled the temperature of the HPLC columns at a fixed composition of a mobile phase consisting of 57(v/v)% methylene chloride and 43(v/v)% acetonitrile. It was found that, at the fixed mobile phase composition, the temperature of LCCC (T_LCCC) is higher for C18-bonded chromatographic columns with larger average pore size. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 2533–2540, 2009     

Structural and optical characterization of Si-implanted Al0.18Ga0.82N

Both structural and optical activation studies of Si-implanted Al_0.18Ga_0.82N have been made as a function of anneal temperature by using the x-ray rocking curve measurements and photoluminescence (PL) and time-resolved PL (TRPL) measurements. The full width at half maximum values of both (002) and (102) direction $\omega$-rocking curves for the Si-implanted Al_0.18Ga_0.82N samples decrease as the anneal temperature increases from 1150 to 1250 ^°C. The peak widths of the rocking curves for the as-implanted sample are much broader than those for the Si-implanted and annealed samples, indicating the implantation damage recovery after high temperature anneal. With increasing anneal temperature, the PL peak intensity increases and the PL decay becomes slower. The increase of PL intensity and recombination rate is attributed to both an increase of Si-donor activation and lattice damage recovery. These PL and x-ray results are very consistent with the results of anneal temperature-dependent electrical activation study.     

Infinitely many shape invariant potentials and new orthogonal polynomials

Three sets of exactly solvable one-dimensional quantum mechanical potentials are presented. These are shape invariant potentials obtained by deforming the radial oscillator and the trigonometric/hyperbolic Pöschl–Teller potentials in terms of their degree ℓ polynomial eigenfunctions. We present the entire eigenfunctions for these Hamiltonians (ℓ=1,2,…) in terms of new orthogonal polynomials. Two recently reported shape invariant potentials of Quesne and Gómez-Ullate et al.'s are the first members of these infinitely many potentials.     

Magnetic moment of hyperons in nuclear matter by using quark–meson coupling models

We calculate the magnetic moments of hyperons in dense nuclear matter by using relativistic quark models. Hyperons are treated as MIT bags, and the interactions are considered to be mediated by the exchange of scalar and vector mesons which are approximated as mean fields. Model dependence is investigated by using the quark–meson coupling model and the modified quark–meson coupling model; in the former the bag constant is independent of density and in the latter it depends on density. Both models give us the magnitudes of the magnetic moments increasing with density for most octet baryons. But there is a considerable model dependence in the values of the magnetic moments in dense medium. The magnetic moments at the nuclear saturation density calculated by the quark–meson coupling model are only a few percents larger than those in free space, but the magnetic moments from the modified quark–meson coupling model increase more than 10% for most hyperons. The correlations between the bag radius of hyperons and the magnetic moments of hyperons in dense matter are discussed.