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231.
Yun‐Hi Kim Seong‐Kuk Ahn Hyung Sun Kim Soon‐Ki Kwon 《Journal of polymer science. Part A, Polymer chemistry》2002,40(23):4288-4296
Two new pyromellitic dianhydrides, 1,4‐bis(4′‐t‐butylphenyl) pyromellitic dianhydride and 1,4‐bis(4′‐trimethylsilylphenyl) pyromellitic dianhydride, were synthesized via Suzuki coupling, oxidation, and dehydration. A series of new organosoluble polyimides were prepared from the obtained pyromellitic dianhydride and various aromatic diamines by the conventional polycondensation reaction followed by chemical imidization, as well as high‐temperature, one‐step polymerization. The structures of the dianhydrides and polymers were identified with various spectroscopies. The inherent viscosities of the resulting polymers were 0.62–1.89 dL/g. The synthesized polyimides showed good solubility in various organic solvents such as N‐methyl‐2‐pyrrolidinone, N,N‐dimethylacetamide, and p‐chlorophenol. These polymers had glass‐transition temperatures of 230–260 °C. Thermogravimetric analysis showed that all the polymers were stable, with 10% weight losses recorded above 490 °C in nitrogen. The polyimide films had good mechanical properties and high oxygen permselectivity to nitrogen. The oxygen permeability coefficient (P) and the permselectivity of oxygen to nitrogen (P/P) of the films were 13–56 barrer and 3.7–5.5, respectively. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4288–4296, 2002 相似文献
232.
Hyoung‐Juhn Kim Seong Jin An Ju‐Yong Kim Jin Kyoung Moon Sung Yong Cho Yeong Chan Eun Hae‐Kwon Yoon Youngmi Park Ho‐Jin Kweon Eun‐Mi Shin 《Macromolecular rapid communications》2004,25(15):1410-1413
Summary: Fuel cells were designed for high temperature operations. Poly[2,2′‐(m‐phenylene)‐5,5′‐bibenzimidazole] (PBI) was synthesized in a solution of P2O5, CH3SO3H, and CF3SO3H. The PBI was dissolved in a mixture of CF3CO2H and H3PO4 and the solution was used for the preparation of Pt catalyst slurry for membrane electrode assembly. The single cell showed a current density of 280 mA · cm−2 at a cell voltage of 0.5 V with feeds of H2 and O2 at 160 °C and without external humidification.
233.
Yang SH Shin WH Lee JW Kim SY Woo SI Kang JK 《The journal of physical chemistry. B》2006,110(28):13941-13946
Interaction of a transition metal atom with defects in single-walled carbon nanotubes (SWNTs) were investigated through density functional theory calculations. For three kinds of intrinsic defects (single vacancies, double vacancies and Stone-Wales defects) in (5,5) armchair and (10,0) zigzag SWNTs, stable configurations were analyzed. The orientation of the specific bonds of the defects is related to the most stable configuration among several possible configurations. The stable adsorption sites and binding energies of a Ni atom on three intrinsic defects were calculated and compared to those on perfect side walls. All defects enhance Ni adsorption, and the single vacancy shows the most exothermic binding. These results shed light on the nature of the interaction of the transition metal with defects in SWNT, an important topic to the many aspects of carbon nanotubes interacting with transition metals. Particularly, this is useful for the fabrication of nanosized transition metal particles supported on carbon nanotubes. 相似文献
234.
Dr. Surajit Some Sun Jun Kim Prof. Seong Chan Jun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(44):15480-15485
A simple and easy process has been developed to efficiently dope phosphorus into a graphene oxide surface. Phosphorus‐doped graphene oxide (PGO) is prepared by the treatment of polyphosphoric acid with phosphoric acid followed by addition of a graphene oxide solution while maintaining a pH of around 5 by addition of NaOH solution. The resulting materials are characterized by X‐ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT‐IR), X‐ray diffraction (XRD), Raman spectroscopy, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). The as‐made PGO solution‐coated cloth exhibits excellent flame retardation properties. The PGO‐coated cloth emits some smoke at the beginning without catching fire for more than 120 s and maintains its initial shape with little shrinkage. In contrast, the pristine cloth catches fire within 5 s and is completely burned within 25 s, leaving trace amounts of black residue. The simple technique of direct introduction of phosphorus into the graphene oxide surface to produce phosphorus‐doped oxidized carbon nanoplatelets may be a general approach towards the low‐cost mass production of PGO for many practical applications, including flame retardation. 相似文献
235.
Sun Choi Seung Hoon Oh Yong Seung Kim Kyeong Hak Seong Byeung Soo Lim Jong Hyung Lee 《Catalysis Surveys from Asia》2006,10(2):110-116
SK Corporation developed an advanced pyrolysis gasoline (pygas) upgrading (APUSM) technology based on a catalytic process for producing valuable benzene, toluene and xylenes (BTX) and liquefied petroleum gas (LPG) from pygas containing aromatics and non-aromatic hydrocarbons. Hydrodealkylation of heavy aromatics and hydrocracking of non-aromatic hydrocarbons occurred with facility in the conversion of pygas over a proprietary catalyst, metal promoted zeolite. This catalytic process produced benzene and toluene with high purity corresponding to chemical grade while giving mixed xylenes with reduced ethylbenzene. In the present study, we described novel features of the APUSM technology in terms of the process and catalyst. The influence of the process conditions was also examined. This technology has been commercially proven, and hence is available for licensing through Axens, which is a major engineering and licensing company. 相似文献
236.
Single‐step multiresidue determination of ten multiclass veterinary drugs in pork,milk, and eggs using liquid chromatography with tandem mass spectrometry 下载免费PDF全文
Jin‐A Park Dan Zhang Dong‐Soon Kim Seong‐Kwan Kim Kyeong‐Su Cho Dana Jeong Jae‐Han Shim Jin‐Suk Kim Ho‐Chul Shin 《Journal of separation science》2015,38(16):2772-2780
A multiclass, multiresidue determination method is reported for the detection of ten veterinary drugs, including scopolamine, metoclopramide, acriflavine, berberine, tripelennamine, diphenhydramine, acrinol, triamcinolone, loperamide, and roxithromycin in pork, milk, and eggs. The method involves a simple extraction using 0.1% formic acid in acetonitrile, followed by defatting with n‐hexane, centrifugation, and filtration prior to liquid chromatography with tandem mass spectrometric analysis. As ion suppression and enhancement effects are reported, matrix‐matched calibrations are used for quantification, with determination coefficients ≥0.9765. For the majority of the tested analytes, the intra‐ and interday accuracy (expressed as recovery %) range from 70.6 to 94.6% and from 70.1 to 93.3%, respectively, and the precision (expressed as relative standard deviation) ranges from 0.5 to 19.8% and from 2.8 to 18.4% in all matrices. The limits of quantification range between 0.5 and 10 ng/g. The validated tandem mass spectrometry method is successfully applied to market samples; the target analytes are not detected in any of the tested samples. In terms of accuracy, no extract cleanup is deemed necessary. The developed method is feasible for the simultaneous detection of the tested analytes in pork, milk, and eggs. 相似文献
237.
Rapid Preparation of Monolithic Columns for Capillary Electrochromatography Separation 总被引:1,自引:0,他引:1
Wen Jun GONG Yi Jun ZHANG Yu Ping ZHANG Seong Ho CHOI 《中国化学快报》2006,17(6):813-816
Sol-gel technology can provide a versatile approach to the synthesis of organic polymers and organic-inorganic hybrid materials applied in HPLC, micro-HPLC and capillary electrochromatography (CEC)1. It can take place under extraordinarily mild thermal co… 相似文献
238.
Jong Yeob Jeon Eun Yeong Hwang Seong Chan Eo Bun Yeoul Lee 《Journal of polymer science. Part A, Polymer chemistry》2014,52(11):1570-1580
High‐molecular‐weight poly(1,4‐butylene carbonate) (PBC) (Mn: 40,000?90,000) was prepared through the condensation polymerization of dimethyl carbonate (DMC) and 1,4‐butanediol (BD) in the presence of 0.05 mol % sodium alkoxide catalyst. The subsequent feeding of 15 mol % HOAOH, such as 1,6‐hexanediol, 1,5‐pentanediol, 1,4‐cyclohexanedimethanol, or 1,4‐benzenedimethanol and stirring at 190–150 °C converted the extremely thick high‐molecular‐weight polymer to low‐molecular‐weight macrodiols with GPC‐measured Mn ~2000. The analysis of the 1H NMR spectra indicated that the –A– units and 1,4‐butylene units were randomly distributed in the resulting oligomers. The chopping of the high‐molecular‐weight PBC using either triols or tetraols such as glycerol propoxylate, 1,1,1‐tris(hydroxymethyl)ethane, or pentaerythritol also afforded macropolyols containing branched chains with GPC‐measured Mn ~2000. When the chopped polymers were genuine PBCs, the resulting macrodiols or polyols were in a waxy state at room temperature. However, permanently oily compounds were obtained when the chopped polymers were prepared using 0.90 mole fraction of BD admixed with various other diols. The macrodiols and polyols synthesized in this study may have potential applications in the polyurethane industry. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1570–1580 相似文献
239.
Development of a new contactless dielectrophoresis system for active particle manipulation using movable liquid electrodes 下载免费PDF全文
This study presents a new DEP manipulation technique using a movable liquid electrode, which allows manipulation of particles by actively controlling the locations of electrodes and applying on–off electric input signals. This DEP system consists of mercury as a movable liquid electrode, indium tin oxide (ITO)‐coated glass, SU‐8‐based microchannels for electrode passages, and a PDMS medium chamber. A simple squeezing method was introduced to build a thin PDMS layer at the bottom of the medium chamber to create a contactless DEP system. To determine the operating conditions, the DEP force and the friction force were analytically compared for a single cell. In addition, an appropriate frequency range for effective DEP manipulation was chosen based on an estimation of the Clausius–Mossotti factor and the effective complex permittivity of the yeast cell using the concentric shell model. With this system, we demonstrated the active manipulation of yeast cells, and measured the collection efficiency and the dielectrophoretic velocity of cells for different AC electric field strengths and applied frequencies. The experimental results showed that the maximum collection efficiency reached was approximately 90%, and the dielectrophoretic velocity increased with increasing frequency and attained the maximum value of 10.85 ± 0.95 μm/s at 100 kHz, above which it decreased. 相似文献
240.
A Label‐Free Electrochemical Aptasensor for Thrombin Using a Single‐Wall Carbon Nanotube (SWCNT) Casted Glassy Carbon Electrode (GCE) 下载免费PDF全文
An electrochemical aptasensor with a thrombin binding aptamer (TBA) was developed using a single‐wall carbon nanotube (SWCNT) casted GCE. The TBA was immobilized on SWCNTs through π‐stacking without any special modification, resulting in helical wrapping to the surface. In the presence of thrombin, the TBA binds with thrombin and the TBA concentration on the SWCNT surface decreases. The remaining amount of TBA can be analyzed by an electrochemical method without any label, because the guanine bases of the nucleic acid are measurable by electrochemical methods. The electrochemical oxidation of guanine nucleotides was enhanced by electrocatalytic mediation using Ru(bpy)32+ for higher sensitivity and reduction of the overpotential for electrochemical detection. 相似文献