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51.
Solvent and pH effects on fast and ultrasensitive 1,1'-oxalyldi(4-methyl)imidazole chemiluminescence
Solvent and pH effects on fast and ultrasensitive 1,1'-oxalyldi(4-methyl)imidazole chemiluminescence (OD4MI-CL) were studied. The influences of these two factors on the complex OD4MI-CL reaction are discussed within a conceptual prototype for developing aqueous and non-aqueous capillary electrophoresis (ACE and NACE) devices with OD4MI-CL detection. The reaction channel length and OD4MI yield from the reaction between bis(2,4,6-trichlorophenyl) oxalate (TCPO) and 4-methylimidazole in the channel will be influenced by pH, water volume fraction, and cosolvent properties of the solution. Optimum OD4MI-CL efficiency is observed at pH 6.5 when 1-propanol, which has a low dielectric constant (epsilon = 20.8), is used as the NACE solvent in the separation channel. Water (epsilon = 80.1), the solvent in the ACE separation channel, acts similarly to a high dielectric constant organic solvent in NACE because the disadvantages normally associated with TCPO-CL reactions in water disappear due to the faster OD4MI-CL reaction versus OD4MI decomposition in aqueous solution. Therefore, it is expected that the OD4MI-CL detection system can be used in both NACE and ACE devices without requiring detector modifications. We also conclude that OD4MI-CL detection in NACE and ACE devices will be much more sensitive than the TCPO-CL detection used in current NACE devices. 相似文献
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In the separation of several substances by displacement development, the minimum distance is calculated that the band must travel to obtain a separation of the solutes into zones.The method has been applied to the separation of lithium, sodium, ammonium and potassium ions on Dowex-50 resin, using calcium ions as the developer. 相似文献
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Label-free cell separation and sorting in microfluidic systems 总被引:2,自引:0,他引:2
Daniel R. Gossett Westbrook M. Weaver Albert J. Mach Soojung Claire Hur Henry Tat Kwong Tse Wonhee Lee Hamed Amini Dino Di Carlo 《Analytical and bioanalytical chemistry》2010,397(8):3249-3267
Cell separation and sorting are essential steps in cell biology research and in many diagnostic and therapeutic methods. Recently,
there has been interest in methods which avoid the use of biochemical labels; numerous intrinsic biomarkers have been explored
to identify cells including size, electrical polarizability, and hydrodynamic properties. This review highlights microfluidic
techniques used for label-free discrimination and fractionation of cell populations. Microfluidic systems have been adopted
to precisely handle single cells and interface with other tools for biochemical analysis. We analyzed many of these techniques,
detailing their mode of separation, while concentrating on recent developments and evaluating their prospects for application.
Furthermore, this was done from a perspective where inertial effects are considered important and general performance metrics
were proposed which would ease comparison of reported technologies. Lastly, we assess the current state of these technologies
and suggest directions which may make them more accessible. 相似文献
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Thin film deposition processes emit large amounts of NF3 and by-product particles, which are of great concerns in the semiconductor industry, from the environmental and economic points of view. With an objective to overcome these concerns, plasmas are generated from a cylindrical reactor placed before a vacuum pump. The discharge stability is evaluated by monitoring the changes in the plasma images with the pressure. By using a particle sampler and a particle trap, the size and quantity of the by-product particles are compared during plasma-on and plasma-off. The effects of adding O2 and H2O to the by-products of the NF3 abatement process are investigated by analyzing the spectra obtained with a Fourier transform infrared spectroscopy. Further, the H2O flow rate is optimized for the highest destruction and removal efficiency of NF3. Finally, the applicability of our device to the after-treatment equipment is discussed. 相似文献
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In this note, we construct generalized Shioda-Inose structures on K3 surfaces using cyclic covers and almost functoriality of Shioda-Inose structures with respect to normal subgroups of a given group of symplectic automorphisms. 相似文献
60.
A Highly Stable and Magnetically Recyclable Nanocatalyst System: Mesoporous Silica Spheres Embedded with FeCo/Graphitic Shell Magnetic Nanoparticles and Pt Nanocatalysts
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Da Jeong Kim Dr. Yan Li Yun Jin Kim Prof. Nam Hwi Hur Prof. Won Seok Seo 《化学:亚洲杂志》2015,10(12):2755-2761
We have developed a highly stable and magnetically recyclable nanocatalyst system for alkene hydrogenation. The materials are composed of mesoporous silica spheres (MSS) embedded with FeCo/graphitic shell (FeCo/GC) magnetic nanoparticles and Pt nanocatalysts (Pt‐FeCo/GC@MSS). The Pt‐FeCo/GC@MSS have superparamagnetism at room temperature and show type IV isotherm typical for mesoporous silica, thereby ensuring a large enough inner space (surface area of 235.3 m2 g?1, pore volume of 0.165 cm3 g?1, and pore diameter of 2.8 nm) to undergo catalytic reactions. We have shown that the Pt‐FeCo/GC@MSS system readily converts cyclohexene into cyclohexane, which is the only product isolated and Pt‐FeCo/GC@MSS can be seperated very quickly by an external magnetic field after the catalytic reaction is finished. We have demonstrated that the recycled Pt‐FeCo/GC@MSS can be reused further for the same hydrogenation reaction at least four times without loss in the initial catalytic activity. 相似文献