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排序方式: 共有1033条查询结果,搜索用时 93 毫秒
31.
Bodwell GJ Bridson JN Cyrañski MK Kennedy JW Krygowski TM Mannion MR Miller DO 《The Journal of organic chemistry》2003,68(6):2089-2098
32.
MacMillan JB Ernst-Russell MA de Ropp JS Molinski TF 《The Journal of organic chemistry》2002,67(23):8210-8215
The structures of lipopeptides lobocyclamides A (1), B (2), and C (3) were solved using a combination of mass spectrometry, 2D NMR spectroscopy, and degradative analysis. Lobocyclamides B and C are the first peptides reported with the unusual amino acid 4-hydroxythreonine and also incorporate the rare homologous long-chain beta-amino acids 3-aminooctanoic acid and 3-aminodecanoic acid, respectively. The absolute configurations of the amino acid residues in each compound were assigned, after acid hydrolysis, by either direct chiral HPLC comparison with authentic standards or by prior derivatization by Marfey's method and reversed-phase HPLC. Both compounds exhibited moderate antifungal activity against a panel of Candida spp., including two fluconazole-resistant strains. When tested as a mixture, lobocyclamides A and B displayed synergistic in vitro antifungal activity, a phenomenon noted earlier for the related peptides laxaphycins A and B. 相似文献
33.
Tadeusz Bednarski 《Probability Theory and Related Fields》1981,58(3):397-405
Summary Solutions to minimax test problems between neighbourhoods generated by specially defined capacities are discussed. The capacities are superpositions of probability measures and concave functions, so the paper covers most of the earlier results of Huber and Rieder concerning minimax testing between -contamination and total variation neighbourhoods. It is shown that the Neyman-Pearson lemma for 2-alternating capacities, proved by Huber and Strassen, can be applied to test problems between noncompact neighbourhoods of probability measures. It turns out that the Radon-Nikodym derivative between the special capacities is usually a nondecreasing function of the truncated likelihood ratio of some probability measures. 相似文献
34.
Five chemical compounds, CuMoO4, Cu3Mo2O9, Cu2Mo3O10, Cu6Mo4O15, and Cu4?x Mo3O12 (0.10 ? x ? 0.40), were identified in the system Cu2OCuOMoO3 and characterized by DTA, X-ray powder patterns, ir spectra, and magnetic properties. Cupric molybdates CuMoO4 and Cu3Mo2O9 are stable in air up to 820 and 855°C, respectively, melting at these temperatures with simultaneous decomposition (oxygen loss). Congruent mp of cuprous molybdates Cu2Mo3O10 and Cu6Mo4O15, in argon, are 532 and 466°C, respectively. Nonstoichiometric phase Cu4?x Mo3O12 = Cu2+3Cu01?xMo6+3O12, melts in argon between 630 and 650°C depending on the value of x and at 525–530°C undergoes polymorphic transformation. Areas of coexistence of the above-mentioned phases are determined. The μeff of Cu2+ ions and θ values are: 1.80 B.M. and 28°K for CuMoO4, 1.71 B.M. and ? 12°K for Cu3Mo2O9, and 1.74 B.M. and ? 93°K for Cu4?xMo3O12. Below 200°K CuMoO4 becomes antiferromagnetic. Cu2Mo3O10 and Cu6Mo4O15 show weak temperature-independent paramagnetism. 相似文献
35.
Teresa Olszewska Maria J. Milewska Maria Gdaniec Tadeusz Połoński 《Tetrahedron: Asymmetry》2012,23(3-4):278-283
The crystal structures of several bicyclic N-nitrosamines indicate that they crystallize in the chiral (Sohncke) space group P212121 as conglomerates. This allows the resolution of these compounds by manual picking of the enantiomorphous crystals. The optical activity of the single crystals was confirmed by their CD spectra taken in KBr disks. The absolute configurations of the title nitrosamines were assigned by crystallographic measurements and by a comparison of their CD spectra with those of a reference compound resolved by classical methods. The observed Cotton effect signs, corresponding to the n–π1 transition, were correlated with the helicity of the inherently chiral nitrosamine chromophore. 相似文献
36.
Abstract Products of polyaddition of isocyanates with other components containing reactive atoms of hydrogen are of growing interest due to various possibilities of their application. 相似文献
37.
38.
Prof. Juliusz Pernak Michał Niemczak Prof. Łukasz Chrzanowski Łukasz Ławniczak Przemysław Fochtman Katarzyna Marcinkowska Prof. Tadeusz Praczyk 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(34):12012-12021
This study focused on the synthesis and subsequent characterization of herbicidal ionic liquids based on betaine and carnitine, two derivatives of amino acids, which were used as cations. Four commonly used herbicides (2,4‐D, MCPA, MCPP and Dicamba) were used as anions in simple (single anion) and oligomeric (two anions) salts. The obtained salts were subjected to analyzes regarding physicochemical properties (density, viscosity, refractive index, thermal decomposition profiles and solubility) as well as evaluation of their herbicidal activity under greenhouse and field conditions, toxicity towards rats and biodegradability. The obtained results suggest that the synthesized herbicidal ionic liquids displayed low toxicity (classified as category 4 compounds) and showed similar or improved efficacy against weed compared to reference herbicides. The highest increase was observed during field trials for salts containing 2,4‐D as the anion, which also exhibited the highest biodegradability (>75 %). 相似文献
39.
Dr. Mateusz Janeta Prof. Tadeusz Lis Prof. Sławomir Szafert 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(60):13686-13697
In the present research, the synthesis, spectroscopic characterization, and structural investigations of a unique ZnII complex of imine-functionalized polyhedral oligomeric silsesquioxane (POSS) is designed, and hereby described, as a catalyst for the synthesis of cyclic carbonates from epoxides and CO2. The uncommon features of the designed catalytic system is the elimination of the need for a high pressure of CO2 and the significant shortening of reaction times commonly associated with such difficult transformations like that of styrene oxide to styrene carbonate. Our studies have shown that imine-POSS is able to chelate metal ions like ZnII to form a unique coordination complex. The silsesquioxane core and the hindrance of the side arms (their steric effect) influence the construction process of the homoleptic Zn4@POSS-1 complex. The compound was characterized in solution by NMR (1H, 13C, 29Si), ESI-MS, UV/Vis spectroscopy and in the solid state by thermogravimetric/differential thermal analysis (TG-DTA), elemental analysis, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), cross-polarization magic angle spinning (CP MAS) NMR (13C, 29Si) spectroscopy, and X-ray crystallography. 相似文献
40.