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21.
Morimasa Saito 《Analytical and bioanalytical chemistry》1995,351(2-3):148-153
Relative sensitivity factors (RSF) (Fe=1) were determined for steel, aluminium and copper standard samples by direct current glow discharge mass spectrometry using Kr and Xe as discharge gas. In general, the RSF values in Kr and Xe were higher than in Ar; however for S and P in Kr gas and P, As and Se in Xe gas they were considerably lower. This decrease is related to the relative importance of the Penning ionization process in overall ionization of the sputtered species. The results showed the percentage of Penning ionization to account for 75.6–82.0% for Se, As and P and 64.2% for S. 相似文献
22.
Yuzo Yamazawa Tadashi Iwai Akihiko Ito Koichiro Hayashi 《Journal of polymer science. Part A, Polymer chemistry》1971,9(2):257-263
The in-source polymerization of trioxane in the solid state was investigated over a wide range of temperature and pressure, i.e., from 30 to 140°C and up to 7000 kg/cm2, respectively. In the polymerization that was carried out slightly below the melting point under pressure, the higher the pressure, the higher the rate of polymerization. It was confirmed that the maximum rate of solid-state polymerization of trioxane occurs near the melting points, even under elevated pressure. The rate of polymerization decreased with increasing pressure at constant temperature. The shape of the time–conversion curves may be classified into two types, i.e., one which is typical of high pressure and low temperature, and the other which is typical of low pressure and high temperature. Changes in the shape of the conversion—intrinsic viscosity curves occurred coincidentally. Thus, three regions for the different “polymerization characteristic” were determined as functions of polymerization temperature and pressure. Explanations are given for the above-mentioned polymerization characteristic. 相似文献
23.
Yahachi Saito Tadao Koyama Kenichiro Kawabata 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):421-424
Single-layer (SL) carbon tubes were produced by arc evaporation of graphite rods containing iron-group metals (Fe, Co, Ni, Fe/Co, Co/Ni, Fe/Ni) under He and Ar gas. Transmission electron microscopy (TEM) revealed that these elemental and binary metals, excluding Fe which need a special atmosphere (a mixture of Ar and CH4), showed catalytic activity producing SL tubes under pure inactive gases. Fe/Ni alloy was the most effectual catalysts for producing SL tubes. The highest abundance of SL tubes in raw soot was estimated to be ~ 10% from TEM observation. Smoke particles directly caught on TEM grids near an evaporation source during arcburning were also investigated, and it was suggested that small metal particles were first formed in the gas phase and then SL tubes grew from them. 相似文献
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N Saito H Kawaguchi Y Ohtsuka N Shimizu S Inayama 《Chemical & pharmaceutical bulletin》1991,39(11):3085-3087
Hansenula anomala, which catalyzes an asymmetric reduction, was immobilized in bulk or spherical crosslinked polymers. The catalytic activity of the yeast for enantio-selective reduction of 3,8-dioxo-4-methoxycarbonyl-9-methyl-delta 4(10)-octalin (lab) was severely affected by the immobilization conditions, such as the crosslink density, and by hydrophobicity of polymers and other components used for immobilization, oxygen concentration in the medium, etc. In some immobilized systems, the ratio of resulting enantiomers was inverted from that in a free yeast system. 相似文献
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A rapid and sensitive high-performance liquid chromatographic method has been developed for the quantitative analysis of methylguanidine and guanidine in physiological fluids. These quanidino compounds are separated on a 6 x 0.23 cm cation-exchange column with 0.5 M sodium hydroxide solution. The guanidino compounds are detected with a fluorometer, which monitors the fluorescent guanidine derivatives produced by the reaction of the eluted constituents with 9,10-phenanthrenequinone. Sensitivity to sub-nanomole levels of methylguanidine and guanidine is demonstrated. The method was successfully applied to physiological fluids such as serum and cerebrospinal fluid from uremic patients. 相似文献
30.
Hato M Yamashita I Kato T Abe Y 《Langmuir : the ACS journal of surfaces and colloids》2004,20(26):11366-11373
Temperature- and concentration-dependent aqueous phase diagram of a novel alkylglycoside, 1-O-phytanyl-beta-D-xyloside (beta-Xyl(Phyt)), was studied using small-angle X-ray scattering, polarizing optical microscopy, and differential scanning calorimetry. The phases found in this system include an Lc phase, an Lalpha phase, an HII phase, two inverted cubic phases of crystallographic space groups Pn3m and Ia3d, and a fluid isotropic phase, FI. The phase diagram of the beta-Xyl(Phyt)/water system is similar to that for the 1-monooleylglycerol (MO)/water system, suggesting that the phase behavior is largely determined by the overall molecular shape rather than the details of surfactant molecular structure. Moreover, the structural parameters of the beta-Xyl(Phyt) liquid crystals are also similar to those of the MO/water, due primarily to the similar molecular dimensions of two molecules. As compared to the MO/water system, however, the beta-Xyl(Phyt)/water system displays a lower value of TK ( approximately 8.(5) degrees C) and a wider temperature window for the mesophases (8.(5)-120 degrees C). Moreover, beta-Xyl(Phyt) is chemically more robust than MO, as the ether linkage is more stable against hydrolysis than the ester linkage and the phytanyl chain is fully saturated. 相似文献