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61.
62.
Nozawa K Gailhanou H Raison L Panizza P Ushiki H Sellier E Delville JP Delville MH 《Langmuir : the ACS journal of surfaces and colloids》2005,21(4):1516-1523
Control over the synthesis of monodisperse silica particles up to mesoscopic scale is generally made difficult due to intrinsic limitation to submicrometric dimensions and secondary nucleation in seeded experiments. To investigate this issue and overcome these difficulties, we have implemented single step processing by quantifying the effects of the progressive addition of a diluted tetraethyl orthosilicate solution in ethanol on the size and monodispersity of silica particles. Contrary to particles grown in seeded polymerization, monodisperse particles with size up to 2 microm were synthesized. Moreover, the particles exhibit a final diameter (d(f)), which varies with V(-1/3) over more than 2 orders of magnitude in rate of addition (V). On the basis of a kinetic study in the presence of addition showing that particle growth is limited by the diffusion of monomer species, we developed a diffusion-limited growth model to theoretically explain the observed d(f)(V) behavior and quantitatively retrieve the measured amplitude and exponent. Using a single parameter procedure, we can therefore predict and generate in the room temperature range, monodisperse particles of a targeted size by simply adjusting the rate of addition. 相似文献
63.
Structure of amipurimycin was determined chemically to be . 相似文献
64.
65.
A method is described for the determination of benzethonium and benzalkonium compounds (1–5 × 10?6 M) based on the formation of ion-associates with bromocresol green (BCG) and quinine in 1,2-dichloroethane. Benzethonium and benzalkonium are extracted quantitatively after the formation of a new type of ion-associate with BCG and quinine in an aqueous solution at pH 8.2. The ion-associate shows an absorption maximum at 630 nm. Many other quaternary ammonium species and amines do not interfere. The method is applied to a range of pharmaceutical products. 相似文献
66.
Using a straightforward chemo-enzymatic procedure, 1-beta-O-acyl glucuronides of three non-steroidal anti-inflammatory drugs, diclofenac (DF) 5, mefenamic acid (MF) 6 and (S)-naproxen (NP) 7, were prepared. Caesium salts of these carboxylic acid drugs reacted with commercially available methyl 2,3,4-tri-O-acetyl-1-bromo-1-deoxy-alpha-D-glucopyranuronate 4 to give exclusively the corresponding 1-beta-O-acyl glucuronides 8-10 in moderate yields. The protecting acetyl (for -OH group) and methyl ester (for -CO2H group) groups of each sugar moiety were easily removed to provide the corresponding free 1-beta-O-acyl glucuronides 1-3 in high yields. Deprotection was achieved through effective enzyme-catalysed chemo-selective hydrolyses of the acetyl groups using lipase AS Amano (LAS), and of the methyl ester group using esterase from porcine liver (PLE). 相似文献
67.
Hiraku Nozawa 《manuscripta mathematica》2010,132(1-2):257-271
Let ${(M,\mathcal{F})}$ be a closed manifold with a Riemannian foliation. The Álvarez class of ${(M,\mathcal{F})}$ is a cohomology class of M of degree 1 whose triviality characterizes the minimizability or the geometrically tautness of ${(M,\mathcal{F})}$ . We show that the integral of the Álvarez class of ${(M,\mathcal{F})}$ along every closed path is the logarithm of an algebraic integer if π1 M is polycyclic or ${\mathcal{F}}$ is of polynomial growth. 相似文献
68.
Tadao Shimizu 《应用光谱学评论》2013,48(2):163-221
Various characteristics of molecules have been clarified by spectroscopic methods in which the interactions of molecules with the radiation field were investigated. A stationary response of a molecule excited by a radiation field appears as a spectral line. Information on molecules may be obtained from position (resonance frequency), intensity, and shape and width of the spectral line. So far the interaction of molecules with the radiation field has been studied primarily in a “frequency domain.” Although molecular spectroscopy is one of the research fields in modern science which has the longest history, a variety of important aspects have been demonstrated very recently in this field as radiation sources have been improved. When the radiation field is “weak,” the photon nature of the radiation field is dominant in the interaction with a molecule, such as in the cases of emission, absorption, and scattering of photons. When the radiation field is “strong,” in the sense that many photons exist in a proper mode of the radiation field, the wave nature of the field plays an important role in the interaction. In this case the radiation may be described in the form of the classical field, say, a sinusoidal function of the time and spatial coordinates, coherently interacting with the molecule, which is described quantum mechanically. Here nonlinear properties would appear in the interactions: saturation in absorption, induced scattering, multiphoton processes, coherent transients, etc. 相似文献
69.
The chemical etching of fission tracks in ethylene-tetrafluoro-ethylene copolymer was studied. Etched holes 3000–4000 Å in diameter was recognized by electron microscopy for a film bombarded by fission fragments in oxygen and etched in a 12N sodium hydroxide solution at 125°C. The radial etching rate at 125°C was 6–8 Å/hr, which is less than 17 Å/hr for polyvinylidene fluoride in the same sodium hydroxide concentration at 85°C. The smaller rate is a reflection of the larger chemical resistivity of ethylene-tetrafluoro-ethylene copolymer than polyvinylidene fluoride. 相似文献
70.
T. Kawabata T. Adachi M. Fujiwara K. Hatanaka Y. Ishiguro M. Itoh Y. Maeda H. Matsubara H. Miyasako Y. Nozawa T. Saito S. Sakaguchi Y. Sasamoto Y. Shimizu T. Takahashi A. Tamii S. Terashima H. Tokieda N. Tomida T. Uesaka M. Uchida Y. Yasuda N. Yokota H. P. Yoshida J. Zenihiro 《Few-Body Systems》2013,54(1-4):93-97
The alpha inelastic scattering from 24Mg was measured to obtain the isoscalar natural-parity excitation strengths and to search for the α-condensed states. The multipole decomposition analysis for the measured cross sections was performed. The strength distributions for the ${{\Delta}L=0{-}3}$ were successfully obtained and the possible candidates for the α-condensed states around the 16O core were found. 相似文献