Au_(38)团簇上小分子H_2O和O_2共同吸附的第一性原理研究

利用密度泛函理论(DFT)计算的方法,对O_2,H_2O单独吸附和共吸附在Au_(38)团簇上的吸附性质进行了结构,能量和电子分析.计算结果表明,O_2倾向于吸附在edge位,H_2O则倾向于吸附在top位.Au(100)表面较之Au(111)表面更有利于O_2,H_2O的吸附,这与实验结果相符合.H_2O和O_2共吸附研究表明,H_2O的存在促进了O_2的吸附.Mulliken和分态密度(PDOS)分析得出:在共吸附中,H_2O将部分电子转移给了O_2,促进了O_2的活化与解离,并生成了类似H_2O_2的中间态,从而为催化氧化反应提供了O活性物种.     

Ti(SO_4)_2水解-水热法制备锐钛型纳米TiO_2及其光催化性能

以Ti(SO4)2水溶液为原料,在水热条件下直接水解合成了锐钛型纳米TiO2颗粒。利用透射电镜(TEM)、X射线衍射(XRD)、BET低温吸附和紫外-可见光谱(UV-Vis)等方法对产物进行了表征,并研究了样品光催化降解甲基橙(MO)的性能。结果表明所制得纳米TiO2颗粒为锐钛矿型,晶型良好,平均粒径为24 nm,BET比表面积约为56.20 m2.g-1。光催化活性与商品纳米TiO2(P25)相近,具有良好的工业应用前景。     

Narrow Linewidth Tm^3＋-Doped Large Core Fiber Laser Based on a Femtosecond Written Fiber Bragg Grating

A diode laser （LD） clad-pumped narrow linewidth all-fiber Tm^3＋-doped fiber laser is reported with a maximal output power of 27W at 1.947μm. By successively splicing an LD pigtail fiber, a single-mode Tm^3＋-doped fiber, and a multi-mode Tm^3＋-doped fiber, the fiber laser has 70pm narrow linewidth output, and a high slope efficiency of nearly 47.5% with respect to the launched pump power. The high reflectivity fiber Bragg gratings, which are directly written into the single-mode Tm^3＋-doped fiber core by the 800nm femtosecond pulsed laser, act as the high reflectivity coupler. The output laser has diffraction-limited beam quality with a factor M^2 of 1.29, when the output laser power is nearly 27W.     

Hopf Bifurcations for the Recently Proposed Smooth-and-Discontinuous Oscillator

We investigate the Hopf bifurcations of the recently proposed smooth-and-discontinuous （SD） oscillator which exhibits both smooth and discontinuous dynamics depending on the value of a parameter a. The nonlinearity presented in this system characterizes irrationality and piecewise linearity for smooth and discontinuous cases, respectively, which could not meet the requirements of the conventional methods due to the barrier of Taylor expansion. Introducing a series of new kinds of elliptic integrals of the first and second kind to the perturbed oscillator, we obtain the Poincare-Birchoff normal forms of Hopf bifurcations for both smooth and discontinuous regimes. We also demonstrate the criteria for the occurrence of Hopf bifurcations, the stability of periodic solutions bifurcating from the equilibria and the excellent agreement between the theoretical and numerical results.     

依赖强度耦合的级联三能级原子系统中双模压缩真空初态场的非经典性质

运用全量子理论研究了依赖强度耦合的级联三能级原子系统中双模压缩真空初态场的压缩及量子统计性质,并讨论了初始光场的压缩参量以及原子—光场单光子失谐量对光场非经典性质的影响.     

高山仰止,四海闻之——贺马大猷先生九十五岁华诞

<正>2010年3月1日,是国际著名声学家、我国现代声学事业的开创者和奠基者之一、中国科学院资深院士、中国科学院声学研究所研究员、《声学学报》主编马大猷先生95岁华诞,为此,《声学学报》编辑部从先生的部分学生和同事中征集了声学基础和声学应用基础研究方面有代表性的研究论文,专辑出版,以     

溅射工艺参数对硅薄膜微结构影响的Raman分析

为了解决碳化硅难以进行光学加工的问题,该文采用射频磁控溅射方法,在碳化硅反射镜坯体上沉积与碳化硅具有相近热膨胀系数且易于进行光学加工的硅薄膜。利用拉曼光谱(Raman)对衬底温度、射频功率、衬底偏压等溅射工艺条件对硅膜微结构的影响进行了分析。研究发现：随着衬底温度的升高,薄膜的晶化率先增大后减小;衬底偏压的增加不利于薄膜有序结构的形成;射频功率对薄膜微结构的影响比较复杂,随着功率的升高,薄膜晶粒尺寸减小,晶化率降低,当射频功率进一步升高时,薄膜中有序团簇尺寸和晶化率逐渐升高。但过高的射频功率反而不利于薄膜的晶化。     

N2���������ŵ���΢���������ŵ�ת���PIC/MCģ��

开发了氮空心阴极放电PIC/MC二维自洽模型。研究了N2传统空心阴极向微空心阴极放电转变过程中电势和电场的变化。结果表明,不同尺寸的空心阴极放电的电势及电场分布规律几乎类似,但空心阴极孔径减小且气压增加时,电场近似线性增加;典型微空心阴极电场比传统空心阴极放电电场约大3个量级;微空心阴极放电产生的电子,氮分子离子和氮原子离子的密度比传统空心阴极放电约大3个量级,且微空心阴极放电中,N2+密度比N+密度大8倍以上。     

Coupled THz Waveguide Utilizing Surface Plasmon Polaritons on Thin Dielectric Slab Sandwiched between Two Corrugated Metallic Claddings

We present a comprehensive experimental study of terahertz （THz） wave propagation utilizing surface plasmon polaritons （SPPs） on the interfaces of a thin dielectric core layer sandwiched between two corrugated metallic claddings. THz wave impinges on the structured surfaces at normal incidence. Long-lasting oscillation propagation features are observed in the temporal waveform after traveling through the periodic arrays. The enhanced THz transmission can be achieved due to the coupling between incident waves to SPPs at the bottom and top interfaces. The finite element method is used to simulate the field distribution and the transmission mode in the waveguide. The hybrid waveguide with low absorption has great potential applications in THz integrated devices.     

有机垃圾厌氧发酵过程的生物反应热模型研究

为了考察有机厌氧发酵过程生物热对发酵系统温度的影响,利用微生物生长动力学模型方程式和各组分的物料衡算方程式,建立了有机垃圾厌氧发酵生物反应热的动力学模型,并通过遗传算法对模型部分参数进行了优化.计算结果与文献中的实验值最大相对误差小于2%,表明所建立的生物反应热模型基本可信.本文模型和计算结果可为有机垃圾厌氧发酵过程保温装置的优化设计提供参考依据.