基于三苯胺和咔唑的联吡啶铱化合物的合成及其在光催化水产氢中的应用研究

以三苯胺、咔唑、4,4′-二羧基联吡啶为原料,设计并合成了两个联吡啶铱（III）配合物Ir1和Ir2,其结构经¹H NMR, ¹³C NMR和HR-MS(MALDI-TOF)表征。并利用紫外可见光谱（UV-Vis）、荧光发射光谱（Photoluminescence）和循环伏安法研究了化合物的光学和电学性质。结果表明：Ir1和Ir2的紫外可见光吸收波长分别位于456 nm 和448 nm,相应的发射波长分别为645 nm和678 nm,说明其均能利用可见光; Ir1和Ir2的HOMO电位为-5.125~-5.510 eV, LOMO电位为-2.880~-0.310 eV,满足作为光敏剂的基本条件。研究了化合物在可见光照射下光催化水分解产生氢气的效果。结果表明：Ir1和Ir2的氢气值TONs(turnover numbers)达到2 827和1 908。     

α-Carbonyl Radical Cyclizatio n in Organic Synthesis

Intramolecular radical cyclization reactions are now used routinely to synthesize carbocyclic and heterocyclic structures. We have reported that α-carbonyl radicals 1, generated from the corresponding iodo ketones or enones, underwent intramolecular radical cyclization smoothly to afford products 2.1, 2,3     

银袋内酯乙的乙酰化物的晶体结构和分子结构

本文报道从变色马兜铃(Aristolochia versicolar)的块根中提取的一种新倍半萜内酯-银袋内酯乙的乙酰化物的晶体结构和分子结构.分子式为C~17H~22O~4,分子量290.4,晶体属单斜晶系,空间群为P2~1,a=0.9594(5),b=0.6626(6),c=1.2924(12)um,β=94.48(6)`,V=0.819(1)nm^3,Z=2,Dx=1,18g.cm^-^3,F(000)=266e,μ=0.77cm^-^1(MoKa).结构用直接法解出,经最小二乘法修正后1280个衍射点偏离因子为R=5.5%,Rw=5.2%.分子由椅型.椅型的1,5二烯十员环([2323]矩形)和共用两个相邻DunitzIII型碳C(4),C(5),一个Dunitz II型碳C(6)的五员内酯环组成.十员环与五员内酯环之间夹角为99.该分子骨架拓扑在迄今已知的倍半萜内酯中只与银袋内酯丙相似.所有非氢原子的键长和键角均在实验误差范围内接近理论值。     

APPROXIMATE B.S. WAVE FUNCTIONS FOR AN ELECTROMAGNETIC BOUND SYSTEM OF SPINS (1/2, 1/2) OR (1/2, 1/2) WITH UNEQUAL MASSES

The Bethe-Salpeter equation for an electromagnetic bound system of spins (1/2—1/2) or (1/2—1/2) with unequal masses are solved in this paper. The approximate B.S. wave functions for these systems are given. Utilising these wave functions, the decay rate and branching ratio for Ξ⁰→(Σ⁺μ^－)+v_μ are calculated with accuracy up to order O(α). The results are wΞ⁰→(Σ⁺μ^－)+v_μ1.12(1/sec) and R=[wΞ⁰→(Σ⁺μ^－)+v_μ]/[wΞ⁰→(Σ⁺μ^－)+v_μ]4.7×10^-7. Similarly, the process Λ→(pμ^－)+v_μ is also discussed.     

COMMENTS ON THE NEW NEUTRINO "BALANCE": A DISCUSSION OF THE FEASIBILITY OF USING THE ELECTRON CAPTURE PROCESS IN158Tb, 157Tb FOR NEUTRINO MASS DETERMINATION

It is found that owing to the large energy difference in K-and L-shells of the daughter atom, ¹⁵⁸Tb is not the best candidate for neutrino "balance". Instead, ^l57Tb can offer a better chance for. neutrino mass determination if the Q-value 55 far obtained is verified. If it is so,then the relevant atomic calculation with high precision is very necessary. It is shown that to include the radiative correction in the Hartree-Fock calculation is very important for such atoms as ¹⁵⁷Gd and ¹⁵⁷Tb.     

ON THE NEUTRINO MASS,THE ABUNDANCE OF RIGHT-HANDED NEUTRINO AND THE CLOSENESS OF THE UNIVERSE

We point out that although the neutrino mass is finite,the left-handed neutrino density still dominates over the righthanded one in the universe unless there exists one or more elementary fernions (quark or lepton) whose mass is larger than 10⁶ GeV. or M_WR/M_WL≤10². (M_WLand M_WR are the left and right handed intermediate boson respectively.If there exists neutrino the mass of which is about 34 ev. as indicated in some experiments, then one can conclude that the total neutrino mass of the universe s,bvld contribute abput 99%. to the whole masses and lead to the closeness of the universe.This conclusion can be brought to the agreement of all observation datd which have been-obtained so far. A mass limit of all species of neutrinos obtained by reexamining all data is ≤ 200 eV.     

INFORMATION ABOUT SUBQUARK FROM EXPERIMENTS ON SUPERNIGH ENERGY COSMIC RAY

In this paper a kind of fireball model for subquark stratum is proposed, which can be used to explain the cosmic ray experiments for superhigh energy range, e. g., the mean multiplicity of secondary particles increases as S increases average transversal momentum ⊥> increases as S increases …etc. It can also give predictions which can be verified experimentally. This means that the information of the existence of subquark can be probed in the experiments on superhigh energy cosmic ray. Furthermore, this also means that some new phenomena observed in the experiments. on superhigh energy cosmiq ray provide. probably this kind of information.     

CIRCULAR DICHROISM SPECTRA OF SYSTEM I PARTICLES FROM NORMAL CHLOROPLASTS AND CAROTENOID-DEFICIENT MUTANTS OF MAIZE

Abstract— Circular dichroism (CD) spectra were studied in System I particles prepared by digitonin fragmentation of chloroplasts of normal maize and carotenoid-deficient mutants. CD bands of pigment molecules were found to be higher in particles than in solutions. This phenomenon was most pronounced for the particles containing the carotenoid composition of normal chloroplast lamellae. The CD signal of chlorophylls bound to particles of carotenoid-deficient chloroplasts was closer to that found in solutions. This indicates that aggregation and/or binding of chlorophylls in carotenoid-deficient mutants may be less extensive than in normal chloroplasts.     

Development of an RPLC-based Method for Measurement of Indoprofen Stability and Validation of the Method

A method for quantitative measurement of the photochemical decomposition of the anti-inflammatory agent, indoprofen （INP） is descriped. An RPLC-based assay that could determine the extent of degradation of INP in a rapid, sensitive, and accurate manner was developed. The method was validated under photoirradiation. Quantitation was monitored with an Inertsil ODS-3V column using a mobile phase of acetonitril and 1% HOAc solution in deionized H2O. Statistics relevant to the system criteria, peak integrity and resolution among the parent drug and its degradation products were performed. From the intra- and inter-day tests, the coefficients of variation were found to range from 0.59% to 4.25% for the former and from 0.71% to 4.86% for the latter. The good selectivity and specificity of this RPLC-based procedure render it suitable for measurements of INP stability.     

聚焦形貌恢复方法模型设计

采用基于拉普拉斯算符聚焦形貌恢复方法,提出了模拟目标深度测量的数值模型。数值模拟的核心是基于通过几何光学预测的理想图像的卷积与透镜广义孔径函数的多色点扩散函数,即用聚焦误差替代抛物线圆柱形貌或高斯函数。该模型可以使用基于聚焦形貌恢复方法的传感器真实组件参数、光源光谱、光学系统离差、相机的光谱灵敏度。提出了光学系统离差（消球差、消色差、色差）对确定目标表面形貌的精确度和可靠性的影响。结果表明,该模型可以有效提高实验效率,缩短时滞,降低成本。