CdSe量子点的光物理性质研究与荧光杂化纤维的制备

半导体纳米晶体(NCs)具有良好的光稳定性,广泛的发射持久性和高消光系数,在过去几年被广泛研究报道,其中,硒化镉半导体纳米晶体(CdSe NCs)被广泛用于电子照明、太阳能发电、光电传感等领域.然而CdSe NCs的电学、热力学和光物理性质具有较强的尺寸依赖性,在传统的制备方法及应用中容易出现晶体表面缺陷和悬空键以及较...     

紫外光谱估测贵州天麻中的天麻素

采用高效液相色谱法和紫外光谱法测定名贵中药材贵州天麻样品中天麻素的含量,选择在最大吸收波长223nm处,分析天麻素含量与紫外光谱的吸光度数值之间的相关性.采用先聚类后回归的分析法进一步估测天麻中天麻素的含量.结果表明:在223nm处,天麻素含量与紫外光谱的吸光度数值呈显著相关,其相关系数均达到0.98以上.对回归模型进行检验,预测值与实测值吻合.这表明紫外光谱法可为系统评价贵州天麻等级提供理论依据和相关技术手段.     

用于长城等古建筑探测的NMR探测器的磁体设计

以万里长城为代表的古建筑是世界瑰宝,更是中华民族的象征和骄傲.本文提出利用便携式核磁共振（NMR）装置来探测研究这类古建筑的建筑材料,在不对其造成损伤的基础上,发掘其隐含的科学、技术和工程相关的丰富信息.为此,作为第一步,设计了适合于探测这类古建筑的便携式单边NMR探测器组合式磁体.该探测器的磁体结构以semi-Halbach为基础,通过不同磁体模块间的组合得到对应移动探测模式、长距离探测模式和均匀磁场探测模式的磁体结构.随后根据优化结果,设计加工了磁体组件,并采用该磁体进行了流体、长城城砖和现代红砖的NMR实验,实测结果与模拟一致.该组合式磁体的优点在于通过不同磁体模块组合,实现了多种探测方式,适用于探测长城等这类古建筑物需要多种探测模式的科学研究.     

Tm-Doped Fibre Laser Pumped Cr^2＋：ZnSe Poly-Crystal Laser

Demonstrations of cw lasing in Cr^2＋：ZnSe poly-crystal are reported. The laser consists of a 1.7-mm-thick Cr^2＋ ：ZnSe poly-crystal disc pumped by a Tin-silica double-clad fibre laser at 2050nm. Using a concave high- reflection mirror with a radius of curvature of 500mm as the rear mirror, the laser delivers up to 1030mW of radiation around 2.367μm.     

RPIC/ICP-MS测定水中的Cr(Ⅲ)和Cr(Ⅵ)

建立了反相离子对色谱-电感耦合等离子体-质谱(RPIC/ICP-MS)联用技术测定水中痕量三价铬Cr(Ⅲ)和六价铬Cr(Ⅵ)的分析方法。通过对流动相的组成、浓度、pH值等色谱条件的实验,确定当流动相组成为0.25mmol.L-1乙二胺四乙酸二钠和2mmol.L-1四丁基氢氧化铵,5%(V/V)甲醇,pH=7.0时,成功分离了Cr(Ⅲ)和Cr(Ⅵ)离子。ICP-MS测定时选用碰撞反应接口技术(CRI)消除40Ar12C+与35Cl16OH+对52Cr+的质谱干扰,Cr(Ⅲ)和Cr(Ⅵ)的检出限分别为0.50、0.34μg.L-1,RSD<10%(n=5)。应用于湖北黄冈、黄石、襄阳等地企业废水中Cr(Ⅲ)和Cr(Ⅵ)含量的测定,加标回收率为86.1%—100.1%。与分光光度法比对,实验证明本方法能克服用分光光度法测定水中六价铬由样品本身带来的干扰。     

离散元与壳体有限元结合的多尺度方法及其应用

在深入研究复杂结构和非均质材料冲击响应和破坏机理的过程中,往往遇到多尺度计算问题。本文尝试建立三维离散元与壳体有限元结合的多尺度方法用于处理圆柱壳问题,该方法采用三维离散元对感兴趣的局域进行局部模拟,利用平板壳体有限元进行整体模拟,采用一种特殊的过渡层使离散元区和有限元区能很好的衔接。我们将这一方法应用于激光辐照下充压柱壳的热/力耦合冲击破坏响应,得到的模拟结果与文献报道有较好的吻合。     

大电流稳定发射铁电阴极的模拟与实验研究

讨论了铁电阴极的发射机理, 借助MAFIA对不同电极结构的铁电阴极表面电场分布进行了模拟计算. 计算中发现, 发射面电极结构对铁电阴极表面三界点处的场增强效应影响很大,特别是具有孤岛电极结构的铁电阴极具有更大的三界点场强,从而获得更大和更稳定的发射电流. 通过对电极结构及其工艺的改进,使用PLZT铁电阴极在实验中得到了大于100A的电流.     

POSITIVE DEFINITE PROBLEM OF ENERGY DENSITY AND RADIATIVE ENERGY FLUX FOR PULSE CYLINDRICAL GRAVITATIONAL WAVE

By using the general expressions of energy momentum pseudo-tensor of the cylin-drical gravitational waves (GW) given by Rosen and Virbhadra in Cartesian coor-dinates, the concrete forms of energy density and radiative energy flux of the pulse cylindrical GW are obtained. Their physical properties, suitable range and asymp-totic behaviour are considered. It is found that: For the region in which space radial coordinates to origin are greater than the pulse width of the pulse cylindrical GW, the energy density and radiative energy flux of the outward travelling pulse cylindrical GW propagating along at light-cone are positive definite. However, for the region in which the space radial coordinates are less than the pulse width, there is no guarantee for the positive definite property of the radiative energy flux of the outward travelling wave. Moreover, we show that the asymptotic behaviour of the energy and energy flux densities of the pulse cylindrical GW and that of the Riemann curvature tensor have good self-consistancy in space like, time like and null infinity regions.     

Hopf Bifurcation Control of a Hyperchaotic Circuit System

This paper is concerned with the Hopf bifurcation control of a new hyperchaotic circuit system. The stability of the hyperchaotie circuit system depends on a selected control parameter is studied, and the critical value of the system parameter at which Hopf bifurcation occurs is investigated. Theoretical analysis give the stability of the Hopf bifurcation. In particular, washout filter aided feedback controllers are designed for delaying the bifurcation point and ensuring the stability of the bifurcated limit cycles. An important feature of the control laws is that they do not result in any change in the set of equilibria. Computer simulation results are presented to confirm the analytical predictions.     

黄芩中锗的分光光度研究

对黄芩中的锗进行了分光光度法研究，结果表明，黄芩中含有丰富的有机锗。本方法简单可靠，可获得满意的分析结果。