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971.
H. Kim R.C.Y. Auyeung M. Ollinger G.P. Kushto Z.H. Kafafi A. Piqué 《Applied Physics A: Materials Science & Processing》2006,83(1):73-76
Low-temperature laser sintering has been successfully demonstrated to improve the overall conversion efficiency of dye-sensitized solar cells. Mesoporous TiO2 electrodes were prepared from a colloidal solution of TiO2 nanopowders by a laser direct-write technique and then sintered by a quasi-continuous-wave UV laser (λ=355 nm) for the fabrication of dye-sensitized solar cells. The overall conversion efficiency of the cells based on the laser-sintered TiO2 electrodes was double that of the devices with non-laser-treated TiO2 electrodes. This enhancement is attributed to both the removal of organic additives and the improved inter-nanoparticle electrical contacts induced by the laser-sintering process, which led to an increase in porosity and dye-absorption sites in the TiO2 electrodes. PACS 61.80.Ba; 61.46.+w; 73.22.-f; 84.60.Jt 相似文献
972.
G. Hanna T. Glatzel S. Sadewasser N. Ott H.P. Strunk U. Rau J.H. Werner 《Applied Physics A: Materials Science & Processing》2006,82(1):1-7
The influence of different film textures on the electronic properties of polycrystalline Cu(In,Ga)Se2 absorbers is studied by measuring the laterally resolved optoelectronic properties of differently textured Cu(In,Ga)Se2 films with Kelvin probe force microscopy and cathodoluminescence. The grain boundaries in (112)- and (220/204)-textured films behave differently. The work-function profile measured with the Kelvin probe across a grain boundary in (112)-textured films shows a dip indicating positive charges at the grain boundaries. In panchromatic cathodoluminescence mappings in a transmission electron microscope, such grain boundaries appear dark, i.e. the strongly reduced luminescence indicates that the grain boundaries represent strong non-radiative recombination centers. In contrast, grain boundaries in (220/204)-textured films give rise to a dip or a step in the work function indicating slightly negative charge or neutrality. Cathodoluminescence is reduced at such grain boundaries, but less dramatically than in the (112)-textured case. However, when Na is present in the (220/204)-textured films, the grain boundaries are almost invisible in cathodoluminescence mappings. This strong passivating action of Na occurs only in the (220/204)-textured films, due to a particular grain-boundary population. In (112)-textured films and films without pronounced texture, this passivation effect is much less noticeable. PACS 73.50.Gr; 73.61.Ga; 78.60.Hk; 87.64.Dt 相似文献
973.
Girard V Farrenq R Sorokin E Sorokina IT Guelachvili G Picqué N 《Chemical physics letters》2006,419(4-6):584-588
The spectral dynamics of a mid-infrared multimode Cr(2+):ZnSe laser located in a vacuum sealed chamber containing acetylene at low pressure is analyzed by a stepping-mode high-resolution time-resolved Fourier transform interferometer. Doppler-limited absorption spectra of C(2)H(2) in natural isotopic abundance are recorded around 4000 cm(-1) with kilometric absorption path lengths and sensitivities better than 3 10(-8) cm(-1). Two cold bands are newly identified and assigned to the ν(1)+ν(4) (1) and ν(3)+ν(5) (1) transitions of (12)C(13)CH(2). The ν(1)+ν(5) (1) band of (12)C(2)HD and fourteen (12)C(2)H(2) bands are observed, among which for the first time ν(2)+2ν(4) (2)+ν(5) (-1). 相似文献
974.
The bond random mixed compound Fe(Br0.9I0.1)2 has been studied by magnetization and Mössbauer measurements. Although the zero-field cooled and field-cooled magnetization variations are not like a typical spin glass one, the Mössbauer spectrum below Néel temperature shows a hyperfine field distribution. It implies that the 10% FeI2 mixed in FeBr2 can be induced by the bond random effect which causes the sample to exhibit a spin glass-like behavior. 相似文献
975.
Bubble pressure points of ethanol–1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea refrigerant) mixtures from the third Industrial Fluid Properties Simulation Challenge are computed using publicly available molecular simulation software. Several published force fields are compared against the known answers provided in the contest guidelines and the best force fields are used to make predictions for the unknown results. 相似文献
976.
G.J. Zalmai Qing-hong Zhang 《应用数学学报(英文版)》2007,23(2):217-234
In this paper,we discuss a large number of sets of global parametric sufficient optimality condi-tions under various gcneralized (η,ρ)-invexity assumptions for a semi-infinite minmax fractional programmingproblem. 相似文献
977.
978.
V. S. Bilanych I. I. Makauz T. D. Mel’nichenko I. M. Rizak V. M. Rizak 《Physics of the Solid State》2006,48(11):2060-2064
The internal friction in Ge x As40 ? x S60 glasses is investigated in the temperature range 100 K-T g at infralow frequencies (10?3?10?1 Hz). It is shown that the concentration dependence of the internal friction of these materials changes as a result of the transformation of the dominant kinetic unit in dissipative processes of the relaxation and nonrelaxation types. It is established tha the change in the mechanism of internal friction in the Ge x As40 ? x S60 glasses leads to a jump in the activation energy of the α relaxation and to a local minimum in the frequency factor τ0. 相似文献
979.
T. G. Dzherayan A. V. Rudnev V. P. Morgalyuk 《Russian Journal of Applied Chemistry》2006,79(10):1634-1638
Synthesis of polyhexamethyleneguanidine hydrochloride was studied by capillary electrophoresis. A procedure for determining the reaction components was developed. 相似文献
980.
Rogério S. Mol 《Bulletin of the Brazilian Mathematical Society》2006,37(1):29-48
Résumé. Nous définissons des classes polaires associées à une distribution holomorphe singulière de sous-espaces tangents d’une variété
projective lisse. Nous prouvons que ces classes polaires peuvent être calculées en fonction des classes de Chern-Mather du
faisceau tangent de la distribution et réciproquement. Nous utilisons leurs degrés pour borner les degrés de certaines classes
polaires associés à une variété invariante.
*Ce travail a été soutenu par l’Accord de Coopération France-Brésil (CNRS/CNPq) et par la Fondation CAPES-Brésil. 相似文献