The epitaxial growth of gaas using alkylarsine: Part 2. molecular orbital calculation

Semi-empirical molecular orbital calculations were carried out for the compounds (C₂H₅)₃As, (C₂H₅)₃Ga and RAsH₂ (R = C₂H₅, i-C₃H₇, i-C₄H₉, and t-C₄H₉) by using the CNDO/2-U program, and their capability of β-elimination reaction is compared on the basis of the torsion energy to the transition state, electrostatic interactions and orbital overlapping between the central atom and the β-hydrogen, and bond order of the metal-carbon, and carbon-hydrogen bond. In the comparison of (C₂H₅)₃As with (C₂H₅)₃Ga, we found that the β-elimination of (C₂H₅)₃As could hardly be expected to take place in the thermal decomposition. The capability of β-elimination would be smaller in C₂H₅AsH₂ than that in (C₂H₅)₃As. Moreover when the ethyl group is replaced by a t-butyl group in RAsH₂, the β-elimination reaction appears to become more difficult and a large possibility for a radical process is suggested.     

Silver nitrate-acetonitrile and iodine-benzene complexes as studied by NMR in thermotropic liquid crystals

Silver nitrate-acetonitrile and π iodine-benzene complexes in thermotropic liquid crystals have been studied by ¹H, ²H, and ¹³C NMR spectroscopy and by optical microscopy. Evidence for at least two silver complexes in each liquid crystal is presented.     

Properties of neodymium-doped aluminophosphate laser glasses

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 56, No. 1, pp. 90–95, January, 1992.     

Theory of A ϕ-periodic one-dimensional bundle of dielectric waveguides

Mogil' Division, Institute of Physics, Belorussian Academy of Sciences. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 35, No. 2, pp. 200–204, February, 1992.     

On some nonlinear problems in mathematical physics with exponents close to critical ones

The paper deals with several problems having the following common feature. The differential equation under consideration contains a power function of the solution or of its gradient, with the exponent depending on a small parameter. This dependence is such that a certain property of the solutions corresponding to the positive values of the parameter may disappear as the latter tends to zero. This phenomenon is shown to be lacking in the case where not only the said exponent, but also the coefficients of the equation depend on the small parameter in a suitable way. Several theorems are proved on sharp conditions, ensuring such uniformity of various properties exhibited by the solutions. Bibliography: 44 titles. Dedicated to Olga Arsenievna Oleinik This paper has been supported in part by the Russian Foundation for Basic Research (Project 93-013-1744) and by the International Science Foundation (Grant MIE000). Translated from Trudy Seminara imeni I. G. Petrovskogo, No. 19, pp. 000-000, 0000.