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21.
The coordination chemistry of a saccharide-based ferrichrome analogue, 1-O-methyl-2,3,4-tris-O-[4-(N-hydroxy-N-methylcarbamoyl)-n-butyrate]-alpha-d-glucopyranoside (H(3)L), is reported, along with its pK(a) values, Fe(III) and Fe(II) chelation constants, and aqueous-solution speciation as determined by spectrophotometric and potentiometric titration techniques. The use of a saccharide platform to synthesize a hexadentate trihydroxamic acid chelator provides some advantages over other approaches to ferrichrome models, including significant water solubility and hydrogen-bonding capability of the backbone that can potentially provide favorable receptor recognition and biological activity. The pK(a) values for the hydroxamate moieties were found to be similar to those of other trihydroxamates. Proton-dependent Fe(III)-H(3)L and Fe(II)-H(3)L equilibrium constants were determined using a model involving the sequential protonation of the iron(III)- and iron(II)-ligand complexes. These results were used to calculate the formation constants, log beta(110) = 31.86 for Fe(III)L and 12.1 for Fe(II)L(-). The calculated pFe value of 27.1 indicates that H(3)L possesses an Fe(III) affinity comparable to or greater than those of ferrichrome and other ferrichrome analogues and is thermodynamically capable of removing Fe(III) from transferrin. E(1/2) for the Fe(III)L/Fe(II)L(-) couple was determined to be -436 mV from quasi-reversible cyclic voltammograms at pH = 9, and the pH-dependent E(1/2) profile was used to determine the Fe(II)L(-) protonation constants. 相似文献
22.
The quenching process of fluorescence emission in polyfluorene (PF) due to the presence of intramolecular 9-fluorenone (9 FL) moieties is studied in dilute toluene solution as a function of 9 FL content in eight copolymers containing both fluorene and fluorenone units (PF/FL(x)). The absorption spectrum of PF/FL(x) copolymers clearly shows a new absorption band, redshifted relatively to the PF and 9-fluorenone absorption, which increases in intensity when the fluorenone fraction increases and also decreases with solvent polarity. Fluorescence emission spectra of PF/FL(x) show that this redshifted and unstructured emission does not coincide with the 9-fluorenone emission and, with increasing solvent polarity, it further redshifts and decreases in intensity. An isoemissive point is clearly observed on the fluorescence emission spectra of PF/FL(x) as a function of fluorenone content, showing that the new emission band is formed at the expense of PF. We propose the formation of an intramolecular charge transfer complex (ICTC) between PF units and 9-fluorenone to explain the appearance of the new emission band. Global analysis of time resolved fluorescence decays collected at 415 nm (PF emission) and 580 nm (the ICTC emission) show that three exponentials are generally needed to achieve excellent fits. Two of the components (420 ps and 6.5 ns) are independent of 9-fluorenone fraction. A further fast component is strongly dependent on fluorenone fraction and ranges between 280 and 70 ps. This component appears as a decay time at 415 nm and as a rise time at 580 nm and is ascribed to the migration of exciton to quenching sites (formation of intramolecular CT complex or exciton ionization at CT complex). A kinetic mechanism involving three different kinetic species, quenched PF units kinetically coupled with the ICTC complex, and unquenched PF units is proposed to explain the experimental data and the quenching rate constant is obtained, k(1) congruent with 10(11) s(-1). This is an experimental measurement of the intrachain exciton hopping rate. 相似文献
23.
A reversed-phase high-performance liquid chromatography/electrospray ionisation mass spectrometry (HPLC/ESI-MS) method has been developed to conclusively differentiate the epimers betamethasone and dexamethasone and various esterification products (betamethasone and dexamethasone 21-acetate, betamethasone and dexamethasone 21-phosphate, betamethasone 17-valerate, betamethasone 21-valerate and betamethasone 17,21-dipropionate) in counterfeit drugs. Good separation with baseline resolution of all epimers or isomers was obtained on a Zorbax Eclipse XDB or Luna C8 column, using a step gradient with mobile phases of 0.05 M ammonium acetate and acetonitrile. Betamethasones can also be distinguished by the relative abundance of their m/z 279 ion in the positive electrospray tandem mass spectra. The LC/MS or LC/MS/MS method developed was successfully applied to the analysis of drug product samples, i.e. creams and tablets. 相似文献
24.
One-bond 13C, 13C-spin-coupling constants have been measured, with natural isotope abundance, in η4-diene, η3-allyl and η2-ene transition-metal carbonyl complexes. Typical values of 1J(C,C) are given for Fe-, Ru- and Os-complexes with the three types of olefinic ligands. The effects of substituents and the structural significance of the C,C-coupling constants are discussed. 相似文献
25.
Gyula Záray Tibor Kántor Gerhard Wolff Zdravka Zadgorska Hubertus Nickel 《Mikrochimica acta》1992,107(3-6):345-358
The analytical capability of high-temperature halogenation with carbon tetrachloride vapour in a graphite furnace was investigated for silicon carbide powder with known chemical composition and particle size. Intensity vs heating time curves were determined for analytical lines of Al, B, Ba, Ca, Cr, Cu, Fe, Mg, Mn, Ti, V and Si constituents, volatilized with and without the presence of CCl4 vapour in the furnace atmosphere. Igniting 10 mg SiC at 2100 °C for 60 s in chlorinating atmosphere, the evaporated fraction of most of the constituents was higher than 90% (for Al about 50%). The line intensity vs sample mass (4–26 mg) relationships were linear for all impurities studied, while the intensity of silicon line showed a relatively small change with the sample mass. BEC (background equivalent concentration) values for this solid sampling technique (10 mg loaded sample) were 2–20 fold lower than those calculated for the conventional solution sample introduction method. 相似文献
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28.
The X-ray structures of 4,10-di-tert-butyl-5,9-diisopropyl-4,5,9,10-tetraazatetracyclo[6.2.2.2(3,6)]tetradecane (s4iPr) and its 4,9-di-tert-butyl-5,10-diisopropyl isomer (a4iPr) are reported. Both compounds are in conformations having their in-N-alkyl groups (directed toward the central CH-CH bond of the molecule) anti to each other, as expected from previous work. The principal feature of interest is that one in-isopropyl group in each compound is in an eclipsed conformation, NN,C(alpha)Me twist angle -0.5(5) degrees for s4iPr and -6.4(4) degrees for a4iPr. Low energy (somewhat less) eclipsed in-isopropyl conformations are predicted by both molecular mechanics (MM2) and semiempirical quantum mechanical (AM1) calculations. The asymmetry of the potentially C(2) symmetric a4iPr because the two in-isopropyl groups are in different rotamers is apparently not a result of crystal packing forces, because a conformation with different isopropyl rotamers is the more stable one by at least 1.0 kcal/mol in solution, determined by (13)C-NMR spectroscopy. This result is not predicted by either calculation method. The "monomer", 2-tert-butyl-3-isopropyl-2,3-diazabicyclo[2.2.2]octane (3), proves to be a poor model for the conformations of 4iPr. 相似文献
29.
Mossin S Weihe H Sørensen HO Lima N Sessoli R 《Dalton transactions (Cambridge, England : 2003)》2004,(4):632-639
The synthesis, structure and magnetic properties of the one-dimensional chain compounds [Mn(cyclam)(SO4)]ClO4.H2O (1) and [Mn(cyclam)(HCOO)](CF3SO3)(ClO4) (2) are reported. Cyclam is the cyclic tetradentate ligand 1,4,7,11-tetraazacyclotetradecane. Both chain compounds exhibit antiferromagnetic interactions within the chains. A magnetic ordering phase transition at 5.5 K in (1) is investigated by magnetisation measurements along the three principal crystallographic axes of a single crystal and the results show unambiguously that the ferromagnetic ordering is only taking place along one crystallographic axis. The spin structure of the magnetic ordered phase and the magnitude of the ferromagnetic moment are correlated with the crystal structure and symmetry of the compound. 相似文献
30.
Susanne M. Kuen Krzysztof P. Rybakowski 《Journal of Mathematical Analysis and Applications》1985,112(2):378-390
Let b: [?1, 0] → be a nondecreasing, strictly convex C2-function with b(? 1) = 0, and let g: n → n be a locally Lipschitzian mapping, which is the gradient of a function G: n → . Consider the following vector-valued integro-differential equation of the Levin-Nohel type . (E) This equation is used in applications to model various viscoelastic phenomena. By LaSalle's invariance principle, every bounded solution x(t) goes to a connected set of zeros of g, as time t goes to infinity. It is the purpose of this paper to give several geometric criteria assuring the boundedness of solutions of (E) or some of its components. 相似文献