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121.
K. M. Biswas R. N. Dhara H. Mallik S. Halder A. Sinha-Chaudhuri A. Saha D. Ganguly P. De A. S. Brahmachari 《Monatshefte für Chemie / Chemical Monthly》1996,127(1):111-116
Summary The number of carbons represented by each signal of the phenylindoles1,4, and5 is measured quantitatively by integration of their13C NMR spectra, recorded after adding chromium(III) acetylacetonate to the sample solutions as a paramagnetic relaxation agent. Their carbon chemical shifts are assigned unambiguously; the literature assignments of4 are confirmed. By a comparative study of the carbon chemical shifts of1,4, and5, those of2 and3 are also assigned. Theortho carbons of the phenyl group of4 resonate upfield with respect to thepara carbon. Theortho carbons of the 2- and 3-phenyl moieties of1–3 and5, however, are found to absorb downfield from the correspondingpara carbons, probably because of steric and/or electronic effects exerted by their neighbouring phenyl group.
Kernresonanzspektroskopie, 6. Mitt. Einige quantitative Anwendungen der13C-NMR-Spektroskopie auf Phenylindole
Zusammenfassung Die Anzahl der durch jedes Signal der Phenylindole1,4 und5 repräsentierten Kohlenstoffatome wird durch Integration der nach Zusatz von Chrom(III)acetonylacetat als Relaxationsreagens aufgenommenen13C-NMR-Spektren bestimmt. Ihre chemischen Verschiebungen werden eindeutig zugeordnet; die Literaturwerte für4 werden bestätigt. Durch eine vergleichende Untersuchung der13C-chemischen Verschiebungen von1,4 und5 können jene von2 und3 ebenfalls zugeordnet werden. Dieortho-Kohlenstoffe der Phenylgruppe von4 sind gegenüber denpara-Kohlenstoffatomen zu höherem Feld verschoben. Für die 2- und 3-Phenyl-Substituenten von1–3 und5 kehren sich die Verhältnisse um, wahrscheinlich wegen sterischer und/oder elektronischer Effekte der benachbarten Phenylgruppe.相似文献
122.
123.
Simple and efficient strategies toward the synthesis of trisubstituted pyrrolizidines and disubstituted oxazolidine systems by 1,3-dipolar cycloaddition reactions using arylaldehydes and α-amino acids have been developed, followed by a one-pot, three-component strategy. Electron-deficient dipolarophiles, chalcones, were reacted with nonstabilized azomethine ylides derived from arylaldehyde and L-proline in dry dimethyl formamide, leading to substituted pyrrolizidines. The route to substituted oxazolidines involved cycloaddition to the C?O bond of a second molecule of the aldehyde. The structures and stereochemistry of the cycloadducts were established by infrared (IR), NMR spectroscopy, and single-crystal x-ray crystallographic analyses. Condensed Fukui functions and local electrophilicity indices have been computed to characterize the reactive sites and predict the preferred interactions of azomethine ylides to planar chalcones. The softness-matching indices have been evaluated to determine the regioselectivity of the cycloaddition reactions. The theoretical predictions were found to be in complete agreement with the experimental results, implying that the density functional theory (DFT)-based reactivity indices correctly predict the regioselectivities of 1,3-dipolar cycloadditions of azomethine ylides to planar chalcones. The frontier molecular orbital (FMO) energies, electronic chemical potentials, chemical hardness, chemical softness, and global electrophilicity indices of azomethine ylides have been calculated at the DFT/B3LYP/6-31 + G (d, p) level of theory. 相似文献
124.
Ayan Dhara Joshua Weinmann Ana‐Maria Krause Dr. Florian Beuerle 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(35):12473-12478
The introduction of one alkyne moiety at the central carbon atom of the tripodal tribenzotriquinacene scaffold allows easy access to a great variety of apically functionalized derivatives. The spatially well‐separated arrangement of different functional units on the convex face and outer rim was further proven by single‐crystal X‐ray studies. Subsequent modifications that feature a general protecting group‐free strategy for the demethylation of protected catechols in the presence of a terminal alkyne group, an azide–alkyne Huisgen cycloaddition, and Sonogashira cross‐coupling reactions showcase the high synthetic potential of this modular approach for tribenzotriquinacene derivatization. 相似文献
125.
126.
Two hexanuclear zinc(II) complexes, [Zn6(L1)2(μ2-OH)2(μ2-CH3COO)8] · CH3CN (1 · CH3CN) and [Zn6(L2)2(μ2-OH)2(μ2-CH3COO)8] · 4CH3CN (2 · 4CH3CN), where HL1 = 4-methyl-2,6-bis(cyclohexylmethyliminomethyl)-phenol and HL2 = 4-methyl-2,6-bis(1-naphthalylmethyliminomethyl)-phenol, have been synthesized and characterized by elemental analysis, FT-IR and fluorescence spectroscopic methods, and by X-ray diffraction analysis. In the asymmetric unit of complex 1, two of the three zinc atoms have pentacoordinate geometries and the other is tetrahedrally coordinated, whereas the three distinct Zn atoms in complex 2 adopt three different coordination environments, namely distorted octahedral, trigonal bipyramidal and tetrahedral. The fluorescence properties of the ligands and complexes have been investigated. 相似文献
127.
128.
Dr. Debashis Dhara Dr. Scott M. Baliban Dr. Chang-Xin Huo Zahra Rashidijahanabad Dr. Khandra T. Sears Dr. Setare Tahmasebi Nick Dr. Anup Kumar Misra Dr. Sharon M. Tennant Dr. Xuefei Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(68):15953-15968
With the emergence of multidrug resistant Salmonella strains, the development of anti-Salmonella vaccines is an important task. Currently there are no approved vaccines against Salmonella Paratyphi A, the leading cause of paratyphoid fever. To fill this gap, oligosaccharides corresponding to the O-polysaccharide repeating units from the surface of Salmonella Paratyphi A have been synthesized through convergent stereoselective glycosylations. The synthetic glycan antigen was conjugated with a powerful immunogenic carrier system, the bacteriophage Qβ. The resulting construct was able to elicit strong and long-lasting anti-glycan IgG antibody responses, which were highly selective toward Salmonella Paratyphi A associated glycans. The availability of well-defined glycan antigen enabled the determination that one repeating unit of the polysaccharide is sufficient to induce protective antibodies, and the paratose residue and/or the O-acetyl modifications on the backbone are important for recognition by antibodies elicited by a Qβ-tetrasaccharide conjugate. Immune sera provided excellent protection to mice from lethal challenge with Salmonella Paratyphi A, highlighting the potential of the synthetic glycan-based vaccine. 相似文献
129.
Basudeb Dhara 《印度理论与应用数学杂志》2011,42(5):357-369
Let R be a prime ring, d, δ two derivations of R, L a noncentral Lie ideal of R and 0 ≠ a ∈ R. The main object in this paper is to discuss the situations a (d (x)x − xδ (x))
n
= 0 for all x ∈ L and a (d (x)x − xδ (x)) ∈ Z (R) for all x ∈ L, where n ≥ 1 is a fixed integer. 相似文献
130.
Surajit Maity Mridula Guin Dr. Prashant Chandra Singh Prof. G. Naresh Patwari 《Chemphyschem》2011,12(1):26-46
Molecules with multiple hydrogen bonding sites offer the opportunity to investigate competitive hydrogen bonding. Such an investigation can become quite interesting, particularly when the molecule of interest has neither lone‐pair electrons nor strongly acidic/basic groups. Phenylacetylene is one such molecule with three hydrogen bonding sites that cannot be ranked into any known hierarchical pattern. Herein we review the structures of several binary complexes of phenylacetylene investigated using infrared optical double‐resonance spectroscopy in combination with high‐level ab initio methods. The diversity of intermolecular structures formed by phenylacetylene with various reagents is remarkable. The nature of intermolecular interaction with various reagents is the result of a subtle balance between various configurations and competition between the electrostatic and dispersion energy terms, while trying to maximize the total interaction strength. 相似文献