Implications of Nitrogen Doping on Geometrical and Electronic Structure of the Fullerene Dimers

Because of its unsaturated bonds, C₆₀ is susceptible to polymerize into dimers. The implications of nitrogen doping on the geometrical and electronic structure of C₆₀ dimers have been ambiguous for years. A quarter‐century after the discovery of azafullerene dimer (C₅₉N)₂, we reported its single crystallographic structure in 2019. Herein, the unambiguous crystal structure information of (C₅₉N)₂ is elucidated specifically, revealing that the inter‐cage C—C single bond length of (C₅₉N)₂ is comparable with that of an ordinary C(sp³)‐C(sp³) single bond, and that the most stable conformer of (C₅₉N)₂ is gauche‐conformer with a dihedral angle of 66°. To amend the structural deviations, geometrical structure of (C₅₉N)₂ is optimized by a B3LYP‐D3BJ function, which is proved to be more consistent with its single crystal structure than those by the commonly used B3LYP function. Moreover, the calculation method is also suitable for other representative fullerene dimers, such as (C₆₀)₂ and its divalent anion. Additionally, the dissociation of (C₅₉N)₂ at 473 K under mass spectrometric conditions suggests the inter‐cage C—C bond is relatively weaker than an ordinary C—C single bond, which can be explained by the interaction energies of inter‐cages.     

Polymer electrolytes—relaxation and transport properties

Relaxations in polymer electrolytes were studied in poly(ethylene oxide) and epoxidized natural rubbers both filled with lithium perchlorate. Impedance relaxation was investigated over a wide range of salt concentration at room temperature. Imaginary part of impedance as a function of frequency exhibits generally one maximum and one minimum. These two extreme values rule properties in the DC limit. They can be related to transport properties and degree of dissociation. It turns out that DC conductivity is dominantly ruled by transport coefficient.     

圆形薄板二维驻波的研究

在理论上和实验上对圆形薄板二维驻波波节图形(克拉尼图形)进行了研究,通过在极坐标下对圆形薄板的竖向小振动方程进行分离变量,求解出圆形薄板小振动方程在自由边条件下的解析解的简正模式,并进行了数值模拟.发现通过调节圆形薄板上点振动源的位置和频率,可精确控制薄板上出现的克拉尼图形.实验上观察到了仅有圆形波节线,仅有辐射状波节线,以及两种波节线同时存在3种情形,且波节线的数量可严格控制.并在此基础上计算了圆形薄板上二维振动的波矢和波速,以及弹性模量等物理量,且理论结果跟实验符合得很好.     

基于双移位器的FLEXIO模拟SPI总线的设计与实现

针对嵌入式系统设计中专用的串行外设接口SPI数量不能满足要求的问题,提出一种基于双移位器的FlexIO来模拟SPI通信总线的全新方案,首先阐述了FlexIO的硬件架构,然后在分析标准SPI通信协议的基础上,通过对其内部定时器,移位器与芯片引脚的合理配置并结合少量的软件编程设计,最终模拟出拥有全双工,同步功能的SPI通信总线。通过与标准SPI从机通信的实验,表明了用FlexIO模拟的SPI通信总线具有硬件配置灵活,软件需求少且通信可靠的优点,同时也对用它来模拟其他类型的串行通信总线提供了一定的参考价值。     

电容式液氢密度计冷冲击性能试验研究

建立了一套电容式液氢密度计冷冲击试验系统,对新研制的密度计传感器和变送器进行液氢工况下的联合调试,研究其在液氢冲击下的数据采集传输转换性能。从理论分析、系统设计、试验验证、数据分析四方面详细阐述了该试验过程。试验结果表明:密度计在液氢下的信号采集传输特性与理论分析特性基本吻合,输出信号正常,实现了该试验预期效果。     

980nm半导体激光器输出光谱特性的改善

为了改善980nm半导体激光器的输出光谱特性,采用传输矩阵分析法推导了双布喇格光纤光栅谐振腔的传输表达式,对布喇格光纤光栅长度和谐振腔腔长对输出光谱的影响进行模拟仿真,结果表明布喇格光纤光栅长度对输出光谱的影响大于谐振腔腔长对输出光谱的影响,加长布喇格光纤光栅长度能压缩输出光谱线宽.在980nm半导体激光器尾纤上写入不同布喇格光纤光栅长度的双布喇格光纤光栅谐振腔,验证了引入双布喇格光纤光栅谐振腔在压缩980nm半导体激光器输出光谱线宽的同时改善了其输出光谱的稳定性.当环境温度在0~75℃范围内变化时,980nm半导体激光器输出中心波长仅变化0.06nm.     

通过双Σ型激光方案控制振动态布居转移

通过使用含时量子波包方法,对HF分子该类型的布居转移动力学进行了研究. 提出双Σ型激光控制方案,用于控制布居从|v=16>能级向|v=0>能级进行转移. 该方案的第一步是将布居从|v=16>经过中间能级|v=11>向|v=7>转移,第二步是将布居从|v=7>经过中间能级|v=3>向|v=0>转移. 在每一个步骤中,三个振动能级在两束重叠的激光脉冲作用下形成一个Σ型的布居转移路径. 通过优化激光的强度、频率和延迟时间,得到了最大的布居转移效率. 计算并比较了正序脉冲和反序脉冲两种情况,在这两种情况下,布居都可以超过90%从|v=16>能级向|v=0>能级进行转移.