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921.
Selçuk Demir Hamide Merve Çepni Małgorzata Hołyńska Muammer Kavanoz Fatih Yilmaz Yunus Zorlu 《Journal of Coordination Chemistry》2017,70(19):3422-3433
Via an oxidation reaction of Cu(I) iodide with pyridine-2,6-dicarboxylic acid (H2L) in DMF three copper(II) complexes, [(CH3)2NH2]2[CuL2] (1), K2[CuL2]?H2L?H2O (2) and [Cu(L)(H2O)]n (3), were synthesized and characterized. The structures of 1–3 were determined by single crystal X-ray diffraction studies. In-situ DMF decomposition produces dimethylamine base under solvothermal conditions and a proton transfer reaction takes place for the complex formation of 1. 3-D networks are stabilized in 1 and 2 via hydrogen bonds. Complex 3 is a 1-D coordination polymer with Cu-O semi-coordination bonds. Thermal decomposition of the complexes results in the corresponding metal oxides. Also, the electrochemical behavior of 1 was determined to be a metal-centered and diffusion-controlled, one-electron reduction process. 相似文献
922.
The light leakage in a black state of in-plane switching (IPS) liquid crystal display (LCD) associated with rubbing process has been investigated. The mechanical rubbing process with a cloth caused orientation disorders in the liquid crystal directors and these partial orientation disorders result in residual retardations of the IPS LCD, causing the light leakages at the black state. In this study, we theoretically estimated how the light leakage is associated with the rubbing uniformity using 2 × 2 Jones matrix equation and also experimentally confirmed how it is associated with structural properties of the alignment layer. The light leakage was clearly reduced in the alignment layer with reduced crystallinity and flexibility. 相似文献
923.
A higher order asymptotic solution of near-tip field is studied for plane-atrain Mode-I quasi-static steady crack growth in
the incompressible (v=1/2) elastic perfectly-plastic media. The results show that the near-tip stress and strain are fully continuous, and the
strain possesses In (A/r) singularity at the crack tip. The expressions of the stress, strain and velocity in each region are also given.
The project supported by National Natural Science Foundation of China 相似文献
924.
The orienting properties of incompressible discotic nematic liquid crystals for creeping flows between converging and diverging planar walls (Jeffrey-Hamel) are analyzed using the Leslie-Ericksen theory. The dependence of director orientation on the reactive parameter and the flow kinematics is presented. Closed form stationary solutions for the director orientation are found when elastic effects are neglected. Stationary numerical solutions for the velocity and director fields using the full Leslie-Ericksen theory are presented. The director field in converging flow is characterized by azimuthal (radial) centerline orientation, by being asymmetric with respect to the azimuthal (radial) direction, and by having an allowed orientation range that spans two half-quadrants (full quadrants). In the limiting case of perfectly flat disk ( –) the flow-induced director orientation in converging flow is the azimuthal direction, while in diverging flow the director rotates by a full n radians. By reducing the vertex angle between the walls to vanishingly small values, converging flow solutions properly reduce to those of flow between parallel plates, but diverging flows are expected to lead to a new instability. 相似文献
925.
Experimental and theoretical study of the nonlinear response of agiant magnetostrictive rod 总被引:1,自引:0,他引:1
In this paper, a magnetomechanical coupling constitutive relation of the giant magnetostrictive material was investigated
experimentally and theoretically. A grain-oriented magnetostrictive rod of iron and rare earth was tested under a combined
magnetomechanical loading. Two types of experimental curves were obtained, i.e., the magnetostrictive curve of the extensional
strain vs the magnetic field, and the curve of the magnetic polarization intensity vs the pre-stress. A new theoretical constitutive
model, based on the density of domain switching, is developed. Comparison of the theoretical predictions with the experimental
results indicates that this model can capture the main characteristics of the magnetoelastic coupling deformation of a giant
magnetostrictive rod.
The project supported by the National Natural Science Foundation of China (10025209, 10132010, 10102007) 相似文献
926.
The classical Rayleigh-Taylor instability is shown to be valid in a nonlinear dynamical sense for smooth density profiles.
(Accepted September 23, 2002)
Published online February 26, 2003
Communicated by Y. Brenier 相似文献
927.
928.
Cruciform and lap welds were fatigue tested under constant amplitude axial load and SAE Bracket spectrum load conditions. For the cruciform joints, fatigue cracks generally initiate at the root but may initiate at the toe if higher bending stresses are induced by joint distortion. For lap welds, the stress ratio () and weld shape are the major factors influencing the fatigue crack initiation site.The fatigue test results were compared with predictions made using an analytical model developed by the authors, and good agreement between experiment and theory was observed. The model for the predictions assumes that the fatigue crack initiation period, which is the number of cycles for the initiation of a fatigue crack and its early growth and coalescence into a dominant fatigue crack, is the main portion of the total fatigue life at long lives. 相似文献
929.
In spite of its simplicity and a well-defined theoretical basis, the Flory–Guggenheim approach is conventionally regarded as inapplicable to off-lattice system since the insertion probability of the approach does not account for the excluded region, existing in the off-lattice system. In this work, we propose the insertion probability accounting for the excluded region of off-lattice fluids and derive a new version of equation of state (EOS) for hard-sphere chains basing on the Flory–Guggenheim approach. To investigate the behavior of the excluded regions, a Monte Carlo sampling was performed for hard disks and the various excluded regions were found to have different density dependence. On the basis of the simulation result, we formulated the insertion probability for hard-sphere and that of hard-sphere chain which accounts for the effect of chain-connectivity on the monomer insertion. The proposed insertion probability was found to correctly predict the simulation data for monomer and correctly correlate the simulation data for chain fluids. The resulting EOS was found to meet closed-packed limit and predict the simulation data of compressibility factor for monomer and chains with a reasonable degree of accuracy. When compared with other off-lattice based EOS, it shows a comparable or better result. For second virial coefficient of chain molecules, the model was found to reasonably predict the simulation data. 相似文献
930.
Lee JM Min YJ Lee KB Jeon SG Na JG Ryu HJ 《Langmuir : the ACS journal of surfaces and colloids》2010,26(24):18788-18797
The awareness of symptoms of global warming and its seriousness urges the development of technologies to reduce greenhouse gas emissions. Carbon dioxide (CO(2)) is a representative greenhouse gas, and numerous methods to capture and storage CO(2) have been considered. Recently, the technology to remove high-temperature CO(2) by sorption has received lots of attention. In this study, hydrotalcite, which has been known to have CO(2) sorption capability at high temperature, was impregnated with K(2)CO(3) to enhance CO(2) sorption uptake, and the mechanism of CO(2) sorption enhancement on K(2)CO(3)-promoted hydrotalcite was investigated. Thermogravimetric analysis was used to measure equilibrium CO(2) sorption uptake and to estimate CO(2) sorption kinetics. The analyses based on N(2) gas physisorption, X-ray diffractometry, Fourier transform infrared spectrometry, Raman spectrometry, transmission electron microscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy were carried out to elucidate the characteristics of sorbents and the mechanism of enhanced CO(2) sorption. The equilibrium CO(2) sorption uptake on hydrotalcite could be increased up to 10 times by impregnation with K(2)CO(3), and there was an optimal amount of K(2)CO(3) for a maximum equilibrium CO(2) sorption uptake. In the K(2)CO(3)-promoted hydrotalcite, K(2)CO(3) was incorporated without changing the structure of hydrotalcite and it was thermally stabilized, resulting in the enhanced equilibrium CO(2) sorption uptake and fast CO(2) sorption kinetics. 相似文献